Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response
- Autores
- Parra, Rodrigo; Savu, Raluca; Ramajo, Leandro Alfredo; Ponce, Miguel Adolfo; Varela, J. A.; Castro, Miriam Susana; Bueno. P. R.; Joanni, E.
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A new sol–gel synthesis procedure of stable calcium copper titanate (CaCu3Ti4O12—CCTO) precursor sols for the fabrication of porous films was developed. The composition of the sol was selected in order to avoid the precipitation of undesired phases; ethanol was used as solvent, acetic acid as modifier and poly(ethyleneglycol) as a linker agent. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 °C. The main phase present in the samples, as detected by X-ray diffraction and Raman spectroscopy, was CaCu3Ti4O12. Scanning electron microscopy analysis showed that mesoporous structures, with thicknesses between 200 and 400 nm, were developed as a result of the processing conditions. The films were tested regarding their sensibility towards oxygen and nitrogen at atmospheric pressure using working temperatures from 200 to 290 °C. The samples exhibited n-type conductivity, high sensitivity and short response times. These characteristics indicate that CCTO mesoporous structures obtained by sol–gel are suitable for application in gas sensing.
Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Savu, Raluca. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ponce, Miguel Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Varela, J. A.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Bueno. P. R.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Joanni, E.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil. Centro de Tecnologia da Informação Renato Archer; Brasil - Materia
-
Cacu3ti4o12
Mesoporous Films
Gas Sensor - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/13241
Ver los metadatos del registro completo
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Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing responseParra, RodrigoSavu, RalucaRamajo, Leandro AlfredoPonce, Miguel AdolfoVarela, J. A.Castro, Miriam SusanaBueno. P. R.Joanni, E.Cacu3ti4o12Mesoporous FilmsGas Sensorhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new sol–gel synthesis procedure of stable calcium copper titanate (CaCu3Ti4O12—CCTO) precursor sols for the fabrication of porous films was developed. The composition of the sol was selected in order to avoid the precipitation of undesired phases; ethanol was used as solvent, acetic acid as modifier and poly(ethyleneglycol) as a linker agent. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 °C. The main phase present in the samples, as detected by X-ray diffraction and Raman spectroscopy, was CaCu3Ti4O12. Scanning electron microscopy analysis showed that mesoporous structures, with thicknesses between 200 and 400 nm, were developed as a result of the processing conditions. The films were tested regarding their sensibility towards oxygen and nitrogen at atmospheric pressure using working temperatures from 200 to 290 °C. The samples exhibited n-type conductivity, high sensitivity and short response times. These characteristics indicate that CCTO mesoporous structures obtained by sol–gel are suitable for application in gas sensing.Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Savu, Raluca. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Ponce, Miguel Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Varela, J. A.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Bueno. P. R.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Joanni, E.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil. Centro de Tecnologia da Informação Renato Archer; BrasilElsevier2010-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13241Parra, Rodrigo; Savu, Raluca; Ramajo, Leandro Alfredo; Ponce, Miguel Adolfo; Varela, J. A.; et al.; Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response; Elsevier; Journal Of Solid State Chemistry; 183; 6; 1-4-2010; 1209-12140022-4596enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022459610001234info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2010.03.033info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:59:41Zoai:ri.conicet.gov.ar:11336/13241instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:59:41.895CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response |
title |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response |
spellingShingle |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response Parra, Rodrigo Cacu3ti4o12 Mesoporous Films Gas Sensor |
title_short |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response |
title_full |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response |
title_fullStr |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response |
title_full_unstemmed |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response |
title_sort |
Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response |
dc.creator.none.fl_str_mv |
Parra, Rodrigo Savu, Raluca Ramajo, Leandro Alfredo Ponce, Miguel Adolfo Varela, J. A. Castro, Miriam Susana Bueno. P. R. Joanni, E. |
author |
Parra, Rodrigo |
author_facet |
Parra, Rodrigo Savu, Raluca Ramajo, Leandro Alfredo Ponce, Miguel Adolfo Varela, J. A. Castro, Miriam Susana Bueno. P. R. Joanni, E. |
author_role |
author |
author2 |
Savu, Raluca Ramajo, Leandro Alfredo Ponce, Miguel Adolfo Varela, J. A. Castro, Miriam Susana Bueno. P. R. Joanni, E. |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Cacu3ti4o12 Mesoporous Films Gas Sensor |
topic |
Cacu3ti4o12 Mesoporous Films Gas Sensor |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A new sol–gel synthesis procedure of stable calcium copper titanate (CaCu3Ti4O12—CCTO) precursor sols for the fabrication of porous films was developed. The composition of the sol was selected in order to avoid the precipitation of undesired phases; ethanol was used as solvent, acetic acid as modifier and poly(ethyleneglycol) as a linker agent. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 °C. The main phase present in the samples, as detected by X-ray diffraction and Raman spectroscopy, was CaCu3Ti4O12. Scanning electron microscopy analysis showed that mesoporous structures, with thicknesses between 200 and 400 nm, were developed as a result of the processing conditions. The films were tested regarding their sensibility towards oxygen and nitrogen at atmospheric pressure using working temperatures from 200 to 290 °C. The samples exhibited n-type conductivity, high sensitivity and short response times. These characteristics indicate that CCTO mesoporous structures obtained by sol–gel are suitable for application in gas sensing. Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Savu, Raluca. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil Fil: Ramajo, Leandro Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Ponce, Miguel Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Varela, J. A.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil Fil: Castro, Miriam Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina Fil: Bueno. P. R.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil Fil: Joanni, E.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil. Centro de Tecnologia da Informação Renato Archer; Brasil |
description |
A new sol–gel synthesis procedure of stable calcium copper titanate (CaCu3Ti4O12—CCTO) precursor sols for the fabrication of porous films was developed. The composition of the sol was selected in order to avoid the precipitation of undesired phases; ethanol was used as solvent, acetic acid as modifier and poly(ethyleneglycol) as a linker agent. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 °C. The main phase present in the samples, as detected by X-ray diffraction and Raman spectroscopy, was CaCu3Ti4O12. Scanning electron microscopy analysis showed that mesoporous structures, with thicknesses between 200 and 400 nm, were developed as a result of the processing conditions. The films were tested regarding their sensibility towards oxygen and nitrogen at atmospheric pressure using working temperatures from 200 to 290 °C. The samples exhibited n-type conductivity, high sensitivity and short response times. These characteristics indicate that CCTO mesoporous structures obtained by sol–gel are suitable for application in gas sensing. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-04-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/13241 Parra, Rodrigo; Savu, Raluca; Ramajo, Leandro Alfredo; Ponce, Miguel Adolfo; Varela, J. A.; et al.; Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response; Elsevier; Journal Of Solid State Chemistry; 183; 6; 1-4-2010; 1209-1214 0022-4596 |
url |
http://hdl.handle.net/11336/13241 |
identifier_str_mv |
Parra, Rodrigo; Savu, Raluca; Ramajo, Leandro Alfredo; Ponce, Miguel Adolfo; Varela, J. A.; et al.; Sol–gel synthesis of mesoporous CaCu3Ti4O12 thin films and their gas sensing response; Elsevier; Journal Of Solid State Chemistry; 183; 6; 1-4-2010; 1209-1214 0022-4596 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022459610001234 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2010.03.033 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613769289793536 |
score |
13.070432 |