Polymeric networks based on tung oil: reaction and modification with green oil monomers

Autores
Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A highly unsaturated vegetable oil (tung oil) was cationically copolymerized with a vegetable oil derived monomer, that replaces the more frequently used styrene. The synthesized comonomer was methyl ester of tung oil, obtained by transesterification of the plant oil with methanol. Alternatively, the incorporation of a green modifier, a commercial acrylated epoxidized soybean oil, was also considered. The use of any of these modifiers allowed preparing materials with an elevated content of bio-derived components.All the materials obtained presented good mechanical damping capacity, as well as dynamic mechanical properties comparable to analogous materials obtained by copolymerization with styrene. Incorporation of low concentrations of divinylbenzene in the formulations allowed increasing rigidity and glass transition temperatures (Tg) of the materials. One of the formulations prepared by copolymerization with the tung oil methyl ester presented shape memory behavior.
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Tung Oil
Methyl Ester
Acrylated Epoxidized Soybean Oil
Damping Properties
Cationic Copolymerization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10425
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/10425
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Polymeric networks based on tung oil: reaction and modification with green oil monomersMeiorin, CintiaAranguren, Mirta InesMosiewicki, Mirna AlejandraTung OilMethyl EsterAcrylated Epoxidized Soybean OilDamping PropertiesCationic Copolymerizationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A highly unsaturated vegetable oil (tung oil) was cationically copolymerized with a vegetable oil derived monomer, that replaces the more frequently used styrene. The synthesized comonomer was methyl ester of tung oil, obtained by transesterification of the plant oil with methanol. Alternatively, the incorporation of a green modifier, a commercial acrylated epoxidized soybean oil, was also considered. The use of any of these modifiers allowed preparing materials with an elevated content of bio-derived components.All the materials obtained presented good mechanical damping capacity, as well as dynamic mechanical properties comparable to analogous materials obtained by copolymerization with styrene. Incorporation of low concentrations of divinylbenzene in the formulations allowed increasing rigidity and glass transition temperatures (Tg) of the materials. One of the formulations prepared by copolymerization with the tung oil methyl ester presented shape memory behavior.Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2015-01-19info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10425Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Polymeric networks based on tung oil: reaction and modification with green oil monomers; Elsevier; European Polymer Journal; 67; 19-1-2015; 551-5600014-3057enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0014305715000178info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2015.01.005info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:42Zoai:ri.conicet.gov.ar:11336/10425instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:42.565CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polymeric networks based on tung oil: reaction and modification with green oil monomers
title Polymeric networks based on tung oil: reaction and modification with green oil monomers
spellingShingle Polymeric networks based on tung oil: reaction and modification with green oil monomers
Meiorin, Cintia
Tung Oil
Methyl Ester
Acrylated Epoxidized Soybean Oil
Damping Properties
Cationic Copolymerization
title_short Polymeric networks based on tung oil: reaction and modification with green oil monomers
title_full Polymeric networks based on tung oil: reaction and modification with green oil monomers
title_fullStr Polymeric networks based on tung oil: reaction and modification with green oil monomers
title_full_unstemmed Polymeric networks based on tung oil: reaction and modification with green oil monomers
title_sort Polymeric networks based on tung oil: reaction and modification with green oil monomers
dc.creator.none.fl_str_mv Meiorin, Cintia
Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author Meiorin, Cintia
author_facet Meiorin, Cintia
Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author_role author
author2 Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author2_role author
author
dc.subject.none.fl_str_mv Tung Oil
Methyl Ester
Acrylated Epoxidized Soybean Oil
Damping Properties
Cationic Copolymerization
topic Tung Oil
Methyl Ester
Acrylated Epoxidized Soybean Oil
Damping Properties
Cationic Copolymerization
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A highly unsaturated vegetable oil (tung oil) was cationically copolymerized with a vegetable oil derived monomer, that replaces the more frequently used styrene. The synthesized comonomer was methyl ester of tung oil, obtained by transesterification of the plant oil with methanol. Alternatively, the incorporation of a green modifier, a commercial acrylated epoxidized soybean oil, was also considered. The use of any of these modifiers allowed preparing materials with an elevated content of bio-derived components.All the materials obtained presented good mechanical damping capacity, as well as dynamic mechanical properties comparable to analogous materials obtained by copolymerization with styrene. Incorporation of low concentrations of divinylbenzene in the formulations allowed increasing rigidity and glass transition temperatures (Tg) of the materials. One of the formulations prepared by copolymerization with the tung oil methyl ester presented shape memory behavior.
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description A highly unsaturated vegetable oil (tung oil) was cationically copolymerized with a vegetable oil derived monomer, that replaces the more frequently used styrene. The synthesized comonomer was methyl ester of tung oil, obtained by transesterification of the plant oil with methanol. Alternatively, the incorporation of a green modifier, a commercial acrylated epoxidized soybean oil, was also considered. The use of any of these modifiers allowed preparing materials with an elevated content of bio-derived components.All the materials obtained presented good mechanical damping capacity, as well as dynamic mechanical properties comparable to analogous materials obtained by copolymerization with styrene. Incorporation of low concentrations of divinylbenzene in the formulations allowed increasing rigidity and glass transition temperatures (Tg) of the materials. One of the formulations prepared by copolymerization with the tung oil methyl ester presented shape memory behavior.
publishDate 2015
dc.date.none.fl_str_mv 2015-01-19
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10425
Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Polymeric networks based on tung oil: reaction and modification with green oil monomers; Elsevier; European Polymer Journal; 67; 19-1-2015; 551-560
0014-3057
url http://hdl.handle.net/11336/10425
identifier_str_mv Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Polymeric networks based on tung oil: reaction and modification with green oil monomers; Elsevier; European Polymer Journal; 67; 19-1-2015; 551-560
0014-3057
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0014305715000178
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2015.01.005
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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