Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity

Autores
Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The mechanical and damping properties as well as the shape memory behavior of copolymers obtained by cationic copolymerization of tung oil with styrene with different stoichiometric ratios are presented and analyzed in this work. The glass transition temperatures are close to room temperature for all the copolymers, and generally increase with the content of styrene. A similar trend is observed for the modulus, which exhibits values from 4.89 MPa for the copolymer with 30 wt% styrene to 13.92 MPa for the copolymer with 70 wt% styrene. These hard elastomers present shape memory behavior with high recovery and fixity ratios, as well as high damping quality (damping factors 0.4 and 1.38 at 28.9 and 43.3 °C, for the tung oil homopolymer and the copolymer with 70 wt% styrene, respectively), opening possibilities for practical applications that require material response close to room temperature.
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
CATIONIC COPOLYMERIZATION
DAMPING PROPERTIES
SHAPE MEMORY EFFECT
STYRENE
VEGETABLE OIL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/96091

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network_name_str CONICET Digital (CONICET)
spelling Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacityMeiorin, CintiaAranguren, Mirta InesMosiewicki, Mirna AlejandraCATIONIC COPOLYMERIZATIONDAMPING PROPERTIESSHAPE MEMORY EFFECTSTYRENEVEGETABLE OILhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The mechanical and damping properties as well as the shape memory behavior of copolymers obtained by cationic copolymerization of tung oil with styrene with different stoichiometric ratios are presented and analyzed in this work. The glass transition temperatures are close to room temperature for all the copolymers, and generally increase with the content of styrene. A similar trend is observed for the modulus, which exhibits values from 4.89 MPa for the copolymer with 30 wt% styrene to 13.92 MPa for the copolymer with 70 wt% styrene. These hard elastomers present shape memory behavior with high recovery and fixity ratios, as well as high damping quality (damping factors 0.4 and 1.38 at 28.9 and 43.3 °C, for the tung oil homopolymer and the copolymer with 70 wt% styrene, respectively), opening possibilities for practical applications that require material response close to room temperature.Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Ltd2012-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/96091Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity; John Wiley & Sons Ltd; Polymer International; 61; 5; 5-2012; 735-7420959-8103CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/pi.3231info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/pi.3231info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:14:17Zoai:ri.conicet.gov.ar:11336/96091instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:14:17.408CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
title Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
spellingShingle Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
Meiorin, Cintia
CATIONIC COPOLYMERIZATION
DAMPING PROPERTIES
SHAPE MEMORY EFFECT
STYRENE
VEGETABLE OIL
title_short Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
title_full Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
title_fullStr Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
title_full_unstemmed Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
title_sort Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity
dc.creator.none.fl_str_mv Meiorin, Cintia
Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author Meiorin, Cintia
author_facet Meiorin, Cintia
Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author_role author
author2 Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author2_role author
author
dc.subject.none.fl_str_mv CATIONIC COPOLYMERIZATION
DAMPING PROPERTIES
SHAPE MEMORY EFFECT
STYRENE
VEGETABLE OIL
topic CATIONIC COPOLYMERIZATION
DAMPING PROPERTIES
SHAPE MEMORY EFFECT
STYRENE
VEGETABLE OIL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The mechanical and damping properties as well as the shape memory behavior of copolymers obtained by cationic copolymerization of tung oil with styrene with different stoichiometric ratios are presented and analyzed in this work. The glass transition temperatures are close to room temperature for all the copolymers, and generally increase with the content of styrene. A similar trend is observed for the modulus, which exhibits values from 4.89 MPa for the copolymer with 30 wt% styrene to 13.92 MPa for the copolymer with 70 wt% styrene. These hard elastomers present shape memory behavior with high recovery and fixity ratios, as well as high damping quality (damping factors 0.4 and 1.38 at 28.9 and 43.3 °C, for the tung oil homopolymer and the copolymer with 70 wt% styrene, respectively), opening possibilities for practical applications that require material response close to room temperature.
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The mechanical and damping properties as well as the shape memory behavior of copolymers obtained by cationic copolymerization of tung oil with styrene with different stoichiometric ratios are presented and analyzed in this work. The glass transition temperatures are close to room temperature for all the copolymers, and generally increase with the content of styrene. A similar trend is observed for the modulus, which exhibits values from 4.89 MPa for the copolymer with 30 wt% styrene to 13.92 MPa for the copolymer with 70 wt% styrene. These hard elastomers present shape memory behavior with high recovery and fixity ratios, as well as high damping quality (damping factors 0.4 and 1.38 at 28.9 and 43.3 °C, for the tung oil homopolymer and the copolymer with 70 wt% styrene, respectively), opening possibilities for practical applications that require material response close to room temperature.
publishDate 2012
dc.date.none.fl_str_mv 2012-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/96091
Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity; John Wiley & Sons Ltd; Polymer International; 61; 5; 5-2012; 735-742
0959-8103
CONICET Digital
CONICET
url http://hdl.handle.net/11336/96091
identifier_str_mv Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Vegetable oil/styrene thermoset copolymers with shape memory behavior and damping capacity; John Wiley & Sons Ltd; Polymer International; 61; 5; 5-2012; 735-742
0959-8103
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/pi.3231
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/pi.3231
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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