Ageing of thermosets based on tung oil/styrene/divinylbenzene

Autores
Meiorin, Cintia; Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
New thermoset polymers prepared by cationic co-polymerization of tung oil with styrene and/or divinylbenzene were evaluated at different times after their preparation. The changes in the properties were correlated with the composition of the copolymers. The action of atmospheric oxygen on the fatty acid unsaturations produced chemical changes in these polymers, which affected the properties of the cured materials. These changes were analyzed by FTIR, dynamic mechanical properties and mechanical testing. An increase in the modulus with time for all the analyzed samples was observed, as well as a large effect on the glass transition temperature and, consequently, in the shape memory properties.
Fil: Meiorin, Cintia. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Mosiewicki, Mirna Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Aranguren, Mirta Ines. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Materia
AGEING
MECHANICAL PROPERTIES
OXIDATIVE POLYMERIZATION
TUNG OIL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2755

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spelling Ageing of thermosets based on tung oil/styrene/divinylbenzeneMeiorin, CintiaMosiewicki, Mirna AlejandraAranguren, Mirta InesAGEINGMECHANICAL PROPERTIESOXIDATIVE POLYMERIZATIONTUNG OILhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1New thermoset polymers prepared by cationic co-polymerization of tung oil with styrene and/or divinylbenzene were evaluated at different times after their preparation. The changes in the properties were correlated with the composition of the copolymers. The action of atmospheric oxygen on the fatty acid unsaturations produced chemical changes in these polymers, which affected the properties of the cured materials. These changes were analyzed by FTIR, dynamic mechanical properties and mechanical testing. An increase in the modulus with time for all the analyzed samples was observed, as well as a large effect on the glass transition temperature and, consequently, in the shape memory properties.Fil: Meiorin, Cintia. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Mosiewicki, Mirna Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Aranguren, Mirta Ines. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaElsevier2012-10-31info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2755Meiorin, Cintia; Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines; Ageing of thermosets based on tung oil/styrene/divinylbenzene; Elsevier; Polymer Testing; 32; 2; 31-10-2012; 249-2550142-9418enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2012.10.009info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0142941812002127info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:04:09Zoai:ri.conicet.gov.ar:11336/2755instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:04:10.095CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ageing of thermosets based on tung oil/styrene/divinylbenzene
title Ageing of thermosets based on tung oil/styrene/divinylbenzene
spellingShingle Ageing of thermosets based on tung oil/styrene/divinylbenzene
Meiorin, Cintia
AGEING
MECHANICAL PROPERTIES
OXIDATIVE POLYMERIZATION
TUNG OIL
title_short Ageing of thermosets based on tung oil/styrene/divinylbenzene
title_full Ageing of thermosets based on tung oil/styrene/divinylbenzene
title_fullStr Ageing of thermosets based on tung oil/styrene/divinylbenzene
title_full_unstemmed Ageing of thermosets based on tung oil/styrene/divinylbenzene
title_sort Ageing of thermosets based on tung oil/styrene/divinylbenzene
dc.creator.none.fl_str_mv Meiorin, Cintia
Mosiewicki, Mirna Alejandra
Aranguren, Mirta Ines
author Meiorin, Cintia
author_facet Meiorin, Cintia
Mosiewicki, Mirna Alejandra
Aranguren, Mirta Ines
author_role author
author2 Mosiewicki, Mirna Alejandra
Aranguren, Mirta Ines
author2_role author
author
dc.subject.none.fl_str_mv AGEING
MECHANICAL PROPERTIES
OXIDATIVE POLYMERIZATION
TUNG OIL
topic AGEING
MECHANICAL PROPERTIES
OXIDATIVE POLYMERIZATION
TUNG OIL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv New thermoset polymers prepared by cationic co-polymerization of tung oil with styrene and/or divinylbenzene were evaluated at different times after their preparation. The changes in the properties were correlated with the composition of the copolymers. The action of atmospheric oxygen on the fatty acid unsaturations produced chemical changes in these polymers, which affected the properties of the cured materials. These changes were analyzed by FTIR, dynamic mechanical properties and mechanical testing. An increase in the modulus with time for all the analyzed samples was observed, as well as a large effect on the glass transition temperature and, consequently, in the shape memory properties.
Fil: Meiorin, Cintia. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Mosiewicki, Mirna Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Aranguren, Mirta Ines. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
description New thermoset polymers prepared by cationic co-polymerization of tung oil with styrene and/or divinylbenzene were evaluated at different times after their preparation. The changes in the properties were correlated with the composition of the copolymers. The action of atmospheric oxygen on the fatty acid unsaturations produced chemical changes in these polymers, which affected the properties of the cured materials. These changes were analyzed by FTIR, dynamic mechanical properties and mechanical testing. An increase in the modulus with time for all the analyzed samples was observed, as well as a large effect on the glass transition temperature and, consequently, in the shape memory properties.
publishDate 2012
dc.date.none.fl_str_mv 2012-10-31
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2755
Meiorin, Cintia; Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines; Ageing of thermosets based on tung oil/styrene/divinylbenzene; Elsevier; Polymer Testing; 32; 2; 31-10-2012; 249-255
0142-9418
url http://hdl.handle.net/11336/2755
identifier_str_mv Meiorin, Cintia; Mosiewicki, Mirna Alejandra; Aranguren, Mirta Ines; Ageing of thermosets based on tung oil/styrene/divinylbenzene; Elsevier; Polymer Testing; 32; 2; 31-10-2012; 249-255
0142-9418
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2012.10.009
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0142941812002127
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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