Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization

Autores
Ribeiro Da Silva, Virginia; Mosiewicki, Mirna Alejandra; Yoshida, Maria Irene; Coelho Da Silva, Mercês; Stefani, Pablo Marcelo; Marcovich, Norma Esther
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m3, depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. © 2013 Elsevier Ltd. All rights reserved.
Fil: Ribeiro Da Silva, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Universidade Federal de Minas Gerais; Brasil. Ministry of Education of Brazil. CAPES Foundation; Brasil
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Yoshida, Maria Irene. Universidade Federal de Minas Gerais; Brasil
Fil: Coelho Da Silva, Mercês. Universidade Federal de Itajubá; Brasil
Fil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Marcovich, Norma Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Polyurethane Foam Tung Oil Mechanical Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/79017
Acceder
id CONICETDig_739cbfc67188fcbd54de7ca0a5d73bcf
oai_identifier_str oai:ri.conicet.gov.ar:11336/79017
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterizationRibeiro Da Silva, VirginiaMosiewicki, Mirna AlejandraYoshida, Maria IreneCoelho Da Silva, MercêsStefani, Pablo MarceloMarcovich, Norma EstherPolyurethane Foam Tung Oil Mechanical Propertieshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m3, depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. © 2013 Elsevier Ltd. All rights reserved.Fil: Ribeiro Da Silva, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Universidade Federal de Minas Gerais; Brasil. Ministry of Education of Brazil. CAPES Foundation; BrasilFil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Yoshida, Maria Irene. Universidade Federal de Minas Gerais; BrasilFil: Coelho Da Silva, Mercês. Universidade Federal de Itajubá; BrasilFil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Marcovich, Norma Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2013-03-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/79017Ribeiro Da Silva, Virginia; Mosiewicki, Mirna Alejandra; Yoshida, Maria Irene; Coelho Da Silva, Mercês; Stefani, Pablo Marcelo; et al.; Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization; Elsevier; Polymer Testing; 32; 4; 21-3-2013; 665-6720142-9418CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2013.03.010info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0142941813000500info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:14:19Zoai:ri.conicet.gov.ar:11336/79017instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:14:19.541CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
title Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
spellingShingle Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
Ribeiro Da Silva, Virginia
Polyurethane Foam Tung Oil Mechanical Properties
title_short Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
title_full Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
title_fullStr Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
title_full_unstemmed Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
title_sort Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
dc.creator.none.fl_str_mv Ribeiro Da Silva, Virginia
Mosiewicki, Mirna Alejandra
Yoshida, Maria Irene
Coelho Da Silva, Mercês
Stefani, Pablo Marcelo
Marcovich, Norma Esther
author Ribeiro Da Silva, Virginia
author_facet Ribeiro Da Silva, Virginia
Mosiewicki, Mirna Alejandra
Yoshida, Maria Irene
Coelho Da Silva, Mercês
Stefani, Pablo Marcelo
Marcovich, Norma Esther
author_role author
author2 Mosiewicki, Mirna Alejandra
Yoshida, Maria Irene
Coelho Da Silva, Mercês
Stefani, Pablo Marcelo
Marcovich, Norma Esther
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Polyurethane Foam Tung Oil Mechanical Properties
topic Polyurethane Foam Tung Oil Mechanical Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m3, depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. © 2013 Elsevier Ltd. All rights reserved.
Fil: Ribeiro Da Silva, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Universidade Federal de Minas Gerais; Brasil. Ministry of Education of Brazil. CAPES Foundation; Brasil
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Yoshida, Maria Irene. Universidade Federal de Minas Gerais; Brasil
Fil: Coelho Da Silva, Mercês. Universidade Federal de Itajubá; Brasil
Fil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Marcovich, Norma Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m3, depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. © 2013 Elsevier Ltd. All rights reserved.
publishDate 2013
dc.date.none.fl_str_mv 2013-03-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/79017
Ribeiro Da Silva, Virginia; Mosiewicki, Mirna Alejandra; Yoshida, Maria Irene; Coelho Da Silva, Mercês; Stefani, Pablo Marcelo; et al.; Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization; Elsevier; Polymer Testing; 32; 4; 21-3-2013; 665-672
0142-9418
CONICET Digital
CONICET
url http://hdl.handle.net/11336/79017
identifier_str_mv Ribeiro Da Silva, Virginia; Mosiewicki, Mirna Alejandra; Yoshida, Maria Irene; Coelho Da Silva, Mercês; Stefani, Pablo Marcelo; et al.; Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization; Elsevier; Polymer Testing; 32; 4; 21-3-2013; 665-672
0142-9418
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymertesting.2013.03.010
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0142941813000500
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614069904998400
score 13.070432

Publicaciones similares