Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates

Autores
Tomba, Juan Pablo; Pastor, José M.
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We present a simple approach that avoids the problem of coupling fluid-sample interaction in confocal Raman depth-profiling with immersion objectives. We use a thin protective medium (polyethylene film) that preserves the sample from direct contact with the coupling fluid, and that can be readily attached/de-attached from the sample surface by applying a small difference of pressure. The strategy was tested performing confocal Raman depth profiling studies on a series of transparent substrates (polypropylene films; 25, 44 and 60 m nominal thickness) and comparing the results with those obtained with conventional approaches. It is shown that the strategy recovers very well all the film features, preserving at the same time a good depth resolution and optical throughput. 
Fil: Tomba, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pastor, José M.. Universidad de Valladolid; España
Materia
Confocal Raman
Depth Profiling
Polymer Films
Immersion Objectives
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66218

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network_name_str CONICET Digital (CONICET)
spelling Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer SubstratesTomba, Juan PabloPastor, José M.Confocal RamanDepth ProfilingPolymer FilmsImmersion Objectiveshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2We present a simple approach that avoids the problem of coupling fluid-sample interaction in confocal Raman depth-profiling with immersion objectives. We use a thin protective medium (polyethylene film) that preserves the sample from direct contact with the coupling fluid, and that can be readily attached/de-attached from the sample surface by applying a small difference of pressure. The strategy was tested performing confocal Raman depth profiling studies on a series of transparent substrates (polypropylene films; 25, 44 and 60 m nominal thickness) and comparing the results with those obtained with conventional approaches. It is shown that the strategy recovers very well all the film features, preserving at the same time a good depth resolution and optical throughput. Fil: Tomba, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Pastor, José M.. Universidad de Valladolid; EspañaWiley VCH Verlag2009-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66218Tomba, Juan Pablo; Pastor, José M.; Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 210; 7; 4-2009; 549-5541022-1352CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/macp.200800582info:eu-repo/semantics/altIdentifier/doi/10.1002/macp.200800582info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:02:48Zoai:ri.conicet.gov.ar:11336/66218instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:02:49.179CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
title Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
spellingShingle Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
Tomba, Juan Pablo
Confocal Raman
Depth Profiling
Polymer Films
Immersion Objectives
title_short Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
title_full Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
title_fullStr Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
title_full_unstemmed Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
title_sort Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates
dc.creator.none.fl_str_mv Tomba, Juan Pablo
Pastor, José M.
author Tomba, Juan Pablo
author_facet Tomba, Juan Pablo
Pastor, José M.
author_role author
author2 Pastor, José M.
author2_role author
dc.subject.none.fl_str_mv Confocal Raman
Depth Profiling
Polymer Films
Immersion Objectives
topic Confocal Raman
Depth Profiling
Polymer Films
Immersion Objectives
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv We present a simple approach that avoids the problem of coupling fluid-sample interaction in confocal Raman depth-profiling with immersion objectives. We use a thin protective medium (polyethylene film) that preserves the sample from direct contact with the coupling fluid, and that can be readily attached/de-attached from the sample surface by applying a small difference of pressure. The strategy was tested performing confocal Raman depth profiling studies on a series of transparent substrates (polypropylene films; 25, 44 and 60 m nominal thickness) and comparing the results with those obtained with conventional approaches. It is shown that the strategy recovers very well all the film features, preserving at the same time a good depth resolution and optical throughput. 
Fil: Tomba, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pastor, José M.. Universidad de Valladolid; España
description We present a simple approach that avoids the problem of coupling fluid-sample interaction in confocal Raman depth-profiling with immersion objectives. We use a thin protective medium (polyethylene film) that preserves the sample from direct contact with the coupling fluid, and that can be readily attached/de-attached from the sample surface by applying a small difference of pressure. The strategy was tested performing confocal Raman depth profiling studies on a series of transparent substrates (polypropylene films; 25, 44 and 60 m nominal thickness) and comparing the results with those obtained with conventional approaches. It is shown that the strategy recovers very well all the film features, preserving at the same time a good depth resolution and optical throughput. 
publishDate 2009
dc.date.none.fl_str_mv 2009-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66218
Tomba, Juan Pablo; Pastor, José M.; Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 210; 7; 4-2009; 549-554
1022-1352
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66218
identifier_str_mv Tomba, Juan Pablo; Pastor, José M.; Confocal Raman Microspectroscopy: A Non-Invasive Approach for in-Depth Analyses of Polymer Substrates; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 210; 7; 4-2009; 549-554
1022-1352
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/macp.200800582
info:eu-repo/semantics/altIdentifier/doi/10.1002/macp.200800582
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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