Solubility of two stable iminium salts in 12 polar solvents
- Autores
- Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.
- Año de publicación
- 2002
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.
Fil: Grande, Maria del Carmen. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Barrero, Carmen Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Marschoff, Carlos Miguel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina
Fil: Rodriguez, Juan Bautista. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Gros, Eduardo G.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina - Materia
-
Properties of iminium salts
Solubility data
Thermodynamic quantities - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/85792
Ver los metadatos del registro completo
id |
CONICETDig_b8e4ca23bfcc4d39bb3d5bf88fabb7f4 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/85792 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Solubility of two stable iminium salts in 12 polar solventsGrande, Maria del CarmenBarrero, Carmen RaquelMarschoff, Carlos MiguelRodriguez, Juan BautistaGros, Eduardo G.Properties of iminium saltsSolubility dataThermodynamic quantitieshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.Fil: Grande, Maria del Carmen. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; ArgentinaFil: Barrero, Carmen Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; ArgentinaFil: Marschoff, Carlos Miguel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; ArgentinaFil: Rodriguez, Juan Bautista. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaFil: Gros, Eduardo G.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaAmerican Chemical Society2002-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/85792Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.; Solubility of two stable iminium salts in 12 polar solvents; American Chemical Society; Journal of Chemical and Engineering Data; 47; 6; 11-2002; 1337-13380021-9568CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/je010263oinfo:eu-repo/semantics/altIdentifier/doi/10.1021/je010263oinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:39:45Zoai:ri.conicet.gov.ar:11336/85792instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:39:45.627CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Solubility of two stable iminium salts in 12 polar solvents |
title |
Solubility of two stable iminium salts in 12 polar solvents |
spellingShingle |
Solubility of two stable iminium salts in 12 polar solvents Grande, Maria del Carmen Properties of iminium salts Solubility data Thermodynamic quantities |
title_short |
Solubility of two stable iminium salts in 12 polar solvents |
title_full |
Solubility of two stable iminium salts in 12 polar solvents |
title_fullStr |
Solubility of two stable iminium salts in 12 polar solvents |
title_full_unstemmed |
Solubility of two stable iminium salts in 12 polar solvents |
title_sort |
Solubility of two stable iminium salts in 12 polar solvents |
dc.creator.none.fl_str_mv |
Grande, Maria del Carmen Barrero, Carmen Raquel Marschoff, Carlos Miguel Rodriguez, Juan Bautista Gros, Eduardo G. |
author |
Grande, Maria del Carmen |
author_facet |
Grande, Maria del Carmen Barrero, Carmen Raquel Marschoff, Carlos Miguel Rodriguez, Juan Bautista Gros, Eduardo G. |
author_role |
author |
author2 |
Barrero, Carmen Raquel Marschoff, Carlos Miguel Rodriguez, Juan Bautista Gros, Eduardo G. |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Properties of iminium salts Solubility data Thermodynamic quantities |
topic |
Properties of iminium salts Solubility data Thermodynamic quantities |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated. Fil: Grande, Maria del Carmen. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina Fil: Barrero, Carmen Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina Fil: Marschoff, Carlos Miguel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina Fil: Rodriguez, Juan Bautista. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina Fil: Gros, Eduardo G.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina |
description |
Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-11 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/85792 Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.; Solubility of two stable iminium salts in 12 polar solvents; American Chemical Society; Journal of Chemical and Engineering Data; 47; 6; 11-2002; 1337-1338 0021-9568 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/85792 |
identifier_str_mv |
Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.; Solubility of two stable iminium salts in 12 polar solvents; American Chemical Society; Journal of Chemical and Engineering Data; 47; 6; 11-2002; 1337-1338 0021-9568 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/je010263o info:eu-repo/semantics/altIdentifier/doi/10.1021/je010263o |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614423609606144 |
score |
13.070432 |