Solubility of two stable iminium salts in 12 polar solvents

Autores
Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.
Fil: Grande, Maria del Carmen. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Barrero, Carmen Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Marschoff, Carlos Miguel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina
Fil: Rodriguez, Juan Bautista. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Gros, Eduardo G.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Materia
Properties of iminium salts
Solubility data
Thermodynamic quantities
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/85792
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Solubility of two stable iminium salts in 12 polar solventsGrande, Maria del CarmenBarrero, Carmen RaquelMarschoff, Carlos MiguelRodriguez, Juan BautistaGros, Eduardo G.Properties of iminium saltsSolubility dataThermodynamic quantitieshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.Fil: Grande, Maria del Carmen. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; ArgentinaFil: Barrero, Carmen Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; ArgentinaFil: Marschoff, Carlos Miguel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; ArgentinaFil: Rodriguez, Juan Bautista. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaFil: Gros, Eduardo G.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; ArgentinaAmerican Chemical Society2002-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/85792Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.; Solubility of two stable iminium salts in 12 polar solvents; American Chemical Society; Journal of Chemical and Engineering Data; 47; 6; 11-2002; 1337-13380021-9568CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/je010263oinfo:eu-repo/semantics/altIdentifier/doi/10.1021/je010263oinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:37:26Zoai:ri.conicet.gov.ar:11336/85792instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:37:27.076CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Solubility of two stable iminium salts in 12 polar solvents
title Solubility of two stable iminium salts in 12 polar solvents
spellingShingle Solubility of two stable iminium salts in 12 polar solvents
Grande, Maria del Carmen
Properties of iminium salts
Solubility data
Thermodynamic quantities
title_short Solubility of two stable iminium salts in 12 polar solvents
title_full Solubility of two stable iminium salts in 12 polar solvents
title_fullStr Solubility of two stable iminium salts in 12 polar solvents
title_full_unstemmed Solubility of two stable iminium salts in 12 polar solvents
title_sort Solubility of two stable iminium salts in 12 polar solvents
dc.creator.none.fl_str_mv Grande, Maria del Carmen
Barrero, Carmen Raquel
Marschoff, Carlos Miguel
Rodriguez, Juan Bautista
Gros, Eduardo G.
author Grande, Maria del Carmen
author_facet Grande, Maria del Carmen
Barrero, Carmen Raquel
Marschoff, Carlos Miguel
Rodriguez, Juan Bautista
Gros, Eduardo G.
author_role author
author2 Barrero, Carmen Raquel
Marschoff, Carlos Miguel
Rodriguez, Juan Bautista
Gros, Eduardo G.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Properties of iminium salts
Solubility data
Thermodynamic quantities
topic Properties of iminium salts
Solubility data
Thermodynamic quantities
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.
Fil: Grande, Maria del Carmen. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Barrero, Carmen Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química; Argentina
Fil: Marschoff, Carlos Miguel. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina
Fil: Rodriguez, Juan Bautista. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
Fil: Gros, Eduardo G.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica; Argentina
description Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.
publishDate 2002
dc.date.none.fl_str_mv 2002-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/85792
Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.; Solubility of two stable iminium salts in 12 polar solvents; American Chemical Society; Journal of Chemical and Engineering Data; 47; 6; 11-2002; 1337-1338
0021-9568
CONICET Digital
CONICET
url http://hdl.handle.net/11336/85792
identifier_str_mv Grande, Maria del Carmen; Barrero, Carmen Raquel; Marschoff, Carlos Miguel; Rodriguez, Juan Bautista; Gros, Eduardo G.; Solubility of two stable iminium salts in 12 polar solvents; American Chemical Society; Journal of Chemical and Engineering Data; 47; 6; 11-2002; 1337-1338
0021-9568
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/je010263o
info:eu-repo/semantics/altIdentifier/doi/10.1021/je010263o
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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