Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)
- Autores
- Dennehy, Mariana; Quinzani, Oscar V.; Mandolesi, Sandra D.; Güida, Jorge Alberto; Echeverría, Gustavo Alberto; Piro, Oscar Enrique
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- We report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P2₁/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed.
Centro de Química Inorgánica
Instituto de Física La Plata - Materia
-
Física
Química
Thiosaccharin
Bis(triphenylphosphine)iminium
IR spectroscopy
NMR spectroscopy
X-Ray structure determination - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/146350
Ver los metadatos del registro completo
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Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac)Dennehy, MarianaQuinzani, Oscar V.Mandolesi, Sandra D.Güida, Jorge AlbertoEcheverría, Gustavo AlbertoPiro, Oscar EnriqueFísicaQuímicaThiosaccharinBis(triphenylphosphine)iminiumIR spectroscopyNMR spectroscopyX-Ray structure determinationWe report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P2₁/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed.Centro de Química InorgánicaInstituto de Física La Plata2007-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf669-675http://sedici.unlp.edu.ar/handle/10915/146350enginfo:eu-repo/semantics/altIdentifier/issn/0026-9247info:eu-repo/semantics/altIdentifier/issn/1434-4475info:eu-repo/semantics/altIdentifier/issn/0343-7329info:eu-repo/semantics/altIdentifier/doi/10.1007/s00706-007-0648-8info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:13:21Zoai:sedici.unlp.edu.ar:10915/146350Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:13:21.351SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) |
| title |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) |
| spellingShingle |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) Dennehy, Mariana Física Química Thiosaccharin Bis(triphenylphosphine)iminium IR spectroscopy NMR spectroscopy X-Ray structure determination |
| title_short |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) |
| title_full |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) |
| title_fullStr |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) |
| title_full_unstemmed |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) |
| title_sort |
Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts : Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) |
| dc.creator.none.fl_str_mv |
Dennehy, Mariana Quinzani, Oscar V. Mandolesi, Sandra D. Güida, Jorge Alberto Echeverría, Gustavo Alberto Piro, Oscar Enrique |
| author |
Dennehy, Mariana |
| author_facet |
Dennehy, Mariana Quinzani, Oscar V. Mandolesi, Sandra D. Güida, Jorge Alberto Echeverría, Gustavo Alberto Piro, Oscar Enrique |
| author_role |
author |
| author2 |
Quinzani, Oscar V. Mandolesi, Sandra D. Güida, Jorge Alberto Echeverría, Gustavo Alberto Piro, Oscar Enrique |
| author2_role |
author author author author author |
| dc.subject.none.fl_str_mv |
Física Química Thiosaccharin Bis(triphenylphosphine)iminium IR spectroscopy NMR spectroscopy X-Ray structure determination |
| topic |
Física Química Thiosaccharin Bis(triphenylphosphine)iminium IR spectroscopy NMR spectroscopy X-Ray structure determination |
| dc.description.none.fl_txt_mv |
We report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P2₁/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed. Centro de Química Inorgánica Instituto de Física La Plata |
| description |
We report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P2₁/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed. |
| publishDate |
2007 |
| dc.date.none.fl_str_mv |
2007-07 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/146350 |
| url |
http://sedici.unlp.edu.ar/handle/10915/146350 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
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openAccess |
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http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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application/pdf 669-675 |
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