Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification

Autores
Lencina, Alberto Germán; Romagnoli, Gustavo Alberto; Alonso, Andrea; Ramos, N.; D´Angelo, C.; Lett, Lina Analía Carola; Mestelan, Silvia
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Purpose Agronomic and environmental reasons force farmers to know the total P concentration of composted cattle manure. Laser-Induced Breakdown Spectroscopy seems proper to obtain such information. For logistic reasons (carriage, storage, field application, etc.), a dry matter characterization is also needed. Method Thirty samples of feedlot compost at different stages of stability and maturity were studied. Samples were dried at 50°C for dry matter characterization. As a reference method to determine total P concentration, wet digestion and colorimetry were employed. The area of the P I line emission obtained by laser-induced ablation of the samples was measured to estimate the total P concentration. Randomized calibrations through a modified version of the Kennard-Stone algorithm based on the Mahalanobis distance were performed. Results Dry matter varied from 40% to 90%, and no pattern was found related to compost origin, maturity, or stability. The total P concentration of the studied compost ranged from 1800 ppm up to 11200 ppm. Almost 80% of the calibration fittings have an R2 ≥ 0.895. The mean validation error was less than 22% for about 80% of the calibrations, with a mean prediction error bound to 40%. Discarding outliers, the errors were reduced to 19% and 30%, respectively. Conclusion Water content must be considered in addition to other characterizations due to logistic implications. Calibrations with a 30 percent of prediction error were achieved, which seems enough as a first approximation to predict the total P content in compost for utilization in farms to recycle nutrients.
Fil: Lencina, Alberto Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
Fil: Romagnoli, Gustavo Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
Fil: Alonso, Andrea. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
Fil: Ramos, N.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina
Fil: D´Angelo, C.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física Arroyo Seco; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Lett, Lina Analía Carola. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía; Argentina
Fil: Mestelan, Silvia. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
Materia
FEEDLOT COMPOST
LASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS)
NUTRIENT RECYCLING
TOTAL PHOSPHORUS CONCENTRATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/216992
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/216992
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantificationLencina, Alberto GermánRomagnoli, Gustavo AlbertoAlonso, AndreaRamos, N.D´Angelo, C.Lett, Lina Analía CarolaMestelan, SilviaFEEDLOT COMPOSTLASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS)NUTRIENT RECYCLINGTOTAL PHOSPHORUS CONCENTRATIONhttps://purl.org/becyt/ford/4.1https://purl.org/becyt/ford/4https://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Purpose Agronomic and environmental reasons force farmers to know the total P concentration of composted cattle manure. Laser-Induced Breakdown Spectroscopy seems proper to obtain such information. For logistic reasons (carriage, storage, field application, etc.), a dry matter characterization is also needed. Method Thirty samples of feedlot compost at different stages of stability and maturity were studied. Samples were dried at 50°C for dry matter characterization. As a reference method to determine total P concentration, wet digestion and colorimetry were employed. The area of the P I line emission obtained by laser-induced ablation of the samples was measured to estimate the total P concentration. Randomized calibrations through a modified version of the Kennard-Stone algorithm based on the Mahalanobis distance were performed. Results Dry matter varied from 40% to 90%, and no pattern was found related to compost origin, maturity, or stability. The total P concentration of the studied compost ranged from 1800 ppm up to 11200 ppm. Almost 80% of the calibration fittings have an R2 ≥ 0.895. The mean validation error was less than 22% for about 80% of the calibrations, with a mean prediction error bound to 40%. Discarding outliers, the errors were reduced to 19% and 30%, respectively. Conclusion Water content must be considered in addition to other characterizations due to logistic implications. Calibrations with a 30 percent of prediction error were achieved, which seems enough as a first approximation to predict the total P content in compost for utilization in farms to recycle nutrients.Fil: Lencina, Alberto Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; ArgentinaFil: Romagnoli, Gustavo Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; ArgentinaFil: Alonso, Andrea. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; ArgentinaFil: Ramos, N.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; ArgentinaFil: D´Angelo, C.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física Arroyo Seco; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; ArgentinaFil: Lett, Lina Analía Carola. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía; ArgentinaFil: Mestelan, Silvia. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; ArgentinaIslamic Azad University2022-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/216992Lencina, Alberto Germán; Romagnoli, Gustavo Alberto; Alonso, Andrea; Ramos, N.; D´Angelo, C.; et al.; Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification; Islamic Azad University; International Journal of Recycling of Organic Waste in Agriculture; 11; 3; 6-2022; 319-3322195-32282251-7715CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://ijrowa.khuisf.ac.ir/article_685629.htmlinfo:eu-repo/semantics/altIdentifier/doi/10.30486/ijrowa.2021.1917918.1178info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:19:41Zoai:ri.conicet.gov.ar:11336/216992instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:19:41.623CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
title Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
spellingShingle Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
Lencina, Alberto Germán
FEEDLOT COMPOST
LASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS)
NUTRIENT RECYCLING
TOTAL PHOSPHORUS CONCENTRATION
title_short Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
title_full Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
title_fullStr Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
title_full_unstemmed Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
title_sort Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification
dc.creator.none.fl_str_mv Lencina, Alberto Germán
Romagnoli, Gustavo Alberto
Alonso, Andrea
Ramos, N.
D´Angelo, C.
Lett, Lina Analía Carola
Mestelan, Silvia
author Lencina, Alberto Germán
author_facet Lencina, Alberto Germán
Romagnoli, Gustavo Alberto
Alonso, Andrea
Ramos, N.
D´Angelo, C.
Lett, Lina Analía Carola
Mestelan, Silvia
author_role author
author2 Romagnoli, Gustavo Alberto
Alonso, Andrea
Ramos, N.
D´Angelo, C.
Lett, Lina Analía Carola
Mestelan, Silvia
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv FEEDLOT COMPOST
LASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS)
NUTRIENT RECYCLING
TOTAL PHOSPHORUS CONCENTRATION
topic FEEDLOT COMPOST
LASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS)
NUTRIENT RECYCLING
TOTAL PHOSPHORUS CONCENTRATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/4.1
https://purl.org/becyt/ford/4
https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Purpose Agronomic and environmental reasons force farmers to know the total P concentration of composted cattle manure. Laser-Induced Breakdown Spectroscopy seems proper to obtain such information. For logistic reasons (carriage, storage, field application, etc.), a dry matter characterization is also needed. Method Thirty samples of feedlot compost at different stages of stability and maturity were studied. Samples were dried at 50°C for dry matter characterization. As a reference method to determine total P concentration, wet digestion and colorimetry were employed. The area of the P I line emission obtained by laser-induced ablation of the samples was measured to estimate the total P concentration. Randomized calibrations through a modified version of the Kennard-Stone algorithm based on the Mahalanobis distance were performed. Results Dry matter varied from 40% to 90%, and no pattern was found related to compost origin, maturity, or stability. The total P concentration of the studied compost ranged from 1800 ppm up to 11200 ppm. Almost 80% of the calibration fittings have an R2 ≥ 0.895. The mean validation error was less than 22% for about 80% of the calibrations, with a mean prediction error bound to 40%. Discarding outliers, the errors were reduced to 19% and 30%, respectively. Conclusion Water content must be considered in addition to other characterizations due to logistic implications. Calibrations with a 30 percent of prediction error were achieved, which seems enough as a first approximation to predict the total P content in compost for utilization in farms to recycle nutrients.
Fil: Lencina, Alberto Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tandil; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
Fil: Romagnoli, Gustavo Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
Fil: Alonso, Andrea. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
Fil: Ramos, N.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina
Fil: D´Angelo, C.. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física Arroyo Seco; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Lett, Lina Analía Carola. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía; Argentina
Fil: Mestelan, Silvia. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Centro Regional de Estudios Sistémico de Cadenas Agroalimentarias; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Agronomía. Laboratorio de Análisis de Suelos; Argentina
description Purpose Agronomic and environmental reasons force farmers to know the total P concentration of composted cattle manure. Laser-Induced Breakdown Spectroscopy seems proper to obtain such information. For logistic reasons (carriage, storage, field application, etc.), a dry matter characterization is also needed. Method Thirty samples of feedlot compost at different stages of stability and maturity were studied. Samples were dried at 50°C for dry matter characterization. As a reference method to determine total P concentration, wet digestion and colorimetry were employed. The area of the P I line emission obtained by laser-induced ablation of the samples was measured to estimate the total P concentration. Randomized calibrations through a modified version of the Kennard-Stone algorithm based on the Mahalanobis distance were performed. Results Dry matter varied from 40% to 90%, and no pattern was found related to compost origin, maturity, or stability. The total P concentration of the studied compost ranged from 1800 ppm up to 11200 ppm. Almost 80% of the calibration fittings have an R2 ≥ 0.895. The mean validation error was less than 22% for about 80% of the calibrations, with a mean prediction error bound to 40%. Discarding outliers, the errors were reduced to 19% and 30%, respectively. Conclusion Water content must be considered in addition to other characterizations due to logistic implications. Calibrations with a 30 percent of prediction error were achieved, which seems enough as a first approximation to predict the total P content in compost for utilization in farms to recycle nutrients.
publishDate 2022
dc.date.none.fl_str_mv 2022-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/216992
Lencina, Alberto Germán; Romagnoli, Gustavo Alberto; Alonso, Andrea; Ramos, N.; D´Angelo, C.; et al.; Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification; Islamic Azad University; International Journal of Recycling of Organic Waste in Agriculture; 11; 3; 6-2022; 319-332
2195-3228
2251-7715
CONICET Digital
CONICET
url http://hdl.handle.net/11336/216992
identifier_str_mv Lencina, Alberto Germán; Romagnoli, Gustavo Alberto; Alonso, Andrea; Ramos, N.; D´Angelo, C.; et al.; Laser-induced breakdown spectroscopy applied to cattle compost for phosphorus quantification; Islamic Azad University; International Journal of Recycling of Organic Waste in Agriculture; 11; 3; 6-2022; 319-332
2195-3228
2251-7715
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://ijrowa.khuisf.ac.ir/article_685629.html
info:eu-repo/semantics/altIdentifier/doi/10.30486/ijrowa.2021.1917918.1178
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Islamic Azad University
publisher.none.fl_str_mv Islamic Azad University
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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