Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles
- Autores
- Meiorin, Cintia; Muraca, Diego; Pirota, Kleber R.; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The direct reaction of unmodified tung oil and styrene initiated by boron trifluoride diethyl etherate allowed obtaining thermoset polymers with valuable properties like shape memory behavior. On the other hand, the addition of magnetite nanoparticles (MNPs) to the tung oil/styrene copolymer was considered, in order to improve/modify its properties. MNPs were synthesized by the method of alkaline coprecipitation, followed by coating with oleic acid in order to hydrophobize their surfaces and make them more compatible with the polymeric matrix. Thus, superparamagnetic polymer nanocomposites were prepared from the inclusion of the MNPs to the cationically copolymerized tung oil (TO) and styrene (St) networks. The morphology, dynamic–mechanical and mechanical properties of the copolymers as well as magnetic behavior were significantly affected by the variation of the concentration of the MNPs.
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Muraca, Diego. Universidade Estadual de Campinas; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pirota, Kleber R.. Universidade Estadual de Campinas; Brasil
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
VEGETABLE OIL
NANOCOMPOSITES
MAGNETITE NANOPARTICLES
MAGNETIC PROPERTIES
SHAPE MEMORY PROPERTIES - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/102503
Ver los metadatos del registro completo
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Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticlesMeiorin, CintiaMuraca, DiegoPirota, Kleber R.Aranguren, Mirta InesMosiewicki, Mirna AlejandraVEGETABLE OILNANOCOMPOSITESMAGNETITE NANOPARTICLESMAGNETIC PROPERTIESSHAPE MEMORY PROPERTIEShttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2The direct reaction of unmodified tung oil and styrene initiated by boron trifluoride diethyl etherate allowed obtaining thermoset polymers with valuable properties like shape memory behavior. On the other hand, the addition of magnetite nanoparticles (MNPs) to the tung oil/styrene copolymer was considered, in order to improve/modify its properties. MNPs were synthesized by the method of alkaline coprecipitation, followed by coating with oleic acid in order to hydrophobize their surfaces and make them more compatible with the polymeric matrix. Thus, superparamagnetic polymer nanocomposites were prepared from the inclusion of the MNPs to the cationically copolymerized tung oil (TO) and styrene (St) networks. The morphology, dynamic–mechanical and mechanical properties of the copolymers as well as magnetic behavior were significantly affected by the variation of the concentration of the MNPs.Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Muraca, Diego. Universidade Estadual de Campinas; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pirota, Kleber R.. Universidade Estadual de Campinas; BrasilFil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaPergamon-Elsevier Science Ltd2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/102503Meiorin, Cintia; Muraca, Diego; Pirota, Kleber R.; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 53; 1; 1-2014; 90-990014-3057CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2014.01.018info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0014305714000287info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:42:07Zoai:ri.conicet.gov.ar:11336/102503instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:42:07.485CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles |
title |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles |
spellingShingle |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles Meiorin, Cintia VEGETABLE OIL NANOCOMPOSITES MAGNETITE NANOPARTICLES MAGNETIC PROPERTIES SHAPE MEMORY PROPERTIES |
title_short |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles |
title_full |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles |
title_fullStr |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles |
title_full_unstemmed |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles |
title_sort |
Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles |
dc.creator.none.fl_str_mv |
Meiorin, Cintia Muraca, Diego Pirota, Kleber R. Aranguren, Mirta Ines Mosiewicki, Mirna Alejandra |
author |
Meiorin, Cintia |
author_facet |
Meiorin, Cintia Muraca, Diego Pirota, Kleber R. Aranguren, Mirta Ines Mosiewicki, Mirna Alejandra |
author_role |
author |
author2 |
Muraca, Diego Pirota, Kleber R. Aranguren, Mirta Ines Mosiewicki, Mirna Alejandra |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
VEGETABLE OIL NANOCOMPOSITES MAGNETITE NANOPARTICLES MAGNETIC PROPERTIES SHAPE MEMORY PROPERTIES |
topic |
VEGETABLE OIL NANOCOMPOSITES MAGNETITE NANOPARTICLES MAGNETIC PROPERTIES SHAPE MEMORY PROPERTIES |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The direct reaction of unmodified tung oil and styrene initiated by boron trifluoride diethyl etherate allowed obtaining thermoset polymers with valuable properties like shape memory behavior. On the other hand, the addition of magnetite nanoparticles (MNPs) to the tung oil/styrene copolymer was considered, in order to improve/modify its properties. MNPs were synthesized by the method of alkaline coprecipitation, followed by coating with oleic acid in order to hydrophobize their surfaces and make them more compatible with the polymeric matrix. Thus, superparamagnetic polymer nanocomposites were prepared from the inclusion of the MNPs to the cationically copolymerized tung oil (TO) and styrene (St) networks. The morphology, dynamic–mechanical and mechanical properties of the copolymers as well as magnetic behavior were significantly affected by the variation of the concentration of the MNPs. Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Muraca, Diego. Universidade Estadual de Campinas; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Pirota, Kleber R.. Universidade Estadual de Campinas; Brasil Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
The direct reaction of unmodified tung oil and styrene initiated by boron trifluoride diethyl etherate allowed obtaining thermoset polymers with valuable properties like shape memory behavior. On the other hand, the addition of magnetite nanoparticles (MNPs) to the tung oil/styrene copolymer was considered, in order to improve/modify its properties. MNPs were synthesized by the method of alkaline coprecipitation, followed by coating with oleic acid in order to hydrophobize their surfaces and make them more compatible with the polymeric matrix. Thus, superparamagnetic polymer nanocomposites were prepared from the inclusion of the MNPs to the cationically copolymerized tung oil (TO) and styrene (St) networks. The morphology, dynamic–mechanical and mechanical properties of the copolymers as well as magnetic behavior were significantly affected by the variation of the concentration of the MNPs. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/102503 Meiorin, Cintia; Muraca, Diego; Pirota, Kleber R.; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 53; 1; 1-2014; 90-99 0014-3057 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/102503 |
identifier_str_mv |
Meiorin, Cintia; Muraca, Diego; Pirota, Kleber R.; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles; Pergamon-Elsevier Science Ltd; European Polymer Journal; 53; 1; 1-2014; 90-99 0014-3057 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2014.01.018 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0014305714000287 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613327532064768 |
score |
13.070432 |