Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds

Autores
Fanovich, Maria Alejandra; Jaeger, P.
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work different phenomena related to sorption of carbon dioxide in polycaprolactone (PCL) have been investigated systematically. The use of compressed carbon dioxide is discussed for obtaining porous scaffolds from this biocompatible polymer. In order to determine the plasticization effect of carbon dioxide on the degree of foaming it is necessary to discuss sorption data with respect to morphological features of the polymer at conditions nearby the melting point. The amount of carbon dioxide dissolved and the kinetics of the sorption process are found to depend strongly on temperature and pressure. The solubility takes values of up to 25 wt.% being favoured by a melting and glass transition temperature depression which can be observed along with an enhanced mass transfer rate. In general, CO2 sorption in PCL increases linearly with pressure. When decompressing, microfoaming occurs which enhances the rate of gas release. Changes in morphology and crystallinity occur as a consequence of the pressure treatment. Compared to the melting temperature at atmospheric pressure there is a dramatic reduction observed under pressure where melting occurs already at a temperature below 40 °C. Even after pressure-treatment, there is a remaining change in melting temperature and crystallinity observed. Optimum conditions for obtaining adequate porous scaffolds of PCL are a relatively slow decompression after treatment at 17 MPa and 35 °C.
Fil: Fanovich, Maria Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Jaeger, P.. Hamburg University of Technology; Alemania
Materia
Polycaprolactone
Supercritical Carbon Dioxide
Porous Scaffolds
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6297
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/6297
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffoldsFanovich, Maria AlejandraJaeger, P.PolycaprolactoneSupercritical Carbon DioxidePorous Scaffoldshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work different phenomena related to sorption of carbon dioxide in polycaprolactone (PCL) have been investigated systematically. The use of compressed carbon dioxide is discussed for obtaining porous scaffolds from this biocompatible polymer. In order to determine the plasticization effect of carbon dioxide on the degree of foaming it is necessary to discuss sorption data with respect to morphological features of the polymer at conditions nearby the melting point. The amount of carbon dioxide dissolved and the kinetics of the sorption process are found to depend strongly on temperature and pressure. The solubility takes values of up to 25 wt.% being favoured by a melting and glass transition temperature depression which can be observed along with an enhanced mass transfer rate. In general, CO2 sorption in PCL increases linearly with pressure. When decompressing, microfoaming occurs which enhances the rate of gas release. Changes in morphology and crystallinity occur as a consequence of the pressure treatment. Compared to the melting temperature at atmospheric pressure there is a dramatic reduction observed under pressure where melting occurs already at a temperature below 40 °C. Even after pressure-treatment, there is a remaining change in melting temperature and crystallinity observed. Optimum conditions for obtaining adequate porous scaffolds of PCL are a relatively slow decompression after treatment at 17 MPa and 35 °C.Fil: Fanovich, Maria Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Jaeger, P.. Hamburg University of Technology; AlemaniaElsevier2012-02-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6297Fanovich, Maria Alejandra; Jaeger, P.; Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds; Elsevier; Materials Science & Engineering. C, Biomimetic Materials, Sensors And Systems; 32; 4; 9-2-2012; 961-9680928-4931enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0928493112000732info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1016/j.msec.2012.02.021info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:04Zoai:ri.conicet.gov.ar:11336/6297instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:04.835CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
title Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
spellingShingle Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
Fanovich, Maria Alejandra
Polycaprolactone
Supercritical Carbon Dioxide
Porous Scaffolds
title_short Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
title_full Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
title_fullStr Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
title_full_unstemmed Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
title_sort Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds
dc.creator.none.fl_str_mv Fanovich, Maria Alejandra
Jaeger, P.
author Fanovich, Maria Alejandra
author_facet Fanovich, Maria Alejandra
Jaeger, P.
author_role author
author2 Jaeger, P.
author2_role author
dc.subject.none.fl_str_mv Polycaprolactone
Supercritical Carbon Dioxide
Porous Scaffolds
topic Polycaprolactone
Supercritical Carbon Dioxide
Porous Scaffolds
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work different phenomena related to sorption of carbon dioxide in polycaprolactone (PCL) have been investigated systematically. The use of compressed carbon dioxide is discussed for obtaining porous scaffolds from this biocompatible polymer. In order to determine the plasticization effect of carbon dioxide on the degree of foaming it is necessary to discuss sorption data with respect to morphological features of the polymer at conditions nearby the melting point. The amount of carbon dioxide dissolved and the kinetics of the sorption process are found to depend strongly on temperature and pressure. The solubility takes values of up to 25 wt.% being favoured by a melting and glass transition temperature depression which can be observed along with an enhanced mass transfer rate. In general, CO2 sorption in PCL increases linearly with pressure. When decompressing, microfoaming occurs which enhances the rate of gas release. Changes in morphology and crystallinity occur as a consequence of the pressure treatment. Compared to the melting temperature at atmospheric pressure there is a dramatic reduction observed under pressure where melting occurs already at a temperature below 40 °C. Even after pressure-treatment, there is a remaining change in melting temperature and crystallinity observed. Optimum conditions for obtaining adequate porous scaffolds of PCL are a relatively slow decompression after treatment at 17 MPa and 35 °C.
Fil: Fanovich, Maria Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Jaeger, P.. Hamburg University of Technology; Alemania
description In this work different phenomena related to sorption of carbon dioxide in polycaprolactone (PCL) have been investigated systematically. The use of compressed carbon dioxide is discussed for obtaining porous scaffolds from this biocompatible polymer. In order to determine the plasticization effect of carbon dioxide on the degree of foaming it is necessary to discuss sorption data with respect to morphological features of the polymer at conditions nearby the melting point. The amount of carbon dioxide dissolved and the kinetics of the sorption process are found to depend strongly on temperature and pressure. The solubility takes values of up to 25 wt.% being favoured by a melting and glass transition temperature depression which can be observed along with an enhanced mass transfer rate. In general, CO2 sorption in PCL increases linearly with pressure. When decompressing, microfoaming occurs which enhances the rate of gas release. Changes in morphology and crystallinity occur as a consequence of the pressure treatment. Compared to the melting temperature at atmospheric pressure there is a dramatic reduction observed under pressure where melting occurs already at a temperature below 40 °C. Even after pressure-treatment, there is a remaining change in melting temperature and crystallinity observed. Optimum conditions for obtaining adequate porous scaffolds of PCL are a relatively slow decompression after treatment at 17 MPa and 35 °C.
publishDate 2012
dc.date.none.fl_str_mv 2012-02-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6297
Fanovich, Maria Alejandra; Jaeger, P.; Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds; Elsevier; Materials Science & Engineering. C, Biomimetic Materials, Sensors And Systems; 32; 4; 9-2-2012; 961-968
0928-4931
url http://hdl.handle.net/11336/6297
identifier_str_mv Fanovich, Maria Alejandra; Jaeger, P.; Sorption and diffusion of compressed carbon dioxide in polycaprolactone for the development of porous scaffolds; Elsevier; Materials Science & Engineering. C, Biomimetic Materials, Sensors And Systems; 32; 4; 9-2-2012; 961-968
0928-4931
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0928493112000732
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.msec.2012.02.021
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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