Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films

Autores
Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns.
Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina. Instituto Nacional de Tecnologia Industrial; Argentina
Fil: Petroselli, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina
Fil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina
Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina
Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos Aplicados A la Química Orgánica (i); Argentina
Materia
Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/7419
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/7419
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone filmsMonsalve, Leandro NicolasPetroselli, GabrielaErra Balsells, RosaVazquez, AnaliaBaldessari, AliciaLipaseΒ-PeptoidPolycaprolactoneFilmsSurface Propertieshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns.Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina. Instituto Nacional de Tecnologia Industrial; ArgentinaFil: Petroselli, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; ArgentinaFil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; ArgentinaFil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; ArgentinaFil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos Aplicados A la Química Orgánica (i); ArgentinaElsevier2014-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/7419Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia; Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films; Elsevier; Polymer International; 63; 8; 8-2014; 1523-15301097-0126enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pi.4660/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/pi.4660info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:21Zoai:ri.conicet.gov.ar:11336/7419instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:21.332CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
spellingShingle Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
Monsalve, Leandro Nicolas
Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
title_short Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_full Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_fullStr Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_full_unstemmed Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_sort Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
dc.creator.none.fl_str_mv Monsalve, Leandro Nicolas
Petroselli, Gabriela
Erra Balsells, Rosa
Vazquez, Analia
Baldessari, Alicia
author Monsalve, Leandro Nicolas
author_facet Monsalve, Leandro Nicolas
Petroselli, Gabriela
Erra Balsells, Rosa
Vazquez, Analia
Baldessari, Alicia
author_role author
author2 Petroselli, Gabriela
Erra Balsells, Rosa
Vazquez, Analia
Baldessari, Alicia
author2_role author
author
author
author
dc.subject.none.fl_str_mv Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
topic Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns.
Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina. Instituto Nacional de Tecnologia Industrial; Argentina
Fil: Petroselli, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina
Fil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina
Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina
Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos Aplicados A la Química Orgánica (i); Argentina
description Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns.
publishDate 2014
dc.date.none.fl_str_mv 2014-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/7419
Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia; Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films; Elsevier; Polymer International; 63; 8; 8-2014; 1523-1530
1097-0126
url http://hdl.handle.net/11336/7419
identifier_str_mv Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia; Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films; Elsevier; Polymer International; 63; 8; 8-2014; 1523-1530
1097-0126
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pi.4660/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/pi.4660
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613211825897472
score 13.070432

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