Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis

Autores
Gomez, Germán Ernesto; Onna, Diego Ariel; D'vries, R. F.; Barja, Beatriz Carmen; Ellena, Javier Alcides; Narda, Griselda Edith; Soler Illia, Galo Juan de Avila Arturo
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new uranyl-coordination polymer (UCP) has been solvothermally synthesized employing succinic acid and 1,10-phenanthroline (phen) as ligands. The obtained compound with the formula [(UO2)2(phen)(succ)0.5(OH)(O)4(μ3-O)(H2O)]·H2O (UNSL-1) is classified as 1D chains showing I0O1 connectivity. Also, the asymmetric unit is composed of two hepta-coordinated uranyl centers: U1 is surrounded by five oxygen atoms from succinate, while U2 is surrounded by two nitrogen atoms from phen and three oxygen atoms from succinate ([U1O7] and [U2N2O5]). The secondary-building unit (SBU) is composed of a sharing edge tetrameric cluster linked with a succinate ligand in the [-1 0 1] direction. Besides, the chains are reinforced by π-π stacking interactions between the aromatic rings of the phen molecules to conform a 2D supramolecular arrangement. Moreover, photoluminescence experiments show strong green emission consistent with uranyl crystalline materials. Photophysical characterization was completed via low-temperature measurements (77 K) and recording the decay emission for calculating the lifetime (τobs) value. Regarding its multifunctional properties, a cation-sensing performance was achieved showing selective quenching toward iron ions in aqueous media. Finally, UNSL-1 was tested as an efficient water photocatalyst for dye degradation under simulated sunlight irradiation, exhibiting promising results for organic-pollutant water remediation.
Fil: Gomez, Germán Ernesto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: D'vries, R. F.. Universidad del Cauca; Colombia
Fil: Barja, Beatriz Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Ellena, Javier Alcides. Universidade de Sao Paulo; Brasil
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
URANYL-COORDINATION POLYMER
GREEN LIGHT EMITTER
PHOTOCATALYSIS
DYE DEGRADATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/143943
Acceder
id CONICETDig_8f8e90265f2edbc40cbb0fcbd76aa7cc
oai_identifier_str oai:ri.conicet.gov.ar:11336/143943
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysisGomez, Germán ErnestoOnna, Diego ArielD'vries, R. F.Barja, Beatriz CarmenEllena, Javier AlcidesNarda, Griselda EdithSoler Illia, Galo Juan de Avila ArturoURANYL-COORDINATION POLYMERGREEN LIGHT EMITTERPHOTOCATALYSISDYE DEGRADATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new uranyl-coordination polymer (UCP) has been solvothermally synthesized employing succinic acid and 1,10-phenanthroline (phen) as ligands. The obtained compound with the formula [(UO2)2(phen)(succ)0.5(OH)(O)4(μ3-O)(H2O)]·H2O (UNSL-1) is classified as 1D chains showing I0O1 connectivity. Also, the asymmetric unit is composed of two hepta-coordinated uranyl centers: U1 is surrounded by five oxygen atoms from succinate, while U2 is surrounded by two nitrogen atoms from phen and three oxygen atoms from succinate ([U1O7] and [U2N2O5]). The secondary-building unit (SBU) is composed of a sharing edge tetrameric cluster linked with a succinate ligand in the [-1 0 1] direction. Besides, the chains are reinforced by π-π stacking interactions between the aromatic rings of the phen molecules to conform a 2D supramolecular arrangement. Moreover, photoluminescence experiments show strong green emission consistent with uranyl crystalline materials. Photophysical characterization was completed via low-temperature measurements (77 K) and recording the decay emission for calculating the lifetime (τobs) value. Regarding its multifunctional properties, a cation-sensing performance was achieved showing selective quenching toward iron ions in aqueous media. Finally, UNSL-1 was tested as an efficient water photocatalyst for dye degradation under simulated sunlight irradiation, exhibiting promising results for organic-pollutant water remediation.Fil: Gomez, Germán Ernesto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; ArgentinaFil: D'vries, R. F.. Universidad del Cauca; ColombiaFil: Barja, Beatriz Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Ellena, Javier Alcides. Universidade de Sao Paulo; BrasilFil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaRoyal Society of Chemistry2020-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/143943Gomez, Germán Ernesto; Onna, Diego Ariel; D'vries, R. F.; Barja, Beatriz Carmen; Ellena, Javier Alcides; et al.; Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis; Royal Society of Chemistry; Journal of Materials Chemistry C; 8; 32; 8-2020; 11102-111092050-75262050-7534CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2020/tc/d0tc02623ainfo:eu-repo/semantics/altIdentifier/doi/10.1039/D0TC02623Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:07:19Zoai:ri.conicet.gov.ar:11336/143943instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:07:19.974CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
title Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
spellingShingle Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
Gomez, Germán Ernesto
URANYL-COORDINATION POLYMER
GREEN LIGHT EMITTER
PHOTOCATALYSIS
DYE DEGRADATION
title_short Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
title_full Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
title_fullStr Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
title_full_unstemmed Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
title_sort Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
dc.creator.none.fl_str_mv Gomez, Germán Ernesto
Onna, Diego Ariel
D'vries, R. F.
Barja, Beatriz Carmen
Ellena, Javier Alcides
Narda, Griselda Edith
Soler Illia, Galo Juan de Avila Arturo
author Gomez, Germán Ernesto
author_facet Gomez, Germán Ernesto
Onna, Diego Ariel
D'vries, R. F.
Barja, Beatriz Carmen
Ellena, Javier Alcides
Narda, Griselda Edith
Soler Illia, Galo Juan de Avila Arturo
author_role author
author2 Onna, Diego Ariel
D'vries, R. F.
Barja, Beatriz Carmen
Ellena, Javier Alcides
Narda, Griselda Edith
Soler Illia, Galo Juan de Avila Arturo
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv URANYL-COORDINATION POLYMER
GREEN LIGHT EMITTER
PHOTOCATALYSIS
DYE DEGRADATION
topic URANYL-COORDINATION POLYMER
GREEN LIGHT EMITTER
PHOTOCATALYSIS
DYE DEGRADATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A new uranyl-coordination polymer (UCP) has been solvothermally synthesized employing succinic acid and 1,10-phenanthroline (phen) as ligands. The obtained compound with the formula [(UO2)2(phen)(succ)0.5(OH)(O)4(μ3-O)(H2O)]·H2O (UNSL-1) is classified as 1D chains showing I0O1 connectivity. Also, the asymmetric unit is composed of two hepta-coordinated uranyl centers: U1 is surrounded by five oxygen atoms from succinate, while U2 is surrounded by two nitrogen atoms from phen and three oxygen atoms from succinate ([U1O7] and [U2N2O5]). The secondary-building unit (SBU) is composed of a sharing edge tetrameric cluster linked with a succinate ligand in the [-1 0 1] direction. Besides, the chains are reinforced by π-π stacking interactions between the aromatic rings of the phen molecules to conform a 2D supramolecular arrangement. Moreover, photoluminescence experiments show strong green emission consistent with uranyl crystalline materials. Photophysical characterization was completed via low-temperature measurements (77 K) and recording the decay emission for calculating the lifetime (τobs) value. Regarding its multifunctional properties, a cation-sensing performance was achieved showing selective quenching toward iron ions in aqueous media. Finally, UNSL-1 was tested as an efficient water photocatalyst for dye degradation under simulated sunlight irradiation, exhibiting promising results for organic-pollutant water remediation.
Fil: Gomez, Germán Ernesto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Onna, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: D'vries, R. F.. Universidad del Cauca; Colombia
Fil: Barja, Beatriz Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Ellena, Javier Alcides. Universidade de Sao Paulo; Brasil
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description A new uranyl-coordination polymer (UCP) has been solvothermally synthesized employing succinic acid and 1,10-phenanthroline (phen) as ligands. The obtained compound with the formula [(UO2)2(phen)(succ)0.5(OH)(O)4(μ3-O)(H2O)]·H2O (UNSL-1) is classified as 1D chains showing I0O1 connectivity. Also, the asymmetric unit is composed of two hepta-coordinated uranyl centers: U1 is surrounded by five oxygen atoms from succinate, while U2 is surrounded by two nitrogen atoms from phen and three oxygen atoms from succinate ([U1O7] and [U2N2O5]). The secondary-building unit (SBU) is composed of a sharing edge tetrameric cluster linked with a succinate ligand in the [-1 0 1] direction. Besides, the chains are reinforced by π-π stacking interactions between the aromatic rings of the phen molecules to conform a 2D supramolecular arrangement. Moreover, photoluminescence experiments show strong green emission consistent with uranyl crystalline materials. Photophysical characterization was completed via low-temperature measurements (77 K) and recording the decay emission for calculating the lifetime (τobs) value. Regarding its multifunctional properties, a cation-sensing performance was achieved showing selective quenching toward iron ions in aqueous media. Finally, UNSL-1 was tested as an efficient water photocatalyst for dye degradation under simulated sunlight irradiation, exhibiting promising results for organic-pollutant water remediation.
publishDate 2020
dc.date.none.fl_str_mv 2020-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/143943
Gomez, Germán Ernesto; Onna, Diego Ariel; D'vries, R. F.; Barja, Beatriz Carmen; Ellena, Javier Alcides; et al.; Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis; Royal Society of Chemistry; Journal of Materials Chemistry C; 8; 32; 8-2020; 11102-11109
2050-7526
2050-7534
CONICET Digital
CONICET
url http://hdl.handle.net/11336/143943
identifier_str_mv Gomez, Germán Ernesto; Onna, Diego Ariel; D'vries, R. F.; Barja, Beatriz Carmen; Ellena, Javier Alcides; et al.; Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis; Royal Society of Chemistry; Journal of Materials Chemistry C; 8; 32; 8-2020; 11102-11109
2050-7526
2050-7534
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2020/tc/d0tc02623a
info:eu-repo/semantics/altIdentifier/doi/10.1039/D0TC02623A
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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