Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions

Autores
Herrera, Facundo Carlos; Caraballo, Rolando Manuel; Soler Illia, Galo Juan de Avila Arturo; Gomez, Germán Ernesto; Hamer, Mariana
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Metal-porphyrin frameworks (MPFs) with trivalent lanthanide ions are the most sought-after materials in the last decade. Their porosities are usually complemented with optical properties imparted by the metal nodes, making them attractive multifunctional materials. Here, we report a novel family of 3D MPFs obtained through solvothermal reactions between tetrakis(4-carboxyphenyl) porphyrin (H4TCPP) and different lanthanide sources yielding an isostructural family of compounds along the lanthanide series: [Ln2(DMF)(TCPP)1.5] for Ln= La, Ce, Nd, Pr, Er, Y, Tb, Dy, Sm, Eu, Gd and Tm. Photoluminescent properties of selected phases were explored at room temperature. Also, the photocatalytic performance exhibited by these compounds under sunlight exposure is promising for its implementation in organic pollutant degradation. In order to study the photocatalytic activity of Ln-TCPPs in an aqueous medium, methylene blue (MB) was used as a contaminant model. The efficiency for MB degradation was Sm > Y > Yb > Gd > Er > Eu > either no catalyst or no light, obtaining more than 70% degradation at 120 min with Sm-TCPP. These results open the possibility of using these compounds in optic and optoelectronic devices for water remediation and sensing.
Fil: Herrera, Facundo Carlos. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Caraballo, Rolando Manuel. Universidad Nacional de Luján. Instituto de Ecología y Desarrollo Sustentable. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Ecología y Desarrollo Sustentable; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Hamer, Mariana. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
PORPHYRIN
LANTANIDES
METAL PORPHYRIN FRAMEWORK
PHOTOCATALYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/219611
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide IonsHerrera, Facundo CarlosCaraballo, Rolando ManuelSoler Illia, Galo Juan de Avila ArturoGomez, Germán ErnestoHamer, MarianaPORPHYRINLANTANIDESMETAL PORPHYRIN FRAMEWORKPHOTOCATALYSIShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Metal-porphyrin frameworks (MPFs) with trivalent lanthanide ions are the most sought-after materials in the last decade. Their porosities are usually complemented with optical properties imparted by the metal nodes, making them attractive multifunctional materials. Here, we report a novel family of 3D MPFs obtained through solvothermal reactions between tetrakis(4-carboxyphenyl) porphyrin (H4TCPP) and different lanthanide sources yielding an isostructural family of compounds along the lanthanide series: [Ln2(DMF)(TCPP)1.5] for Ln= La, Ce, Nd, Pr, Er, Y, Tb, Dy, Sm, Eu, Gd and Tm. Photoluminescent properties of selected phases were explored at room temperature. Also, the photocatalytic performance exhibited by these compounds under sunlight exposure is promising for its implementation in organic pollutant degradation. In order to study the photocatalytic activity of Ln-TCPPs in an aqueous medium, methylene blue (MB) was used as a contaminant model. The efficiency for MB degradation was Sm > Y > Yb > Gd > Er > Eu > either no catalyst or no light, obtaining more than 70% degradation at 120 min with Sm-TCPP. These results open the possibility of using these compounds in optic and optoelectronic devices for water remediation and sensing.Fil: Herrera, Facundo Carlos. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Caraballo, Rolando Manuel. Universidad Nacional de Luján. Instituto de Ecología y Desarrollo Sustentable. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Ecología y Desarrollo Sustentable; ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; ArgentinaFil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Hamer, Mariana. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAmerican Chemical Society2023-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/219611Herrera, Facundo Carlos; Caraballo, Rolando Manuel; Soler Illia, Galo Juan de Avila Arturo; Gomez, Germán Ernesto; Hamer, Mariana; Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions; American Chemical Society; ACS Omega; 11-2023; 1-92470-1343CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.3c06153info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.3c06153info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:34:05Zoai:ri.conicet.gov.ar:11336/219611instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:34:06.078CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
title Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
spellingShingle Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
Herrera, Facundo Carlos
PORPHYRIN
LANTANIDES
METAL PORPHYRIN FRAMEWORK
PHOTOCATALYSIS
title_short Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
title_full Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
title_fullStr Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
title_full_unstemmed Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
title_sort Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions
dc.creator.none.fl_str_mv Herrera, Facundo Carlos
Caraballo, Rolando Manuel
Soler Illia, Galo Juan de Avila Arturo
Gomez, Germán Ernesto
Hamer, Mariana
author Herrera, Facundo Carlos
author_facet Herrera, Facundo Carlos
Caraballo, Rolando Manuel
Soler Illia, Galo Juan de Avila Arturo
Gomez, Germán Ernesto
Hamer, Mariana
author_role author
author2 Caraballo, Rolando Manuel
Soler Illia, Galo Juan de Avila Arturo
Gomez, Germán Ernesto
Hamer, Mariana
author2_role author
author
author
author
dc.subject.none.fl_str_mv PORPHYRIN
LANTANIDES
METAL PORPHYRIN FRAMEWORK
PHOTOCATALYSIS
topic PORPHYRIN
LANTANIDES
METAL PORPHYRIN FRAMEWORK
PHOTOCATALYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Metal-porphyrin frameworks (MPFs) with trivalent lanthanide ions are the most sought-after materials in the last decade. Their porosities are usually complemented with optical properties imparted by the metal nodes, making them attractive multifunctional materials. Here, we report a novel family of 3D MPFs obtained through solvothermal reactions between tetrakis(4-carboxyphenyl) porphyrin (H4TCPP) and different lanthanide sources yielding an isostructural family of compounds along the lanthanide series: [Ln2(DMF)(TCPP)1.5] for Ln= La, Ce, Nd, Pr, Er, Y, Tb, Dy, Sm, Eu, Gd and Tm. Photoluminescent properties of selected phases were explored at room temperature. Also, the photocatalytic performance exhibited by these compounds under sunlight exposure is promising for its implementation in organic pollutant degradation. In order to study the photocatalytic activity of Ln-TCPPs in an aqueous medium, methylene blue (MB) was used as a contaminant model. The efficiency for MB degradation was Sm > Y > Yb > Gd > Er > Eu > either no catalyst or no light, obtaining more than 70% degradation at 120 min with Sm-TCPP. These results open the possibility of using these compounds in optic and optoelectronic devices for water remediation and sensing.
Fil: Herrera, Facundo Carlos. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Caraballo, Rolando Manuel. Universidad Nacional de Luján. Instituto de Ecología y Desarrollo Sustentable. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Ecología y Desarrollo Sustentable; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Hamer, Mariana. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Metal-porphyrin frameworks (MPFs) with trivalent lanthanide ions are the most sought-after materials in the last decade. Their porosities are usually complemented with optical properties imparted by the metal nodes, making them attractive multifunctional materials. Here, we report a novel family of 3D MPFs obtained through solvothermal reactions between tetrakis(4-carboxyphenyl) porphyrin (H4TCPP) and different lanthanide sources yielding an isostructural family of compounds along the lanthanide series: [Ln2(DMF)(TCPP)1.5] for Ln= La, Ce, Nd, Pr, Er, Y, Tb, Dy, Sm, Eu, Gd and Tm. Photoluminescent properties of selected phases were explored at room temperature. Also, the photocatalytic performance exhibited by these compounds under sunlight exposure is promising for its implementation in organic pollutant degradation. In order to study the photocatalytic activity of Ln-TCPPs in an aqueous medium, methylene blue (MB) was used as a contaminant model. The efficiency for MB degradation was Sm > Y > Yb > Gd > Er > Eu > either no catalyst or no light, obtaining more than 70% degradation at 120 min with Sm-TCPP. These results open the possibility of using these compounds in optic and optoelectronic devices for water remediation and sensing.
publishDate 2023
dc.date.none.fl_str_mv 2023-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/219611
Herrera, Facundo Carlos; Caraballo, Rolando Manuel; Soler Illia, Galo Juan de Avila Arturo; Gomez, Germán Ernesto; Hamer, Mariana; Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions; American Chemical Society; ACS Omega; 11-2023; 1-9
2470-1343
CONICET Digital
CONICET
url http://hdl.handle.net/11336/219611
identifier_str_mv Herrera, Facundo Carlos; Caraballo, Rolando Manuel; Soler Illia, Galo Juan de Avila Arturo; Gomez, Germán Ernesto; Hamer, Mariana; Sunlight-Driven Photocatalysis for a Set of 3D Metal–Porphyrin Frameworks Based on a Planar Tetracarboxylic Ligand and Lanthanide Ions; American Chemical Society; ACS Omega; 11-2023; 1-9
2470-1343
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsomega.3c06153
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.3c06153
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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