Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
- Autores
- Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds.
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Ridenour, J. August. The George Washington University; Estados Unidos
Fil: Byrne, Nicole M.. The George Washington University; Estados Unidos
Fil: Shevchenko, Alexander P.. Samara University; Rusia
Fil: Cahill, Christopher L.. The George Washington University; Estados Unidos - Materia
-
MOFs
URANYL
LUMINISCENCE
STRUCTURE - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/122926
Ver los metadatos del registro completo
| id |
CONICETDig_16427a3dedbdad9a5ec79faa6692955e |
|---|---|
| oai_identifier_str |
oai:ri.conicet.gov.ar:11336/122926 |
| network_acronym_str |
CONICETDig |
| repository_id_str |
3498 |
| network_name_str |
CONICET Digital (CONICET) |
| spelling |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence propertiesGomez, Germán ErnestoRidenour, J. AugustByrne, Nicole M.Shevchenko, Alexander P.Cahill, Christopher L.MOFsURANYLLUMINISCENCESTRUCTUREhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds.Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Ridenour, J. August. The George Washington University; Estados UnidosFil: Byrne, Nicole M.. The George Washington University; Estados UnidosFil: Shevchenko, Alexander P.. Samara University; RusiaFil: Cahill, Christopher L.. The George Washington University; Estados UnidosAmerican Chemical Society2019-04-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/122926Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.; Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties; American Chemical Society; Inorganic Chemistry; 58; 11; 18-4-2019; 7243-72540020-1669CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00255info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.9b00255info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:00:38Zoai:ri.conicet.gov.ar:11336/122926instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:00:38.693CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties |
| title |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties |
| spellingShingle |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties Gomez, Germán Ernesto MOFs URANYL LUMINISCENCE STRUCTURE |
| title_short |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties |
| title_full |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties |
| title_fullStr |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties |
| title_full_unstemmed |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties |
| title_sort |
Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties |
| dc.creator.none.fl_str_mv |
Gomez, Germán Ernesto Ridenour, J. August Byrne, Nicole M. Shevchenko, Alexander P. Cahill, Christopher L. |
| author |
Gomez, Germán Ernesto |
| author_facet |
Gomez, Germán Ernesto Ridenour, J. August Byrne, Nicole M. Shevchenko, Alexander P. Cahill, Christopher L. |
| author_role |
author |
| author2 |
Ridenour, J. August Byrne, Nicole M. Shevchenko, Alexander P. Cahill, Christopher L. |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
MOFs URANYL LUMINISCENCE STRUCTURE |
| topic |
MOFs URANYL LUMINISCENCE STRUCTURE |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds. Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina Fil: Ridenour, J. August. The George Washington University; Estados Unidos Fil: Byrne, Nicole M.. The George Washington University; Estados Unidos Fil: Shevchenko, Alexander P.. Samara University; Rusia Fil: Cahill, Christopher L.. The George Washington University; Estados Unidos |
| description |
Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds. |
| publishDate |
2019 |
| dc.date.none.fl_str_mv |
2019-04-18 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/122926 Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.; Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties; American Chemical Society; Inorganic Chemistry; 58; 11; 18-4-2019; 7243-7254 0020-1669 CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/122926 |
| identifier_str_mv |
Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.; Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties; American Chemical Society; Inorganic Chemistry; 58; 11; 18-4-2019; 7243-7254 0020-1669 CONICET Digital CONICET |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00255 info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.9b00255 |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
| eu_rights_str_mv |
openAccess |
| rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
| dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
| dc.publisher.none.fl_str_mv |
American Chemical Society |
| publisher.none.fl_str_mv |
American Chemical Society |
| dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
| reponame_str |
CONICET Digital (CONICET) |
| collection |
CONICET Digital (CONICET) |
| instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
| repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
| repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
| _version_ |
1846781171458899968 |
| score |
12.982451 |