Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties

Autores
Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds.
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Ridenour, J. August. The George Washington University; Estados Unidos
Fil: Byrne, Nicole M.. The George Washington University; Estados Unidos
Fil: Shevchenko, Alexander P.. Samara University; Rusia
Fil: Cahill, Christopher L.. The George Washington University; Estados Unidos
Materia
MOFs
URANYL
LUMINISCENCE
STRUCTURE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/122926
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/122926
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence propertiesGomez, Germán ErnestoRidenour, J. AugustByrne, Nicole M.Shevchenko, Alexander P.Cahill, Christopher L.MOFsURANYLLUMINISCENCESTRUCTUREhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds.Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Ridenour, J. August. The George Washington University; Estados UnidosFil: Byrne, Nicole M.. The George Washington University; Estados UnidosFil: Shevchenko, Alexander P.. Samara University; RusiaFil: Cahill, Christopher L.. The George Washington University; Estados UnidosAmerican Chemical Society2019-04-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/122926Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.; Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties; American Chemical Society; Inorganic Chemistry; 58; 11; 18-4-2019; 7243-72540020-1669CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00255info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.9b00255info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:32:38Zoai:ri.conicet.gov.ar:11336/122926instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:32:38.787CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
title Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
spellingShingle Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
Gomez, Germán Ernesto
MOFs
URANYL
LUMINISCENCE
STRUCTURE
title_short Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
title_full Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
title_fullStr Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
title_full_unstemmed Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
title_sort Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties
dc.creator.none.fl_str_mv Gomez, Germán Ernesto
Ridenour, J. August
Byrne, Nicole M.
Shevchenko, Alexander P.
Cahill, Christopher L.
author Gomez, Germán Ernesto
author_facet Gomez, Germán Ernesto
Ridenour, J. August
Byrne, Nicole M.
Shevchenko, Alexander P.
Cahill, Christopher L.
author_role author
author2 Ridenour, J. August
Byrne, Nicole M.
Shevchenko, Alexander P.
Cahill, Christopher L.
author2_role author
author
author
author
dc.subject.none.fl_str_mv MOFs
URANYL
LUMINISCENCE
STRUCTURE
topic MOFs
URANYL
LUMINISCENCE
STRUCTURE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds.
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Ridenour, J. August. The George Washington University; Estados Unidos
Fil: Byrne, Nicole M.. The George Washington University; Estados Unidos
Fil: Shevchenko, Alexander P.. Samara University; Rusia
Fil: Cahill, Christopher L.. The George Washington University; Estados Unidos
description Six new uranyl hybrid materials have been synthesized solvothermally utilizing the ligands 2,2′-bipyridine-3,3′-dicarboxylic acid (H2L) and 2,2′:6′,2′′-terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), [(UO2)(L)(TPY)]·H2O (1), [Ni(TPY)2][(UO2)(L)2]·3H2O (2), and [Cu(TPY)2][(UO2)(L)2]·3H2O (3), or 3D metal–organic frameworks (MOFs, I0O3 connectivity), [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2]·6H2O (4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)(L)3(TPY)2]·4H2O (5), and Na[Ni(UO2)3(OH)(O)(L)3]·9H2O (6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. A topological analysis of 6 reveals a new topology with a 9-nodal 3,3,3,3,3,3,3,4,5-connected network, designated geg1 hereafter. Further, solid state photoluminescence experiments show emission and lifetimes values consistent with related uranyl compounds.
publishDate 2019
dc.date.none.fl_str_mv 2019-04-18
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/122926
Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.; Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties; American Chemical Society; Inorganic Chemistry; 58; 11; 18-4-2019; 7243-7254
0020-1669
CONICET Digital
CONICET
url http://hdl.handle.net/11336/122926
identifier_str_mv Gomez, Germán Ernesto; Ridenour, J. August; Byrne, Nicole M.; Shevchenko, Alexander P.; Cahill, Christopher L.; Novel heterometallic uranyl-transition metal materials: Structure, topology, and solid state photoluminescence properties; American Chemical Society; Inorganic Chemistry; 58; 11; 18-4-2019; 7243-7254
0020-1669
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00255
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.9b00255
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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