Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches

Autores
Talou, Mariano Hernán; Moreno, Rodrigo; Camerucci, Maria Andrea
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this article, the processing and microstructures of porous mullite bodies prepared by modifying the conventional route of the starch consolidation casting method were studied. The proposed route, called the “soluble route”, involves the use of native starches (i.e., potato, cassava, and corn starches) and a synthesized granular cold-water-soluble (GCWS) starch. Stable aqueous mullite-starch suspensions (0.25 starch volume fraction of 40 vol% total solids) were prepared by mixing. The total starch content was a mixture of ungelatinized native starch and GCWS starch with a 1:10 ratio of GCWS starch to total starch. Steady-state shear flow properties of the suspensions were analyzed by measuring viscosity. The addition of CGWS starch increased the starting suspension viscosity and thus prevented the particle segregation. Porous mullite bodies were obtained by heating (80°C, 2 h) the suspensions in metallic molds and by drying (40°C, 24 h) and sintering (1650°C, 2 h) the green disks after burning out the starch (650°C, 2 h). Green bodies obtained before and after the burning-out process, and the sintered disks were characterized with density and porosity measurements (Archimedes method) and microstructural analysis by scanning electron microscopy. The phases generated after the sintering process were determined by X-ray diffraction analysis, and pore size distributions were studied by Hg-porosimetry. The obtained results showed that the use of the GCWS starch made the shaping of homogeneous mullite bodies without cracks or deformations possible along with the development of controlled porous microstructures.
Fil: Talou, Mariano Hernán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Moreno, Rodrigo. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Camerucci, Maria Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Starch Direct Consolidation
Granular Cold-Water-Soluble Starch
Porous Ceramic
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5181
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5181
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starchesTalou, Mariano HernánMoreno, RodrigoCamerucci, Maria AndreaStarch Direct ConsolidationGranular Cold-Water-Soluble StarchPorous Ceramichttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this article, the processing and microstructures of porous mullite bodies prepared by modifying the conventional route of the starch consolidation casting method were studied. The proposed route, called the “soluble route”, involves the use of native starches (i.e., potato, cassava, and corn starches) and a synthesized granular cold-water-soluble (GCWS) starch. Stable aqueous mullite-starch suspensions (0.25 starch volume fraction of 40 vol% total solids) were prepared by mixing. The total starch content was a mixture of ungelatinized native starch and GCWS starch with a 1:10 ratio of GCWS starch to total starch. Steady-state shear flow properties of the suspensions were analyzed by measuring viscosity. The addition of CGWS starch increased the starting suspension viscosity and thus prevented the particle segregation. Porous mullite bodies were obtained by heating (80°C, 2 h) the suspensions in metallic molds and by drying (40°C, 24 h) and sintering (1650°C, 2 h) the green disks after burning out the starch (650°C, 2 h). Green bodies obtained before and after the burning-out process, and the sintered disks were characterized with density and porosity measurements (Archimedes method) and microstructural analysis by scanning electron microscopy. The phases generated after the sintering process were determined by X-ray diffraction analysis, and pore size distributions were studied by Hg-porosimetry. The obtained results showed that the use of the GCWS starch made the shaping of homogeneous mullite bodies without cracks or deformations possible along with the development of controlled porous microstructures.Fil: Talou, Mariano Hernán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Moreno, Rodrigo. Instituto de Ceramica y Vidrio de Madrid; EspañaFil: Camerucci, Maria Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaWiley2014-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/zipapplication/pdfhttp://hdl.handle.net/11336/5181Talou, Mariano Hernán; Moreno, Rodrigo; Camerucci, Maria Andrea; Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches; Wiley; Journal of the American Ceramic Society; 97; 4; 4-2014; 1074-10820002-7820enginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1111/jace.12852info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1111/jace.12852/abstractinfo:eu-repo/semantics/altIdentifier/issn/0002-7820info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:17Zoai:ri.conicet.gov.ar:11336/5181instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:18.153CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
title Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
spellingShingle Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
Talou, Mariano Hernán
Starch Direct Consolidation
Granular Cold-Water-Soluble Starch
Porous Ceramic
title_short Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
title_full Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
title_fullStr Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
title_full_unstemmed Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
title_sort Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches
dc.creator.none.fl_str_mv Talou, Mariano Hernán
Moreno, Rodrigo
Camerucci, Maria Andrea
author Talou, Mariano Hernán
author_facet Talou, Mariano Hernán
Moreno, Rodrigo
Camerucci, Maria Andrea
author_role author
author2 Moreno, Rodrigo
Camerucci, Maria Andrea
author2_role author
author
dc.subject.none.fl_str_mv Starch Direct Consolidation
Granular Cold-Water-Soluble Starch
Porous Ceramic
topic Starch Direct Consolidation
Granular Cold-Water-Soluble Starch
Porous Ceramic
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this article, the processing and microstructures of porous mullite bodies prepared by modifying the conventional route of the starch consolidation casting method were studied. The proposed route, called the “soluble route”, involves the use of native starches (i.e., potato, cassava, and corn starches) and a synthesized granular cold-water-soluble (GCWS) starch. Stable aqueous mullite-starch suspensions (0.25 starch volume fraction of 40 vol% total solids) were prepared by mixing. The total starch content was a mixture of ungelatinized native starch and GCWS starch with a 1:10 ratio of GCWS starch to total starch. Steady-state shear flow properties of the suspensions were analyzed by measuring viscosity. The addition of CGWS starch increased the starting suspension viscosity and thus prevented the particle segregation. Porous mullite bodies were obtained by heating (80°C, 2 h) the suspensions in metallic molds and by drying (40°C, 24 h) and sintering (1650°C, 2 h) the green disks after burning out the starch (650°C, 2 h). Green bodies obtained before and after the burning-out process, and the sintered disks were characterized with density and porosity measurements (Archimedes method) and microstructural analysis by scanning electron microscopy. The phases generated after the sintering process were determined by X-ray diffraction analysis, and pore size distributions were studied by Hg-porosimetry. The obtained results showed that the use of the GCWS starch made the shaping of homogeneous mullite bodies without cracks or deformations possible along with the development of controlled porous microstructures.
Fil: Talou, Mariano Hernán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Moreno, Rodrigo. Instituto de Ceramica y Vidrio de Madrid; España
Fil: Camerucci, Maria Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description In this article, the processing and microstructures of porous mullite bodies prepared by modifying the conventional route of the starch consolidation casting method were studied. The proposed route, called the “soluble route”, involves the use of native starches (i.e., potato, cassava, and corn starches) and a synthesized granular cold-water-soluble (GCWS) starch. Stable aqueous mullite-starch suspensions (0.25 starch volume fraction of 40 vol% total solids) were prepared by mixing. The total starch content was a mixture of ungelatinized native starch and GCWS starch with a 1:10 ratio of GCWS starch to total starch. Steady-state shear flow properties of the suspensions were analyzed by measuring viscosity. The addition of CGWS starch increased the starting suspension viscosity and thus prevented the particle segregation. Porous mullite bodies were obtained by heating (80°C, 2 h) the suspensions in metallic molds and by drying (40°C, 24 h) and sintering (1650°C, 2 h) the green disks after burning out the starch (650°C, 2 h). Green bodies obtained before and after the burning-out process, and the sintered disks were characterized with density and porosity measurements (Archimedes method) and microstructural analysis by scanning electron microscopy. The phases generated after the sintering process were determined by X-ray diffraction analysis, and pore size distributions were studied by Hg-porosimetry. The obtained results showed that the use of the GCWS starch made the shaping of homogeneous mullite bodies without cracks or deformations possible along with the development of controlled porous microstructures.
publishDate 2014
dc.date.none.fl_str_mv 2014-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5181
Talou, Mariano Hernán; Moreno, Rodrigo; Camerucci, Maria Andrea; Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches; Wiley; Journal of the American Ceramic Society; 97; 4; 4-2014; 1074-1082
0002-7820
url http://hdl.handle.net/11336/5181
identifier_str_mv Talou, Mariano Hernán; Moreno, Rodrigo; Camerucci, Maria Andrea; Porous mullite ceramics formed by direct consolidation using native and granular cold-water-soluble starches; Wiley; Journal of the American Ceramic Society; 97; 4; 4-2014; 1074-1082
0002-7820
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1111/jace.12852
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1111/jace.12852/abstract
info:eu-repo/semantics/altIdentifier/issn/0002-7820
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/zip
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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