Electrodeposited Cu2ZnSnS4 thin films

Autores
Valdes, Matias Hernan; Modibedi, M.; Mathe, M.; Hillie, T.; Vazquez, Marcela Vivian
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Cu2ZnSnS4 (CZTS) thin films have been prepared using Electrochemical Atomic Layer Deposition (EC-ALD and also by one-step conventional constant potential electrodeposition. Optimal deposition conditions were investigated using cyclic voltammetry (CV). Then, based on CVs results, CZTS films were grown employing EC-ALD deposition cycles using the sequence Au/S/Cu/S/Zn/S/Sn/S to form the desired quaternary compound. In parallel, conventional one-step electrodeposition was carried out at -0.85 V vs. Ag/AgCl over 1 hour. A thermal treatment in sulfur vapor was also investigated in an attempt to optimize the stoichiometry. The crystal structure of the films was characterized by XRD and micro Raman spectroscopy, while the morphology, thickness, topography and elemental composition were investigated using FIB-SEM and EDS.
Fil: Valdes, Matias Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Modibedi, M.. Energy Materials; Sudáfrica
Fil: Mathe, M.. Energy Materials; Sudáfrica
Fil: Hillie, T.. National Centre For Nano-structured Materials; Sudáfrica
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Electrodeposition
Semiconductors
Thin Films
Czts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/27882
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/27882
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrodeposited Cu2ZnSnS4 thin filmsValdes, Matias HernanModibedi, M.Mathe, M.Hillie, T.Vazquez, Marcela VivianElectrodepositionSemiconductorsThin FilmsCztshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Cu2ZnSnS4 (CZTS) thin films have been prepared using Electrochemical Atomic Layer Deposition (EC-ALD and also by one-step conventional constant potential electrodeposition. Optimal deposition conditions were investigated using cyclic voltammetry (CV). Then, based on CVs results, CZTS films were grown employing EC-ALD deposition cycles using the sequence Au/S/Cu/S/Zn/S/Sn/S to form the desired quaternary compound. In parallel, conventional one-step electrodeposition was carried out at -0.85 V vs. Ag/AgCl over 1 hour. A thermal treatment in sulfur vapor was also investigated in an attempt to optimize the stoichiometry. The crystal structure of the films was characterized by XRD and micro Raman spectroscopy, while the morphology, thickness, topography and elemental composition were investigated using FIB-SEM and EDS.Fil: Valdes, Matias Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Modibedi, M.. Energy Materials; SudáfricaFil: Mathe, M.. Energy Materials; SudáfricaFil: Hillie, T.. National Centre For Nano-structured Materials; SudáfricaFil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier2013-11-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/27882Valdes, Matias Hernan; Modibedi, M.; Mathe, M.; Hillie, T.; Vazquez, Marcela Vivian; Electrodeposited Cu2ZnSnS4 thin films; Elsevier; Electrochimica Acta; 128; 12-11-2013; 393-3990013-4686CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0013468613021786?via%3Dihubinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2013.10.206info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:57:38Zoai:ri.conicet.gov.ar:11336/27882instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:57:38.288CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrodeposited Cu2ZnSnS4 thin films
title Electrodeposited Cu2ZnSnS4 thin films
spellingShingle Electrodeposited Cu2ZnSnS4 thin films
Valdes, Matias Hernan
Electrodeposition
Semiconductors
Thin Films
Czts
title_short Electrodeposited Cu2ZnSnS4 thin films
title_full Electrodeposited Cu2ZnSnS4 thin films
title_fullStr Electrodeposited Cu2ZnSnS4 thin films
title_full_unstemmed Electrodeposited Cu2ZnSnS4 thin films
title_sort Electrodeposited Cu2ZnSnS4 thin films
dc.creator.none.fl_str_mv Valdes, Matias Hernan
Modibedi, M.
Mathe, M.
Hillie, T.
Vazquez, Marcela Vivian
author Valdes, Matias Hernan
author_facet Valdes, Matias Hernan
Modibedi, M.
Mathe, M.
Hillie, T.
Vazquez, Marcela Vivian
author_role author
author2 Modibedi, M.
Mathe, M.
Hillie, T.
Vazquez, Marcela Vivian
author2_role author
author
author
author
dc.subject.none.fl_str_mv Electrodeposition
Semiconductors
Thin Films
Czts
topic Electrodeposition
Semiconductors
Thin Films
Czts
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Cu2ZnSnS4 (CZTS) thin films have been prepared using Electrochemical Atomic Layer Deposition (EC-ALD and also by one-step conventional constant potential electrodeposition. Optimal deposition conditions were investigated using cyclic voltammetry (CV). Then, based on CVs results, CZTS films were grown employing EC-ALD deposition cycles using the sequence Au/S/Cu/S/Zn/S/Sn/S to form the desired quaternary compound. In parallel, conventional one-step electrodeposition was carried out at -0.85 V vs. Ag/AgCl over 1 hour. A thermal treatment in sulfur vapor was also investigated in an attempt to optimize the stoichiometry. The crystal structure of the films was characterized by XRD and micro Raman spectroscopy, while the morphology, thickness, topography and elemental composition were investigated using FIB-SEM and EDS.
Fil: Valdes, Matias Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Modibedi, M.. Energy Materials; Sudáfrica
Fil: Mathe, M.. Energy Materials; Sudáfrica
Fil: Hillie, T.. National Centre For Nano-structured Materials; Sudáfrica
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Cu2ZnSnS4 (CZTS) thin films have been prepared using Electrochemical Atomic Layer Deposition (EC-ALD and also by one-step conventional constant potential electrodeposition. Optimal deposition conditions were investigated using cyclic voltammetry (CV). Then, based on CVs results, CZTS films were grown employing EC-ALD deposition cycles using the sequence Au/S/Cu/S/Zn/S/Sn/S to form the desired quaternary compound. In parallel, conventional one-step electrodeposition was carried out at -0.85 V vs. Ag/AgCl over 1 hour. A thermal treatment in sulfur vapor was also investigated in an attempt to optimize the stoichiometry. The crystal structure of the films was characterized by XRD and micro Raman spectroscopy, while the morphology, thickness, topography and elemental composition were investigated using FIB-SEM and EDS.
publishDate 2013
dc.date.none.fl_str_mv 2013-11-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/27882
Valdes, Matias Hernan; Modibedi, M.; Mathe, M.; Hillie, T.; Vazquez, Marcela Vivian; Electrodeposited Cu2ZnSnS4 thin films; Elsevier; Electrochimica Acta; 128; 12-11-2013; 393-399
0013-4686
CONICET Digital
CONICET
url http://hdl.handle.net/11336/27882
identifier_str_mv Valdes, Matias Hernan; Modibedi, M.; Mathe, M.; Hillie, T.; Vazquez, Marcela Vivian; Electrodeposited Cu2ZnSnS4 thin films; Elsevier; Electrochimica Acta; 128; 12-11-2013; 393-399
0013-4686
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0013468613021786?via%3Dihub
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.electacta.2013.10.206
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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