Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems

Autores
Marsili, Nilda Raquel; Lista, Adriana Guillermina; Fernández Band, Beatriz Susana; Goicoechea, Hector Casimiro; Olivieri, Alejandro Cesar
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This article reports on the first application of a modified version of the bilinear least-squares model to absorbance-pH second-order data recorded for complex samples. The latter are composed of fruit drink powders, where four different analytes and additional background components occur. The analytes are the common juice colorants tartrazine, yellow sunset, allura red and indigo carmine. The data have been measured after generating a double pH gradient within a flow injection system. The selected chemometric methodology adequately exploits the second-order advantage, needed to take into account the background interferents present in real samples. Due to severe spectral overlapping between the acid and basic forms of each of the colorants in the working pH range, other second-order multivariate calibration methods such as parallel factor analysis and multivariate curve resolution-alternating least-squares could not be successfully applied to the presently studied samples. Recoveries of 94.8, 104.7, 109.3 and 105.3% were obtained for yellow sunset, indigo carmine, allura red and tartrazine respectively in the real test samples.
Fil: Marsili, Nilda Raquel. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Fil: Lista, Adriana Guillermina. Universidad Nacional del Sur; Argentina
Fil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Olivieri, Alejandro Cesar. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario; Argentina
Materia
COLORANTS
SECOND-ORDER DATA
COMPLEX SAMPLES
MODIFIED BILINEAR LEAST- SQUARES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/95253
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/95253
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systemsMarsili, Nilda RaquelLista, Adriana GuillerminaFernández Band, Beatriz SusanaGoicoechea, Hector CasimiroOlivieri, Alejandro CesarCOLORANTSSECOND-ORDER DATACOMPLEX SAMPLESMODIFIED BILINEAR LEAST- SQUAREShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This article reports on the first application of a modified version of the bilinear least-squares model to absorbance-pH second-order data recorded for complex samples. The latter are composed of fruit drink powders, where four different analytes and additional background components occur. The analytes are the common juice colorants tartrazine, yellow sunset, allura red and indigo carmine. The data have been measured after generating a double pH gradient within a flow injection system. The selected chemometric methodology adequately exploits the second-order advantage, needed to take into account the background interferents present in real samples. Due to severe spectral overlapping between the acid and basic forms of each of the colorants in the working pH range, other second-order multivariate calibration methods such as parallel factor analysis and multivariate curve resolution-alternating least-squares could not be successfully applied to the presently studied samples. Recoveries of 94.8, 104.7, 109.3 and 105.3% were obtained for yellow sunset, indigo carmine, allura red and tartrazine respectively in the real test samples.Fil: Marsili, Nilda Raquel. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; ArgentinaFil: Lista, Adriana Guillermina. Universidad Nacional del Sur; ArgentinaFil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Olivieri, Alejandro Cesar. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario; ArgentinaRoyal Society of Chemistry2005-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/95253Marsili, Nilda Raquel; Lista, Adriana Guillermina; Fernández Band, Beatriz Susana; Goicoechea, Hector Casimiro; Olivieri, Alejandro Cesar; Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems; Royal Society of Chemistry; Analyst; 130; 9; 9-2005; 1291-12980003-2654CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2005/AN/B504378F#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/B504378Finfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:36:27Zoai:ri.conicet.gov.ar:11336/95253instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:36:27.576CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
title Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
spellingShingle Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
Marsili, Nilda Raquel
COLORANTS
SECOND-ORDER DATA
COMPLEX SAMPLES
MODIFIED BILINEAR LEAST- SQUARES
title_short Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
title_full Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
title_fullStr Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
title_full_unstemmed Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
title_sort Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems
dc.creator.none.fl_str_mv Marsili, Nilda Raquel
Lista, Adriana Guillermina
Fernández Band, Beatriz Susana
Goicoechea, Hector Casimiro
Olivieri, Alejandro Cesar
author Marsili, Nilda Raquel
author_facet Marsili, Nilda Raquel
Lista, Adriana Guillermina
Fernández Band, Beatriz Susana
Goicoechea, Hector Casimiro
Olivieri, Alejandro Cesar
author_role author
author2 Lista, Adriana Guillermina
Fernández Band, Beatriz Susana
Goicoechea, Hector Casimiro
Olivieri, Alejandro Cesar
author2_role author
author
author
author
dc.subject.none.fl_str_mv COLORANTS
SECOND-ORDER DATA
COMPLEX SAMPLES
MODIFIED BILINEAR LEAST- SQUARES
topic COLORANTS
SECOND-ORDER DATA
COMPLEX SAMPLES
MODIFIED BILINEAR LEAST- SQUARES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This article reports on the first application of a modified version of the bilinear least-squares model to absorbance-pH second-order data recorded for complex samples. The latter are composed of fruit drink powders, where four different analytes and additional background components occur. The analytes are the common juice colorants tartrazine, yellow sunset, allura red and indigo carmine. The data have been measured after generating a double pH gradient within a flow injection system. The selected chemometric methodology adequately exploits the second-order advantage, needed to take into account the background interferents present in real samples. Due to severe spectral overlapping between the acid and basic forms of each of the colorants in the working pH range, other second-order multivariate calibration methods such as parallel factor analysis and multivariate curve resolution-alternating least-squares could not be successfully applied to the presently studied samples. Recoveries of 94.8, 104.7, 109.3 and 105.3% were obtained for yellow sunset, indigo carmine, allura red and tartrazine respectively in the real test samples.
Fil: Marsili, Nilda Raquel. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Fil: Lista, Adriana Guillermina. Universidad Nacional del Sur; Argentina
Fil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Olivieri, Alejandro Cesar. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario; Argentina
description This article reports on the first application of a modified version of the bilinear least-squares model to absorbance-pH second-order data recorded for complex samples. The latter are composed of fruit drink powders, where four different analytes and additional background components occur. The analytes are the common juice colorants tartrazine, yellow sunset, allura red and indigo carmine. The data have been measured after generating a double pH gradient within a flow injection system. The selected chemometric methodology adequately exploits the second-order advantage, needed to take into account the background interferents present in real samples. Due to severe spectral overlapping between the acid and basic forms of each of the colorants in the working pH range, other second-order multivariate calibration methods such as parallel factor analysis and multivariate curve resolution-alternating least-squares could not be successfully applied to the presently studied samples. Recoveries of 94.8, 104.7, 109.3 and 105.3% were obtained for yellow sunset, indigo carmine, allura red and tartrazine respectively in the real test samples.
publishDate 2005
dc.date.none.fl_str_mv 2005-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/95253
Marsili, Nilda Raquel; Lista, Adriana Guillermina; Fernández Band, Beatriz Susana; Goicoechea, Hector Casimiro; Olivieri, Alejandro Cesar; Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems; Royal Society of Chemistry; Analyst; 130; 9; 9-2005; 1291-1298
0003-2654
CONICET Digital
CONICET
url http://hdl.handle.net/11336/95253
identifier_str_mv Marsili, Nilda Raquel; Lista, Adriana Guillermina; Fernández Band, Beatriz Susana; Goicoechea, Hector Casimiro; Olivieri, Alejandro Cesar; Evaluation of complex spectral-pH three-way arrays by modified bilinear least-squares: Determination of four different dyes in interfering systems; Royal Society of Chemistry; Analyst; 130; 9; 9-2005; 1291-1298
0003-2654
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2005/AN/B504378F#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/B504378F
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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