Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric

Autores
Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme.
Fil: Ramos, M. E.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina
Fil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina
Fil: Ribeiro Carrott, M. M .L.. Universidade de Évora; Portugal
Fil: Carrott, P. J. M.. Universidade de Évora; Portugal
Materia
MICROPOROUS MATERIALS
ADSORPTION
MICROESTRUCTURE
SURFACE PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/242243
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabricRamos, M. E.Bonelli, Pablo RicardoCukierman, Ana LeaRibeiro Carrott, M. M .L.Carrott, P. J. M.MICROPOROUS MATERIALSADSORPTIONMICROESTRUCTURESURFACE PROPERTIEShttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme.Fil: Ramos, M. E.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; ArgentinaFil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; ArgentinaFil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; ArgentinaFil: Ribeiro Carrott, M. M .L.. Universidade de Évora; PortugalFil: Carrott, P. J. M.. Universidade de Évora; PortugalElsevier Science SA2009-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/242243Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.; Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric; Elsevier Science SA; Materials Chemistry and Physics; 116; 2-3; 8-2009; 310-3140254-0584CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058409001679info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2009.03.042info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:41:23Zoai:ri.conicet.gov.ar:11336/242243instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:41:23.377CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
spellingShingle Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
Ramos, M. E.
MICROPOROUS MATERIALS
ADSORPTION
MICROESTRUCTURE
SURFACE PROPERTIES
title_short Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_full Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_fullStr Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_full_unstemmed Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_sort Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
dc.creator.none.fl_str_mv Ramos, M. E.
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
Ribeiro Carrott, M. M .L.
Carrott, P. J. M.
author Ramos, M. E.
author_facet Ramos, M. E.
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
Ribeiro Carrott, M. M .L.
Carrott, P. J. M.
author_role author
author2 Bonelli, Pablo Ricardo
Cukierman, Ana Lea
Ribeiro Carrott, M. M .L.
Carrott, P. J. M.
author2_role author
author
author
author
dc.subject.none.fl_str_mv MICROPOROUS MATERIALS
ADSORPTION
MICROESTRUCTURE
SURFACE PROPERTIES
topic MICROPOROUS MATERIALS
ADSORPTION
MICROESTRUCTURE
SURFACE PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme.
Fil: Ramos, M. E.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina
Fil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina
Fil: Ribeiro Carrott, M. M .L.. Universidade de Évora; Portugal
Fil: Carrott, P. J. M.. Universidade de Évora; Portugal
description Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme.
publishDate 2009
dc.date.none.fl_str_mv 2009-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/242243
Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.; Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric; Elsevier Science SA; Materials Chemistry and Physics; 116; 2-3; 8-2009; 310-314
0254-0584
CONICET Digital
CONICET
url http://hdl.handle.net/11336/242243
identifier_str_mv Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.; Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric; Elsevier Science SA; Materials Chemistry and Physics; 116; 2-3; 8-2009; 310-314
0254-0584
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058409001679
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2009.03.042
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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