Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
- Autores
- Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme.
Fil: Ramos, M. E.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina
Fil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina
Fil: Ribeiro Carrott, M. M .L.. Universidade de Évora; Portugal
Fil: Carrott, P. J. M.. Universidade de Évora; Portugal - Materia
-
MICROPOROUS MATERIALS
ADSORPTION
MICROESTRUCTURE
SURFACE PROPERTIES - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/242243
Ver los metadatos del registro completo
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Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabricRamos, M. E.Bonelli, Pablo RicardoCukierman, Ana LeaRibeiro Carrott, M. M .L.Carrott, P. J. M.MICROPOROUS MATERIALSADSORPTIONMICROESTRUCTURESURFACE PROPERTIEShttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme.Fil: Ramos, M. E.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; ArgentinaFil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; ArgentinaFil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; ArgentinaFil: Ribeiro Carrott, M. M .L.. Universidade de Évora; PortugalFil: Carrott, P. J. M.. Universidade de Évora; PortugalElsevier Science SA2009-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/242243Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.; Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric; Elsevier Science SA; Materials Chemistry and Physics; 116; 2-3; 8-2009; 310-3140254-0584CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058409001679info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2009.03.042info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:57Zoai:ri.conicet.gov.ar:11336/242243instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:57.922CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric |
title |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric |
spellingShingle |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric Ramos, M. E. MICROPOROUS MATERIALS ADSORPTION MICROESTRUCTURE SURFACE PROPERTIES |
title_short |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric |
title_full |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric |
title_fullStr |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric |
title_full_unstemmed |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric |
title_sort |
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric |
dc.creator.none.fl_str_mv |
Ramos, M. E. Bonelli, Pablo Ricardo Cukierman, Ana Lea Ribeiro Carrott, M. M .L. Carrott, P. J. M. |
author |
Ramos, M. E. |
author_facet |
Ramos, M. E. Bonelli, Pablo Ricardo Cukierman, Ana Lea Ribeiro Carrott, M. M .L. Carrott, P. J. M. |
author_role |
author |
author2 |
Bonelli, Pablo Ricardo Cukierman, Ana Lea Ribeiro Carrott, M. M .L. Carrott, P. J. M. |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
MICROPOROUS MATERIALS ADSORPTION MICROESTRUCTURE SURFACE PROPERTIES |
topic |
MICROPOROUS MATERIALS ADSORPTION MICROESTRUCTURE SURFACE PROPERTIES |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.7 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme. Fil: Ramos, M. E.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina Fil: Bonelli, Pablo Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina Fil: Ribeiro Carrott, M. M .L.. Universidade de Évora; Portugal Fil: Carrott, P. J. M.. Universidade de Évora; Portugal |
description |
Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (660-970°C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition and porosity development of the resulting ACC were examined. Nitrogen isotherms at -196ºC and carbon dioxide isotherms at 0ºC were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963°C showed maximum BET surface area (1705 m2g-1) and total pore volume (0.67 cm3g-1). Results pointed out to a stronger dependence of surface area, total pore volume and microporosity development on the final treatment temperature than on the temperature programme. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/242243 Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.; Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric; Elsevier Science SA; Materials Chemistry and Physics; 116; 2-3; 8-2009; 310-314 0254-0584 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/242243 |
identifier_str_mv |
Ramos, M. E.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M .L.; Carrott, P. J. M.; Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric; Elsevier Science SA; Materials Chemistry and Physics; 116; 2-3; 8-2009; 310-314 0254-0584 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058409001679 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2009.03.042 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science SA |
publisher.none.fl_str_mv |
Elsevier Science SA |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842270100893204480 |
score |
13.13397 |