Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors

Autores
Falco, Camillo; Sieben, Juan Manuel; Brun, Nicolas; Sevilla, Marta; van der Mauelen, Torbjorn; Morallón, Emilia; Cazorla Amorós, Diego; Titirici, Maria Magdalena
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Acid pretreatment of lignocellulosic biomass, required for bioethanol production, generates large amounts of by-products, such as lignin and hydrolyzed hemicellulose fractions, which have found so far very limited applications. In this work, we demonstrate how the recovered hemicellulose hydrolysis products can be effectively utilized as a precursor for the synthesis of functional carbon materials through hydrothermal carbonization (HTC). The morphology and chemical structure of the synthesized HTC carbons are thoroughly characterized to highlight their similarities with glucose-derived HTC carbons. Furthermore, two routes for introducing porosity within the HTC carbon structure are presented: i) silica nanoparticle hard-templating, which is shown to be a viable method for the synthesis of carbonaceous hollow spheres; and ii) KOH chemical activation. The synthesized activated carbons (ACs) show an extremely high porosity (pore volume≈1.0 cm3 g−1) mostly composed of micropores (90 % of total pore volume). Because of their favorable textural properties, the ACs are further tested as electrodes for supercapacitors, yielding very promising results (300 F g−1 at 250 mA g−1) and confirming the high suitability of KOH-activated HTC carbons derived from spruce and corncob hydrolysis products as materials for electric double layer supercapacitors.
Fil: Falco, Camillo . Institute for Advanced Sustainability Studies; Alemania. Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; Alemania
Fil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingenieria Quimica. Instituto Ing.electroquimica y Corrosion; Argentina. Universidad de Alicante; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Brun, Nicolas . Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; Alemania
Fil: Sevilla, Marta . Consejo Superior de Investigaciones Cientificas; España
Fil: van der Mauelen, Torbjorn . Swedish Ethanol Chemistry AB E-Technology; Suecia
Fil: Morallón, Emilia . Universidad de Alicante; España
Fil: Cazorla Amorós, Diego . Universidad de Alicante; España
Fil: Titirici, Maria Magdalena . Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; Alemania
Materia
Biomass
Carbon
Green Chemistry
Microporous Materials
Supercapacitors
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/12448
Acceder
id CONICETDig_0a2bfe0203439eb8cd99811ba03c49a9
oai_identifier_str oai:ri.conicet.gov.ar:11336/12448
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for SupercapacitorsFalco, Camillo Sieben, Juan ManuelBrun, Nicolas Sevilla, Marta van der Mauelen, Torbjorn Morallón, Emilia Cazorla Amorós, Diego Titirici, Maria Magdalena BiomassCarbonGreen ChemistryMicroporous MaterialsSupercapacitorshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Acid pretreatment of lignocellulosic biomass, required for bioethanol production, generates large amounts of by-products, such as lignin and hydrolyzed hemicellulose fractions, which have found so far very limited applications. In this work, we demonstrate how the recovered hemicellulose hydrolysis products can be effectively utilized as a precursor for the synthesis of functional carbon materials through hydrothermal carbonization (HTC). The morphology and chemical structure of the synthesized HTC carbons are thoroughly characterized to highlight their similarities with glucose-derived HTC carbons. Furthermore, two routes for introducing porosity within the HTC carbon structure are presented: i) silica nanoparticle hard-templating, which is shown to be a viable method for the synthesis of carbonaceous hollow spheres; and ii) KOH chemical activation. The synthesized activated carbons (ACs) show an extremely high porosity (pore volume≈1.0 cm3 g−1) mostly composed of micropores (90 % of total pore volume). Because of their favorable textural properties, the ACs are further tested as electrodes for supercapacitors, yielding very promising results (300 F g−1 at 250 mA g−1) and confirming the high suitability of KOH-activated HTC carbons derived from spruce and corncob hydrolysis products as materials for electric double layer supercapacitors.Fil: Falco, Camillo . Institute for Advanced Sustainability Studies; Alemania. Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; AlemaniaFil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingenieria Quimica. Instituto Ing.electroquimica y Corrosion; Argentina. Universidad de Alicante; España. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Brun, Nicolas . Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; AlemaniaFil: Sevilla, Marta . Consejo Superior de Investigaciones Cientificas; EspañaFil: van der Mauelen, Torbjorn . Swedish Ethanol Chemistry AB E-Technology; SueciaFil: Morallón, Emilia . Universidad de Alicante; EspañaFil: Cazorla Amorós, Diego . Universidad de Alicante; EspañaFil: Titirici, Maria Magdalena . Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; AlemaniaWiley VCH Verlag2013-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/12448Falco, Camillo ; Sieben, Juan Manuel; Brun, Nicolas ; Sevilla, Marta ; van der Mauelen, Torbjorn ; et al.; Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors; Wiley VCH Verlag; Chemsuschem; 6; 2; 2-2013; 374-3821864-56311864-564Xenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/cssc.201200817/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/cssc.201200817info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:11:04Zoai:ri.conicet.gov.ar:11336/12448instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:11:04.299CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
title Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
spellingShingle Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
Falco, Camillo
Biomass
Carbon
Green Chemistry
Microporous Materials
Supercapacitors
title_short Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
title_full Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
title_fullStr Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
title_full_unstemmed Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
title_sort Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors
dc.creator.none.fl_str_mv Falco, Camillo
Sieben, Juan Manuel
Brun, Nicolas
Sevilla, Marta
van der Mauelen, Torbjorn
Morallón, Emilia
Cazorla Amorós, Diego
Titirici, Maria Magdalena
author Falco, Camillo
author_facet Falco, Camillo
Sieben, Juan Manuel
Brun, Nicolas
Sevilla, Marta
van der Mauelen, Torbjorn
Morallón, Emilia
Cazorla Amorós, Diego
Titirici, Maria Magdalena
author_role author
author2 Sieben, Juan Manuel
Brun, Nicolas
Sevilla, Marta
van der Mauelen, Torbjorn
Morallón, Emilia
Cazorla Amorós, Diego
Titirici, Maria Magdalena
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Biomass
Carbon
Green Chemistry
Microporous Materials
Supercapacitors
topic Biomass
Carbon
Green Chemistry
Microporous Materials
Supercapacitors
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Acid pretreatment of lignocellulosic biomass, required for bioethanol production, generates large amounts of by-products, such as lignin and hydrolyzed hemicellulose fractions, which have found so far very limited applications. In this work, we demonstrate how the recovered hemicellulose hydrolysis products can be effectively utilized as a precursor for the synthesis of functional carbon materials through hydrothermal carbonization (HTC). The morphology and chemical structure of the synthesized HTC carbons are thoroughly characterized to highlight their similarities with glucose-derived HTC carbons. Furthermore, two routes for introducing porosity within the HTC carbon structure are presented: i) silica nanoparticle hard-templating, which is shown to be a viable method for the synthesis of carbonaceous hollow spheres; and ii) KOH chemical activation. The synthesized activated carbons (ACs) show an extremely high porosity (pore volume≈1.0 cm3 g−1) mostly composed of micropores (90 % of total pore volume). Because of their favorable textural properties, the ACs are further tested as electrodes for supercapacitors, yielding very promising results (300 F g−1 at 250 mA g−1) and confirming the high suitability of KOH-activated HTC carbons derived from spruce and corncob hydrolysis products as materials for electric double layer supercapacitors.
Fil: Falco, Camillo . Institute for Advanced Sustainability Studies; Alemania. Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; Alemania
Fil: Sieben, Juan Manuel. Universidad Nacional del Sur. Departamento de Ingenieria Quimica. Instituto Ing.electroquimica y Corrosion; Argentina. Universidad de Alicante; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Brun, Nicolas . Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; Alemania
Fil: Sevilla, Marta . Consejo Superior de Investigaciones Cientificas; España
Fil: van der Mauelen, Torbjorn . Swedish Ethanol Chemistry AB E-Technology; Suecia
Fil: Morallón, Emilia . Universidad de Alicante; España
Fil: Cazorla Amorós, Diego . Universidad de Alicante; España
Fil: Titirici, Maria Magdalena . Max Planck Institute for Colloids and Interfaces. Colloid Chemistry; Alemania
description Acid pretreatment of lignocellulosic biomass, required for bioethanol production, generates large amounts of by-products, such as lignin and hydrolyzed hemicellulose fractions, which have found so far very limited applications. In this work, we demonstrate how the recovered hemicellulose hydrolysis products can be effectively utilized as a precursor for the synthesis of functional carbon materials through hydrothermal carbonization (HTC). The morphology and chemical structure of the synthesized HTC carbons are thoroughly characterized to highlight their similarities with glucose-derived HTC carbons. Furthermore, two routes for introducing porosity within the HTC carbon structure are presented: i) silica nanoparticle hard-templating, which is shown to be a viable method for the synthesis of carbonaceous hollow spheres; and ii) KOH chemical activation. The synthesized activated carbons (ACs) show an extremely high porosity (pore volume≈1.0 cm3 g−1) mostly composed of micropores (90 % of total pore volume). Because of their favorable textural properties, the ACs are further tested as electrodes for supercapacitors, yielding very promising results (300 F g−1 at 250 mA g−1) and confirming the high suitability of KOH-activated HTC carbons derived from spruce and corncob hydrolysis products as materials for electric double layer supercapacitors.
publishDate 2013
dc.date.none.fl_str_mv 2013-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/12448
Falco, Camillo ; Sieben, Juan Manuel; Brun, Nicolas ; Sevilla, Marta ; van der Mauelen, Torbjorn ; et al.; Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors; Wiley VCH Verlag; Chemsuschem; 6; 2; 2-2013; 374-382
1864-5631
1864-564X
url http://hdl.handle.net/11336/12448
identifier_str_mv Falco, Camillo ; Sieben, Juan Manuel; Brun, Nicolas ; Sevilla, Marta ; van der Mauelen, Torbjorn ; et al.; Hydrothermal Carbons from Hemicellulose-Derived Aqueous Hydrolysis Products as Electrode Materials for Supercapacitors; Wiley VCH Verlag; Chemsuschem; 6; 2; 2-2013; 374-382
1864-5631
1864-564X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/cssc.201200817/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/cssc.201200817
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842270143720194048
score 13.13397

Publicaciones similares