Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior

Autores
Pierella, Liliana Beatriz; Saux, Clara; Bertorello, Hector Raul; Bercoff, Paula Gabriela; Botta, Pablo Martín; Rivas, Jose
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Co-containing molecular sieves with MFI structure was synthesized by the hydrothermal crystallization method and cobalt was incorporated in it by wet impregnation at different percentages. Thermal post-treatments were applied to Co-ZSM-5: calcination and reduction. X ray diffraction (XRD) and FTIR studies confirmed crystallinity, structure and orthorhombic symmetry of the obtained samples (Co-ZSM-5 calcined and Co-ZSM-5 reduced). The XRD, Raman spectroscopy, SEM and TPR techniques for the calcined samples showed the presence of Co3O4 which diminished in the reduced samples and Co0 appeared. The magnetic behavior of the materials was evaluated by magnetization (M) variation with applied magnetic field (H) at different temperatures. Low magnetization is observed in the calcined samples while high values are ttained in the reduced samples, due to the presence of metallic Co.
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Saux, Clara. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Bertorello, Hector Raul. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Universidad de Santiago de Compostela; España
Fil: Rivas, Jose. Universidad de Santiago de Compostela; España
Materia
Microporous Materials
Magnetic Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/40595
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/40595
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behaviorPierella, Liliana BeatrizSaux, ClaraBertorello, Hector RaulBercoff, Paula GabrielaBotta, Pablo MartínRivas, JoseMicroporous MaterialsMagnetic Propertieshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Co-containing molecular sieves with MFI structure was synthesized by the hydrothermal crystallization method and cobalt was incorporated in it by wet impregnation at different percentages. Thermal post-treatments were applied to Co-ZSM-5: calcination and reduction. X ray diffraction (XRD) and FTIR studies confirmed crystallinity, structure and orthorhombic symmetry of the obtained samples (Co-ZSM-5 calcined and Co-ZSM-5 reduced). The XRD, Raman spectroscopy, SEM and TPR techniques for the calcined samples showed the presence of Co3O4 which diminished in the reduced samples and Co0 appeared. The magnetic behavior of the materials was evaluated by magnetization (M) variation with applied magnetic field (H) at different temperatures. Low magnetization is observed in the calcined samples while high values are ttained in the reduced samples, due to the presence of metallic Co.Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Saux, Clara. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Bertorello, Hector Raul. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Universidad de Santiago de Compostela; EspañaFil: Rivas, Jose. Universidad de Santiago de Compostela; EspañaPergamon-Elsevier Science Ltd2007-10-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40595Pierella, Liliana Beatriz; Saux, Clara; Bertorello, Hector Raul; Bercoff, Paula Gabriela; Botta, Pablo Martín; et al.; Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 43; 8-9; 5-10-2007; 2026-20350025-5408CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2007.09.026info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S002554080700428Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:28Zoai:ri.conicet.gov.ar:11336/40595instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:28.656CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
title Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
spellingShingle Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
Pierella, Liliana Beatriz
Microporous Materials
Magnetic Properties
title_short Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
title_full Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
title_fullStr Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
title_full_unstemmed Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
title_sort Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior
dc.creator.none.fl_str_mv Pierella, Liliana Beatriz
Saux, Clara
Bertorello, Hector Raul
Bercoff, Paula Gabriela
Botta, Pablo Martín
Rivas, Jose
author Pierella, Liliana Beatriz
author_facet Pierella, Liliana Beatriz
Saux, Clara
Bertorello, Hector Raul
Bercoff, Paula Gabriela
Botta, Pablo Martín
Rivas, Jose
author_role author
author2 Saux, Clara
Bertorello, Hector Raul
Bercoff, Paula Gabriela
Botta, Pablo Martín
Rivas, Jose
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Microporous Materials
Magnetic Properties
topic Microporous Materials
Magnetic Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Co-containing molecular sieves with MFI structure was synthesized by the hydrothermal crystallization method and cobalt was incorporated in it by wet impregnation at different percentages. Thermal post-treatments were applied to Co-ZSM-5: calcination and reduction. X ray diffraction (XRD) and FTIR studies confirmed crystallinity, structure and orthorhombic symmetry of the obtained samples (Co-ZSM-5 calcined and Co-ZSM-5 reduced). The XRD, Raman spectroscopy, SEM and TPR techniques for the calcined samples showed the presence of Co3O4 which diminished in the reduced samples and Co0 appeared. The magnetic behavior of the materials was evaluated by magnetization (M) variation with applied magnetic field (H) at different temperatures. Low magnetization is observed in the calcined samples while high values are ttained in the reduced samples, due to the presence of metallic Co.
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Saux, Clara. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Bertorello, Hector Raul. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina. Universidad de Santiago de Compostela; España
Fil: Rivas, Jose. Universidad de Santiago de Compostela; España
description Co-containing molecular sieves with MFI structure was synthesized by the hydrothermal crystallization method and cobalt was incorporated in it by wet impregnation at different percentages. Thermal post-treatments were applied to Co-ZSM-5: calcination and reduction. X ray diffraction (XRD) and FTIR studies confirmed crystallinity, structure and orthorhombic symmetry of the obtained samples (Co-ZSM-5 calcined and Co-ZSM-5 reduced). The XRD, Raman spectroscopy, SEM and TPR techniques for the calcined samples showed the presence of Co3O4 which diminished in the reduced samples and Co0 appeared. The magnetic behavior of the materials was evaluated by magnetization (M) variation with applied magnetic field (H) at different temperatures. Low magnetization is observed in the calcined samples while high values are ttained in the reduced samples, due to the presence of metallic Co.
publishDate 2007
dc.date.none.fl_str_mv 2007-10-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/40595
Pierella, Liliana Beatriz; Saux, Clara; Bertorello, Hector Raul; Bercoff, Paula Gabriela; Botta, Pablo Martín; et al.; Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 43; 8-9; 5-10-2007; 2026-2035
0025-5408
CONICET Digital
CONICET
url http://hdl.handle.net/11336/40595
identifier_str_mv Pierella, Liliana Beatriz; Saux, Clara; Bertorello, Hector Raul; Bercoff, Paula Gabriela; Botta, Pablo Martín; et al.; Occluded cobalt species over ZSM-5 matrix: Design, preparation, characterization and magnetic behavior; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 43; 8-9; 5-10-2007; 2026-2035
0025-5408
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2007.09.026
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S002554080700428X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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