Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor

Autores
Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption.
Fil: Ramos, María Eva. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ribeiro Carrott, M. M. L.. Universidade de Évora; Portugal
Fil: Carrott, P. J. M.. Universidade de Évora; Portugal
Materia
Activated Carbon Cloths
Microporous Materials
Surface Properties
Volatile Oranic Compounds Adsorption
Electrocheial Regeneration
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/16489
Acceder
id CONICETDig_b4c2abbd908453264c3e12c9eed8a078
oai_identifier_str oai:ri.conicet.gov.ar:11336/16489
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursorRamos, María EvaBonelli, Pablo RicardoCukierman, Ana LeaRibeiro Carrott, M. M. L.Carrott, P. J. M.Activated Carbon ClothsMicroporous MaterialsSurface PropertiesVolatile Oranic Compounds AdsorptionElectrocheial Regenerationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption.Fil: Ramos, María Eva. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ribeiro Carrott, M. M. L.. Universidade de Évora; PortugalFil: Carrott, P. J. M.. Universidade de Évora; PortugalElsevier Science2010-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/16489Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.; Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor; Elsevier Science; Journal Of Hazardous Materials; 177; 1-3; 5-2010; 175-1820304-3894enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jhazmat.2009.12.014info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0304389409019852info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:27:31Zoai:ri.conicet.gov.ar:11336/16489instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:27:31.635CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
title Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
spellingShingle Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
Ramos, María Eva
Activated Carbon Cloths
Microporous Materials
Surface Properties
Volatile Oranic Compounds Adsorption
Electrocheial Regeneration
title_short Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
title_full Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
title_fullStr Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
title_full_unstemmed Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
title_sort Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
dc.creator.none.fl_str_mv Ramos, María Eva
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
Ribeiro Carrott, M. M. L.
Carrott, P. J. M.
author Ramos, María Eva
author_facet Ramos, María Eva
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
Ribeiro Carrott, M. M. L.
Carrott, P. J. M.
author_role author
author2 Bonelli, Pablo Ricardo
Cukierman, Ana Lea
Ribeiro Carrott, M. M. L.
Carrott, P. J. M.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Activated Carbon Cloths
Microporous Materials
Surface Properties
Volatile Oranic Compounds Adsorption
Electrocheial Regeneration
topic Activated Carbon Cloths
Microporous Materials
Surface Properties
Volatile Oranic Compounds Adsorption
Electrocheial Regeneration
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption.
Fil: Ramos, María Eva. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ribeiro Carrott, M. M. L.. Universidade de Évora; Portugal
Fil: Carrott, P. J. M.. Universidade de Évora; Portugal
description Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption.
publishDate 2010
dc.date.none.fl_str_mv 2010-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/16489
Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.; Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor; Elsevier Science; Journal Of Hazardous Materials; 177; 1-3; 5-2010; 175-182
0304-3894
url http://hdl.handle.net/11336/16489
identifier_str_mv Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.; Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor; Elsevier Science; Journal Of Hazardous Materials; 177; 1-3; 5-2010; 175-182
0304-3894
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jhazmat.2009.12.014
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0304389409019852
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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