Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor
- Autores
- Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption.
Fil: Ramos, María Eva. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ribeiro Carrott, M. M. L.. Universidade de Évora; Portugal
Fil: Carrott, P. J. M.. Universidade de Évora; Portugal - Materia
-
Activated Carbon Cloths
Microporous Materials
Surface Properties
Volatile Oranic Compounds Adsorption
Electrocheial Regeneration - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/16489
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Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursorRamos, María EvaBonelli, Pablo RicardoCukierman, Ana LeaRibeiro Carrott, M. M. L.Carrott, P. J. M.Activated Carbon ClothsMicroporous MaterialsSurface PropertiesVolatile Oranic Compounds AdsorptionElectrocheial Regenerationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption.Fil: Ramos, María Eva. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ribeiro Carrott, M. M. L.. Universidade de Évora; PortugalFil: Carrott, P. J. M.. Universidade de Évora; PortugalElsevier Science2010-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/16489Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.; Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor; Elsevier Science; Journal Of Hazardous Materials; 177; 1-3; 5-2010; 175-1820304-3894enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jhazmat.2009.12.014info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0304389409019852info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:05:41Zoai:ri.conicet.gov.ar:11336/16489instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:05:41.516CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor |
title |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor |
spellingShingle |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor Ramos, María Eva Activated Carbon Cloths Microporous Materials Surface Properties Volatile Oranic Compounds Adsorption Electrocheial Regeneration |
title_short |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor |
title_full |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor |
title_fullStr |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor |
title_full_unstemmed |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor |
title_sort |
Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor |
dc.creator.none.fl_str_mv |
Ramos, María Eva Bonelli, Pablo Ricardo Cukierman, Ana Lea Ribeiro Carrott, M. M. L. Carrott, P. J. M. |
author |
Ramos, María Eva |
author_facet |
Ramos, María Eva Bonelli, Pablo Ricardo Cukierman, Ana Lea Ribeiro Carrott, M. M. L. Carrott, P. J. M. |
author_role |
author |
author2 |
Bonelli, Pablo Ricardo Cukierman, Ana Lea Ribeiro Carrott, M. M. L. Carrott, P. J. M. |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Activated Carbon Cloths Microporous Materials Surface Properties Volatile Oranic Compounds Adsorption Electrocheial Regeneration |
topic |
Activated Carbon Cloths Microporous Materials Surface Properties Volatile Oranic Compounds Adsorption Electrocheial Regeneration |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption. Fil: Ramos, María Eva. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Ribeiro Carrott, M. M. L.. Universidade de Évora; Portugal Fil: Carrott, P. J. M.. Universidade de Évora; Portugal |
description |
Activated carbon cloths (ACC) were prepared from lyocell, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in inert atmosphere at two different final thermal treatment temperatures (864 and 963 °C). Benzene, toluene and n-hexane isotherms at 298 and 273 K were measured in order to gain insight into the porous structure of the ACC and to evaluate their performance for the removal of volatile organic compounds (VOCs). The Dubinin–Radushkevich equation was employed to evaluate textural parameters of the ACC. The textural characteristics of the ACC were compared with those previously determined from nitrogen (77 K) and carbon dioxide (273 K) adsorption data. The samples were essentially microporous. The textural parameters calculated from the hydrocarbon isotherms were in good agreement with those evaluated from nitrogen isotherms for the ACC with the wider microporosity. Additionally, the Freundlich model provided a good description of the experimental isotherms for the three volatile organic compounds. The ACC obtained at the higher temperature exhibited a larger adsorption capacity. The ACC were also electrically conductive and showed potential for regeneration by the Joule effect, as determined from macroscopic electrical measurements before and after n-hexane adsorption. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/16489 Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.; Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor; Elsevier Science; Journal Of Hazardous Materials; 177; 1-3; 5-2010; 175-182 0304-3894 |
url |
http://hdl.handle.net/11336/16489 |
identifier_str_mv |
Ramos, María Eva; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Ribeiro Carrott, M. M. L.; Carrott, P. J. M.; Adsorption of volatile organic compounds onto activated carbon cloths derived from a novel regenerated cellulosic precursor; Elsevier Science; Journal Of Hazardous Materials; 177; 1-3; 5-2010; 175-182 0304-3894 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jhazmat.2009.12.014 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0304389409019852 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269923355656192 |
score |
13.13397 |