Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films

Autores
Manfredi, Liliana Beatriz; Ginés, M. J. L.; Benftez, G. J.; Egli, Walter Alfredo; Rissone, H.; Vázquez, Analía
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Liquid and cured epoxy-phenolic lacquers used as can coatings were characterized. Tinplate was used as the base material, which was coated with lacquers of different epoxy to phenolic ratios (EPRs) from a commercial source. Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) were used together to obtain helpful information about the degree of curing and the composition of the lacquers. From FTIR analysis, we were able to infer that the lacquers were composed of a high-molecular-weight diglycidyl ether of bisphenol A type epoxy resin and a resol-type phenolic resin. In addition, from FTIR spectra, we estimated the EPRs of lacquers applied on the tinplate and detected if they had been overcured. The EPRs of the applied lacquers were estimated also from DSC analysis. From TGA, we detected undercuring in the applied lacquers. © 2005 Wiley Periodicals, Inc.
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ginés, M. J. L.. Centro de Investigacion Industrial; Argentina
Fil: Benftez, G. J.. Centro de Investigacion Industrial; Argentina
Fil: Egli, Walter Alfredo. SIDERAR; Argentina
Fil: Rissone, H.. SIDERAR; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Calorimetry
Coatings
Infrared Spectroscopy
Thermogravimetric Analysis (Tga)
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70449

id CONICETDig_73822ba27223f40a061ae1715fb16b3a
oai_identifier_str oai:ri.conicet.gov.ar:11336/70449
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured filmsManfredi, Liliana BeatrizGinés, M. J. L.Benftez, G. J.Egli, Walter AlfredoRissone, H.Vázquez, AnalíaCalorimetryCoatingsInfrared SpectroscopyThermogravimetric Analysis (Tga)https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Liquid and cured epoxy-phenolic lacquers used as can coatings were characterized. Tinplate was used as the base material, which was coated with lacquers of different epoxy to phenolic ratios (EPRs) from a commercial source. Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) were used together to obtain helpful information about the degree of curing and the composition of the lacquers. From FTIR analysis, we were able to infer that the lacquers were composed of a high-molecular-weight diglycidyl ether of bisphenol A type epoxy resin and a resol-type phenolic resin. In addition, from FTIR spectra, we estimated the EPRs of lacquers applied on the tinplate and detected if they had been overcured. The EPRs of the applied lacquers were estimated also from DSC analysis. From TGA, we detected undercuring in the applied lacquers. © 2005 Wiley Periodicals, Inc.Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ginés, M. J. L.. Centro de Investigacion Industrial; ArgentinaFil: Benftez, G. J.. Centro de Investigacion Industrial; ArgentinaFil: Egli, Walter Alfredo. SIDERAR; ArgentinaFil: Rissone, H.. SIDERAR; ArgentinaFil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2005-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70449Manfredi, Liliana Beatriz; Ginés, M. J. L.; Benftez, G. J.; Egli, Walter Alfredo; Rissone, H.; et al.; Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films; John Wiley & Sons Inc; Journal of Applied Polymer Science; 95; 6; 3-2005; 1448-14580021-8995CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.21389info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.21389info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:24:47Zoai:ri.conicet.gov.ar:11336/70449instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:24:47.354CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
title Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
spellingShingle Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
Manfredi, Liliana Beatriz
Calorimetry
Coatings
Infrared Spectroscopy
Thermogravimetric Analysis (Tga)
title_short Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
title_full Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
title_fullStr Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
title_full_unstemmed Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
title_sort Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films
dc.creator.none.fl_str_mv Manfredi, Liliana Beatriz
Ginés, M. J. L.
Benftez, G. J.
Egli, Walter Alfredo
Rissone, H.
Vázquez, Analía
author Manfredi, Liliana Beatriz
author_facet Manfredi, Liliana Beatriz
Ginés, M. J. L.
Benftez, G. J.
Egli, Walter Alfredo
Rissone, H.
Vázquez, Analía
author_role author
author2 Ginés, M. J. L.
Benftez, G. J.
Egli, Walter Alfredo
Rissone, H.
Vázquez, Analía
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Calorimetry
Coatings
Infrared Spectroscopy
Thermogravimetric Analysis (Tga)
topic Calorimetry
Coatings
Infrared Spectroscopy
Thermogravimetric Analysis (Tga)
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Liquid and cured epoxy-phenolic lacquers used as can coatings were characterized. Tinplate was used as the base material, which was coated with lacquers of different epoxy to phenolic ratios (EPRs) from a commercial source. Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) were used together to obtain helpful information about the degree of curing and the composition of the lacquers. From FTIR analysis, we were able to infer that the lacquers were composed of a high-molecular-weight diglycidyl ether of bisphenol A type epoxy resin and a resol-type phenolic resin. In addition, from FTIR spectra, we estimated the EPRs of lacquers applied on the tinplate and detected if they had been overcured. The EPRs of the applied lacquers were estimated also from DSC analysis. From TGA, we detected undercuring in the applied lacquers. © 2005 Wiley Periodicals, Inc.
Fil: Manfredi, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ginés, M. J. L.. Centro de Investigacion Industrial; Argentina
Fil: Benftez, G. J.. Centro de Investigacion Industrial; Argentina
Fil: Egli, Walter Alfredo. SIDERAR; Argentina
Fil: Rissone, H.. SIDERAR; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Liquid and cured epoxy-phenolic lacquers used as can coatings were characterized. Tinplate was used as the base material, which was coated with lacquers of different epoxy to phenolic ratios (EPRs) from a commercial source. Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) were used together to obtain helpful information about the degree of curing and the composition of the lacquers. From FTIR analysis, we were able to infer that the lacquers were composed of a high-molecular-weight diglycidyl ether of bisphenol A type epoxy resin and a resol-type phenolic resin. In addition, from FTIR spectra, we estimated the EPRs of lacquers applied on the tinplate and detected if they had been overcured. The EPRs of the applied lacquers were estimated also from DSC analysis. From TGA, we detected undercuring in the applied lacquers. © 2005 Wiley Periodicals, Inc.
publishDate 2005
dc.date.none.fl_str_mv 2005-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70449
Manfredi, Liliana Beatriz; Ginés, M. J. L.; Benftez, G. J.; Egli, Walter Alfredo; Rissone, H.; et al.; Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films; John Wiley & Sons Inc; Journal of Applied Polymer Science; 95; 6; 3-2005; 1448-1458
0021-8995
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70449
identifier_str_mv Manfredi, Liliana Beatriz; Ginés, M. J. L.; Benftez, G. J.; Egli, Walter Alfredo; Rissone, H.; et al.; Use of epoxy-phenolic lacquers in food can coatings: Characterization of lacquers and cured films; John Wiley & Sons Inc; Journal of Applied Polymer Science; 95; 6; 3-2005; 1448-1458
0021-8995
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/app.21389
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.21389
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614244980490240
score 13.070432