Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite

Autores
Gil, Diego Mauricio; Nieva, Gladys Leonor; Franco, Diego Gaspar; Gómez, María Inés; Carbonio, Raul Ernesto
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In order to investigate the formation of multiferroic oxide Pb2Fe2O5, the thermal decomposition of Pb[Fe(CN)5NO] has been studied. The complex precursor and the thermal decomposition products were characterized by IR and Raman spectroscopy, thermal analysis, powder X-ray diffraction (PXRD), scanning electron microscopy and magnetic measurements. The crystal structure of Pb[Fe(CN)5NO] was refined by Rietveld analysis. It crystallizes in the orthorhombic system, space group Pnma. The thermal  decomposition in air produces highly pure Pb2Fe2O5 as final product. This oxide is an anion deficient perovskite with an incommensurate superstructure. The magnetic measurements confirm that Pb2Fe2O5 shows a weak ferromagnetic signal probably due to disorder in the perfect antiferromagnetic structure or spin canting. The estimated ordering temperature from the fit of a phenomenological model was 520 K. The SEM images reveal that the thermal decomposition of Pb[Fe(CN)5NO] produces Pb2Fe2O5 with small particle size.

Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquimica, Quimica y Farmacia. Instituto de Quimica Inorganica; Argentina
Fil: Nieva, Gladys Leonor. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (centro Atómico Bariloche); Argentina
Fil: Franco, Diego Gaspar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina
Fil: Gómez, María Inés. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica; Argentina
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones en Físicoquímica de Córdoba; Argentina
Materia
Inorganic Compounds
Magnetic Materials
Powder Diffraction
Thermogravimetric Analysis (Tga)
Magnetic Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/7410
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/7410
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskiteGil, Diego MauricioNieva, Gladys LeonorFranco, Diego GasparGómez, María InésCarbonio, Raul ErnestoInorganic CompoundsMagnetic MaterialsPowder DiffractionThermogravimetric Analysis (Tga)Magnetic Propertieshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In order to investigate the formation of multiferroic oxide Pb2Fe2O5, the thermal decomposition of Pb[Fe(CN)5NO] has been studied. The complex precursor and the thermal decomposition products were characterized by IR and Raman spectroscopy, thermal analysis, powder X-ray diffraction (PXRD), scanning electron microscopy and magnetic measurements. The crystal structure of Pb[Fe(CN)5NO] was refined by Rietveld analysis. It crystallizes in the orthorhombic system, space group Pnma. The thermal  decomposition in air produces highly pure Pb2Fe2O5 as final product. This oxide is an anion deficient perovskite with an incommensurate superstructure. The magnetic measurements confirm that Pb2Fe2O5 shows a weak ferromagnetic signal probably due to disorder in the perfect antiferromagnetic structure or spin canting. The estimated ordering temperature from the fit of a phenomenological model was 520 K. The SEM images reveal that the thermal decomposition of Pb[Fe(CN)5NO] produces Pb2Fe2O5 with small particle size.<br />Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquimica, Quimica y Farmacia. Instituto de Quimica Inorganica; ArgentinaFil: Nieva, Gladys Leonor. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (centro Atómico Bariloche); ArgentinaFil: Franco, Diego Gaspar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); ArgentinaFil: Gómez, María Inés. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica; ArgentinaFil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones en Físicoquímica de Córdoba; ArgentinaElsevier2013-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/7410Gil, Diego Mauricio; Nieva, Gladys Leonor; Franco, Diego Gaspar; Gómez, María Inés; Carbonio, Raul Ernesto; Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite; Elsevier; Materials Chemistry And Physics; 141; 1; 4-2013; 355-3610254-0584enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0254058413003921info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2013.05.022info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:03Zoai:ri.conicet.gov.ar:11336/7410instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:03.646CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
title Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
spellingShingle Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
Gil, Diego Mauricio
Inorganic Compounds
Magnetic Materials
Powder Diffraction
Thermogravimetric Analysis (Tga)
Magnetic Properties
title_short Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
title_full Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
title_fullStr Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
title_full_unstemmed Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
title_sort Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite
dc.creator.none.fl_str_mv Gil, Diego Mauricio
Nieva, Gladys Leonor
Franco, Diego Gaspar
Gómez, María Inés
Carbonio, Raul Ernesto
author Gil, Diego Mauricio
author_facet Gil, Diego Mauricio
Nieva, Gladys Leonor
Franco, Diego Gaspar
Gómez, María Inés
Carbonio, Raul Ernesto
author_role author
author2 Nieva, Gladys Leonor
Franco, Diego Gaspar
Gómez, María Inés
Carbonio, Raul Ernesto
author2_role author
author
author
author
dc.subject.none.fl_str_mv Inorganic Compounds
Magnetic Materials
Powder Diffraction
Thermogravimetric Analysis (Tga)
Magnetic Properties
topic Inorganic Compounds
Magnetic Materials
Powder Diffraction
Thermogravimetric Analysis (Tga)
Magnetic Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In order to investigate the formation of multiferroic oxide Pb2Fe2O5, the thermal decomposition of Pb[Fe(CN)5NO] has been studied. The complex precursor and the thermal decomposition products were characterized by IR and Raman spectroscopy, thermal analysis, powder X-ray diffraction (PXRD), scanning electron microscopy and magnetic measurements. The crystal structure of Pb[Fe(CN)5NO] was refined by Rietveld analysis. It crystallizes in the orthorhombic system, space group Pnma. The thermal  decomposition in air produces highly pure Pb2Fe2O5 as final product. This oxide is an anion deficient perovskite with an incommensurate superstructure. The magnetic measurements confirm that Pb2Fe2O5 shows a weak ferromagnetic signal probably due to disorder in the perfect antiferromagnetic structure or spin canting. The estimated ordering temperature from the fit of a phenomenological model was 520 K. The SEM images reveal that the thermal decomposition of Pb[Fe(CN)5NO] produces Pb2Fe2O5 with small particle size.<br />
Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquimica, Quimica y Farmacia. Instituto de Quimica Inorganica; Argentina
Fil: Nieva, Gladys Leonor. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (centro Atómico Bariloche); Argentina
Fil: Franco, Diego Gaspar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones En Físicoquímica de Córdoba; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina
Fil: Gómez, María Inés. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Orgánica; Argentina
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones en Físicoquímica de Córdoba; Argentina
description In order to investigate the formation of multiferroic oxide Pb2Fe2O5, the thermal decomposition of Pb[Fe(CN)5NO] has been studied. The complex precursor and the thermal decomposition products were characterized by IR and Raman spectroscopy, thermal analysis, powder X-ray diffraction (PXRD), scanning electron microscopy and magnetic measurements. The crystal structure of Pb[Fe(CN)5NO] was refined by Rietveld analysis. It crystallizes in the orthorhombic system, space group Pnma. The thermal  decomposition in air produces highly pure Pb2Fe2O5 as final product. This oxide is an anion deficient perovskite with an incommensurate superstructure. The magnetic measurements confirm that Pb2Fe2O5 shows a weak ferromagnetic signal probably due to disorder in the perfect antiferromagnetic structure or spin canting. The estimated ordering temperature from the fit of a phenomenological model was 520 K. The SEM images reveal that the thermal decomposition of Pb[Fe(CN)5NO] produces Pb2Fe2O5 with small particle size.<br />
publishDate 2013
dc.date.none.fl_str_mv 2013-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/7410
Gil, Diego Mauricio; Nieva, Gladys Leonor; Franco, Diego Gaspar; Gómez, María Inés; Carbonio, Raul Ernesto; Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite; Elsevier; Materials Chemistry And Physics; 141; 1; 4-2013; 355-361
0254-0584
url http://hdl.handle.net/11336/7410
identifier_str_mv Gil, Diego Mauricio; Nieva, Gladys Leonor; Franco, Diego Gaspar; Gómez, María Inés; Carbonio, Raul Ernesto; Lead nitroprusside: A new precursor for the synthesis of the multiferroic Pb2Fe2O5, an anion-deficient perovskite; Elsevier; Materials Chemistry And Physics; 141; 1; 4-2013; 355-361
0254-0584
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0254058413003921
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2013.05.022
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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