Smart and structural thermosets from the cationic copolymerization of a vegetable oil

Autores
Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Copolymers based on tung oil (TO) and presenting a very wide range of properties were obtained. Depending on the chemical composition, materials fitted for structural or functional applications were prepared. The use of divinylbenzene (DVB) as a comonomer in the cationic polymerization of the triglyceride allowed us to obtain polymers with a high thermal stability in an ample temperature range and with a room-temperature modulus close to 1 GPa for percentages of TO up to 40 wt % styrene (St) as a partial replacement of DVB in a copolymer containing 50 wt % TO resulted in a material with shape-memory behavior with switch temperatures in the range 25-40°C. The mechanical properties and shape-memory behavior of copolymers with different chemical compositions were analyzed. It was observed that an increase in the DVB content increased the glass-transition temperature and modulus, which was associated with an increase in the crosslinking density and the contribution of the rigid aromatic structure of the comonomer.
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Cationic Polymerization
Copolymers
Mechanical Properties
Renewable Resources
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/54196
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/54196
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Smart and structural thermosets from the cationic copolymerization of a vegetable oilMeiorin, CintiaAranguren, Mirta InesMosiewicki, Mirna AlejandraCationic PolymerizationCopolymersMechanical PropertiesRenewable Resourceshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Copolymers based on tung oil (TO) and presenting a very wide range of properties were obtained. Depending on the chemical composition, materials fitted for structural or functional applications were prepared. The use of divinylbenzene (DVB) as a comonomer in the cationic polymerization of the triglyceride allowed us to obtain polymers with a high thermal stability in an ample temperature range and with a room-temperature modulus close to 1 GPa for percentages of TO up to 40 wt % styrene (St) as a partial replacement of DVB in a copolymer containing 50 wt % TO resulted in a material with shape-memory behavior with switch temperatures in the range 25-40°C. The mechanical properties and shape-memory behavior of copolymers with different chemical compositions were analyzed. It was observed that an increase in the DVB content increased the glass-transition temperature and modulus, which was associated with an increase in the crosslinking density and the contribution of the rigid aromatic structure of the comonomer.Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2012-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54196Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Smart and structural thermosets from the cationic copolymerization of a vegetable oil; John Wiley & Sons Inc; Journal of Applied Polymer Science; 124; 6; 6-2012; 5071-50780021-8995CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.35630info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.35630info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:47:24Zoai:ri.conicet.gov.ar:11336/54196instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:47:24.481CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Smart and structural thermosets from the cationic copolymerization of a vegetable oil
title Smart and structural thermosets from the cationic copolymerization of a vegetable oil
spellingShingle Smart and structural thermosets from the cationic copolymerization of a vegetable oil
Meiorin, Cintia
Cationic Polymerization
Copolymers
Mechanical Properties
Renewable Resources
title_short Smart and structural thermosets from the cationic copolymerization of a vegetable oil
title_full Smart and structural thermosets from the cationic copolymerization of a vegetable oil
title_fullStr Smart and structural thermosets from the cationic copolymerization of a vegetable oil
title_full_unstemmed Smart and structural thermosets from the cationic copolymerization of a vegetable oil
title_sort Smart and structural thermosets from the cationic copolymerization of a vegetable oil
dc.creator.none.fl_str_mv Meiorin, Cintia
Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author Meiorin, Cintia
author_facet Meiorin, Cintia
Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author_role author
author2 Aranguren, Mirta Ines
Mosiewicki, Mirna Alejandra
author2_role author
author
dc.subject.none.fl_str_mv Cationic Polymerization
Copolymers
Mechanical Properties
Renewable Resources
topic Cationic Polymerization
Copolymers
Mechanical Properties
Renewable Resources
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Copolymers based on tung oil (TO) and presenting a very wide range of properties were obtained. Depending on the chemical composition, materials fitted for structural or functional applications were prepared. The use of divinylbenzene (DVB) as a comonomer in the cationic polymerization of the triglyceride allowed us to obtain polymers with a high thermal stability in an ample temperature range and with a room-temperature modulus close to 1 GPa for percentages of TO up to 40 wt % styrene (St) as a partial replacement of DVB in a copolymer containing 50 wt % TO resulted in a material with shape-memory behavior with switch temperatures in the range 25-40°C. The mechanical properties and shape-memory behavior of copolymers with different chemical compositions were analyzed. It was observed that an increase in the DVB content increased the glass-transition temperature and modulus, which was associated with an increase in the crosslinking density and the contribution of the rigid aromatic structure of the comonomer.
Fil: Meiorin, Cintia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aranguren, Mirta Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mosiewicki, Mirna Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Copolymers based on tung oil (TO) and presenting a very wide range of properties were obtained. Depending on the chemical composition, materials fitted for structural or functional applications were prepared. The use of divinylbenzene (DVB) as a comonomer in the cationic polymerization of the triglyceride allowed us to obtain polymers with a high thermal stability in an ample temperature range and with a room-temperature modulus close to 1 GPa for percentages of TO up to 40 wt % styrene (St) as a partial replacement of DVB in a copolymer containing 50 wt % TO resulted in a material with shape-memory behavior with switch temperatures in the range 25-40°C. The mechanical properties and shape-memory behavior of copolymers with different chemical compositions were analyzed. It was observed that an increase in the DVB content increased the glass-transition temperature and modulus, which was associated with an increase in the crosslinking density and the contribution of the rigid aromatic structure of the comonomer.
publishDate 2012
dc.date.none.fl_str_mv 2012-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/54196
Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Smart and structural thermosets from the cationic copolymerization of a vegetable oil; John Wiley & Sons Inc; Journal of Applied Polymer Science; 124; 6; 6-2012; 5071-5078
0021-8995
CONICET Digital
CONICET
url http://hdl.handle.net/11336/54196
identifier_str_mv Meiorin, Cintia; Aranguren, Mirta Ines; Mosiewicki, Mirna Alejandra; Smart and structural thermosets from the cationic copolymerization of a vegetable oil; John Wiley & Sons Inc; Journal of Applied Polymer Science; 124; 6; 6-2012; 5071-5078
0021-8995
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/app.35630
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.35630
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.084122

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