Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents

Autores
Lopez de Lacalle, Jon; Minudri, Daniela; Picchio, Matías Luis; Gallastegui, Antonela; Mantione, Daniele; Forsyth, Maria Silvia; Mecerreyes, David
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The mitigation of corrosion, especially in coastal regions, stands as a significant social concern necessitating the exploration of environmentally friendly materials. This study introduces phenol-based ionic polymers as both coatings and solution corrosion inhibitors for mild steel. Three methacrylated phenolic deep eutectic monomers (DEMs) bearing catechol and gallol motifs were synthetized for this purpose, taking advantage of polyphenol chemistry. Both the polyphenol DEMs and the UV-photopolymerized ionic polymer coatings formed coordination complexes with iron ions on the surface of the mild steel, resulting in a distinctive colour evolution, transitioning from a non-coloured film to dark purple, characterized by optical imaging and UV-vis absorption analysis. The resulting interfacial complex layer demonstrated exceptional corrosion inhibition efficiency for tannic acid and protocatechuic acid based polymers, achieving efficiencies of 99.84% and 99.54% respectively. Further explanation of this phenomenon involves the investigation of phenolic deep eutectic monomers in solution as model compounds, revealing a purple hue in the solution arising from the complexation between the polyphenol chemistry and the iron ions leached from the steel surface.
Fil: Lopez de Lacalle, Jon. Universidad del Pais Vasco. Polymat.; España
Fil: Minudri, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad del Pais Vasco. Polymat.; España
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gallastegui, Antonela. Universidad del Pais Vasco. Polymat.; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mantione, Daniele. Universidad del Pais Vasco. Polymat.; España
Fil: Forsyth, Maria Silvia. Universidad del Pais Vasco. Polymat.; España
Fil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; España
Materia
Polymeric eutctic solvents
Polyphenols
Anticorrosion coatings
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/265477
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/265477
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solventsLopez de Lacalle, JonMinudri, DanielaPicchio, Matías LuisGallastegui, AntonelaMantione, DanieleForsyth, Maria SilviaMecerreyes, DavidPolymeric eutctic solventsPolyphenolsAnticorrosion coatingshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The mitigation of corrosion, especially in coastal regions, stands as a significant social concern necessitating the exploration of environmentally friendly materials. This study introduces phenol-based ionic polymers as both coatings and solution corrosion inhibitors for mild steel. Three methacrylated phenolic deep eutectic monomers (DEMs) bearing catechol and gallol motifs were synthetized for this purpose, taking advantage of polyphenol chemistry. Both the polyphenol DEMs and the UV-photopolymerized ionic polymer coatings formed coordination complexes with iron ions on the surface of the mild steel, resulting in a distinctive colour evolution, transitioning from a non-coloured film to dark purple, characterized by optical imaging and UV-vis absorption analysis. The resulting interfacial complex layer demonstrated exceptional corrosion inhibition efficiency for tannic acid and protocatechuic acid based polymers, achieving efficiencies of 99.84% and 99.54% respectively. Further explanation of this phenomenon involves the investigation of phenolic deep eutectic monomers in solution as model compounds, revealing a purple hue in the solution arising from the complexation between the polyphenol chemistry and the iron ions leached from the steel surface.Fil: Lopez de Lacalle, Jon. Universidad del Pais Vasco. Polymat.; EspañaFil: Minudri, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad del Pais Vasco. Polymat.; EspañaFil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Gallastegui, Antonela. Universidad del Pais Vasco. Polymat.; España. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mantione, Daniele. Universidad del Pais Vasco. Polymat.; EspañaFil: Forsyth, Maria Silvia. Universidad del Pais Vasco. Polymat.; EspañaFil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; EspañaRoyal Society of Chemistry2024-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/265477Lopez de Lacalle, Jon; Minudri, Daniela; Picchio, Matías Luis; Gallastegui, Antonela; Mantione, Daniele; et al.; Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents; Royal Society of Chemistry; RSC Sustainability; 2; 6; 4-2024; 1809-18182753-8125CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D4SU00117Finfo:eu-repo/semantics/altIdentifier/doi/10.1039/D4SU00117Finfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:39:05Zoai:ri.conicet.gov.ar:11336/265477instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:39:05.911CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
title Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
spellingShingle Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
Lopez de Lacalle, Jon
Polymeric eutctic solvents
Polyphenols
Anticorrosion coatings
title_short Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
title_full Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
title_fullStr Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
title_full_unstemmed Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
title_sort Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents
dc.creator.none.fl_str_mv Lopez de Lacalle, Jon
Minudri, Daniela
Picchio, Matías Luis
Gallastegui, Antonela
Mantione, Daniele
Forsyth, Maria Silvia
Mecerreyes, David
author Lopez de Lacalle, Jon
author_facet Lopez de Lacalle, Jon
Minudri, Daniela
Picchio, Matías Luis
Gallastegui, Antonela
Mantione, Daniele
Forsyth, Maria Silvia
Mecerreyes, David
author_role author
author2 Minudri, Daniela
Picchio, Matías Luis
Gallastegui, Antonela
Mantione, Daniele
Forsyth, Maria Silvia
Mecerreyes, David
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Polymeric eutctic solvents
Polyphenols
Anticorrosion coatings
topic Polymeric eutctic solvents
Polyphenols
Anticorrosion coatings
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The mitigation of corrosion, especially in coastal regions, stands as a significant social concern necessitating the exploration of environmentally friendly materials. This study introduces phenol-based ionic polymers as both coatings and solution corrosion inhibitors for mild steel. Three methacrylated phenolic deep eutectic monomers (DEMs) bearing catechol and gallol motifs were synthetized for this purpose, taking advantage of polyphenol chemistry. Both the polyphenol DEMs and the UV-photopolymerized ionic polymer coatings formed coordination complexes with iron ions on the surface of the mild steel, resulting in a distinctive colour evolution, transitioning from a non-coloured film to dark purple, characterized by optical imaging and UV-vis absorption analysis. The resulting interfacial complex layer demonstrated exceptional corrosion inhibition efficiency for tannic acid and protocatechuic acid based polymers, achieving efficiencies of 99.84% and 99.54% respectively. Further explanation of this phenomenon involves the investigation of phenolic deep eutectic monomers in solution as model compounds, revealing a purple hue in the solution arising from the complexation between the polyphenol chemistry and the iron ions leached from the steel surface.
Fil: Lopez de Lacalle, Jon. Universidad del Pais Vasco. Polymat.; España
Fil: Minudri, Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad del Pais Vasco. Polymat.; España
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gallastegui, Antonela. Universidad del Pais Vasco. Polymat.; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mantione, Daniele. Universidad del Pais Vasco. Polymat.; España
Fil: Forsyth, Maria Silvia. Universidad del Pais Vasco. Polymat.; España
Fil: Mecerreyes, David. Universidad del Pais Vasco. Polymat.; España
description The mitigation of corrosion, especially in coastal regions, stands as a significant social concern necessitating the exploration of environmentally friendly materials. This study introduces phenol-based ionic polymers as both coatings and solution corrosion inhibitors for mild steel. Three methacrylated phenolic deep eutectic monomers (DEMs) bearing catechol and gallol motifs were synthetized for this purpose, taking advantage of polyphenol chemistry. Both the polyphenol DEMs and the UV-photopolymerized ionic polymer coatings formed coordination complexes with iron ions on the surface of the mild steel, resulting in a distinctive colour evolution, transitioning from a non-coloured film to dark purple, characterized by optical imaging and UV-vis absorption analysis. The resulting interfacial complex layer demonstrated exceptional corrosion inhibition efficiency for tannic acid and protocatechuic acid based polymers, achieving efficiencies of 99.84% and 99.54% respectively. Further explanation of this phenomenon involves the investigation of phenolic deep eutectic monomers in solution as model compounds, revealing a purple hue in the solution arising from the complexation between the polyphenol chemistry and the iron ions leached from the steel surface.
publishDate 2024
dc.date.none.fl_str_mv 2024-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/265477
Lopez de Lacalle, Jon; Minudri, Daniela; Picchio, Matías Luis; Gallastegui, Antonela; Mantione, Daniele; et al.; Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents; Royal Society of Chemistry; RSC Sustainability; 2; 6; 4-2024; 1809-1818
2753-8125
CONICET Digital
CONICET
url http://hdl.handle.net/11336/265477
identifier_str_mv Lopez de Lacalle, Jon; Minudri, Daniela; Picchio, Matías Luis; Gallastegui, Antonela; Mantione, Daniele; et al.; Protection coatings for corrosion control of mild steel using phenolic polymeric deep eutectic solvents; Royal Society of Chemistry; RSC Sustainability; 2; 6; 4-2024; 1809-1818
2753-8125
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D4SU00117F
info:eu-repo/semantics/altIdentifier/doi/10.1039/D4SU00117F
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614415576465408
score 13.070432

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