Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols

Autores
López de Lacalle, Jon; Gallastegui, Antonela; Olmedo Martínez, Jorge L.; Moya, Melissa; Lopez Larrea, Naroa; Picchio, Matías Luis; Mecerreyes, David
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability ≈1000% and strength ≈3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.
Fil: López de Lacalle, Jon. Universidad del País Vasco; España
Fil: Gallastegui, Antonela. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Olmedo Martínez, Jorge L.. Universidad del País Vasco; España
Fil: Moya, Melissa. Universidad de Ciencias Médicas; Costa Rica
Fil: Lopez Larrea, Naroa. Universidad del País Vasco; España
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universidad del País Vasco; España
Fil: Mecerreyes, David. Universidad del País Vasco; España
Materia
Ionic polymers
Deep eutectic monomers
Polyphenols
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/225722
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on PolyphenolsLópez de Lacalle, JonGallastegui, AntonelaOlmedo Martínez, Jorge L.Moya, MelissaLopez Larrea, NaroaPicchio, Matías LuisMecerreyes, DavidIonic polymersDeep eutectic monomersPolyphenolshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability ≈1000% and strength ≈3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.Fil: López de Lacalle, Jon. Universidad del País Vasco; EspañaFil: Gallastegui, Antonela. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Olmedo Martínez, Jorge L.. Universidad del País Vasco; EspañaFil: Moya, Melissa. Universidad de Ciencias Médicas; Costa RicaFil: Lopez Larrea, Naroa. Universidad del País Vasco; EspañaFil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universidad del País Vasco; EspañaFil: Mecerreyes, David. Universidad del País Vasco; EspañaAmerican Chemical Society2023-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/225722López de Lacalle, Jon; Gallastegui, Antonela; Olmedo Martínez, Jorge L.; Moya, Melissa; Lopez Larrea, Naroa; et al.; Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols; American Chemical Society; ACS Macro Letters; 12; 2; 1-2023; 125-1322161-1653CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acsmacrolett.2c00657info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:20:01Zoai:ri.conicet.gov.ar:11336/225722instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:20:02.063CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
title Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
spellingShingle Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
López de Lacalle, Jon
Ionic polymers
Deep eutectic monomers
Polyphenols
title_short Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
title_full Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
title_fullStr Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
title_full_unstemmed Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
title_sort Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols
dc.creator.none.fl_str_mv López de Lacalle, Jon
Gallastegui, Antonela
Olmedo Martínez, Jorge L.
Moya, Melissa
Lopez Larrea, Naroa
Picchio, Matías Luis
Mecerreyes, David
author López de Lacalle, Jon
author_facet López de Lacalle, Jon
Gallastegui, Antonela
Olmedo Martínez, Jorge L.
Moya, Melissa
Lopez Larrea, Naroa
Picchio, Matías Luis
Mecerreyes, David
author_role author
author2 Gallastegui, Antonela
Olmedo Martínez, Jorge L.
Moya, Melissa
Lopez Larrea, Naroa
Picchio, Matías Luis
Mecerreyes, David
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Ionic polymers
Deep eutectic monomers
Polyphenols
topic Ionic polymers
Deep eutectic monomers
Polyphenols
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability ≈1000% and strength ≈3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.
Fil: López de Lacalle, Jon. Universidad del País Vasco; España
Fil: Gallastegui, Antonela. Universidad del País Vasco; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Olmedo Martínez, Jorge L.. Universidad del País Vasco; España
Fil: Moya, Melissa. Universidad de Ciencias Médicas; Costa Rica
Fil: Lopez Larrea, Naroa. Universidad del País Vasco; España
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universidad del País Vasco; España
Fil: Mecerreyes, David. Universidad del País Vasco; España
description Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability ≈1000% and strength ≈3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.
publishDate 2023
dc.date.none.fl_str_mv 2023-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/225722
López de Lacalle, Jon; Gallastegui, Antonela; Olmedo Martínez, Jorge L.; Moya, Melissa; Lopez Larrea, Naroa; et al.; Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols; American Chemical Society; ACS Macro Letters; 12; 2; 1-2023; 125-132
2161-1653
CONICET Digital
CONICET
url http://hdl.handle.net/11336/225722
identifier_str_mv López de Lacalle, Jon; Gallastegui, Antonela; Olmedo Martínez, Jorge L.; Moya, Melissa; Lopez Larrea, Naroa; et al.; Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols; American Chemical Society; ACS Macro Letters; 12; 2; 1-2023; 125-132
2161-1653
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acsmacrolett.2c00657
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614176510574592
score 13.070432

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