Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the sta...

Autores
Grosse, Constantino
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A unified extension of the classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal dispersions is presented. Purely analytical expressions for the AC dielectric and electrokinetic response over a broad frequency range including different counterion and co-ion valences and the presence of the stagnant layer conductivity are deduced. The obtained results are generally in good to very good agreement with available numerical data, showing that they should be useful for the interpretation of a broad range of experimental results without having to rely on numerical calculations.
Fil: Grosse, Constantino. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina
Materia
Low Frequency Dielectric Dispersion
Different Valences
Stagnant Layer Conductivity
Stern Layer Conductivity
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/77165
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivityGrosse, ConstantinoLow Frequency Dielectric DispersionDifferent ValencesStagnant Layer ConductivityStern Layer Conductivityhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1A unified extension of the classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal dispersions is presented. Purely analytical expressions for the AC dielectric and electrokinetic response over a broad frequency range including different counterion and co-ion valences and the presence of the stagnant layer conductivity are deduced. The obtained results are generally in good to very good agreement with available numerical data, showing that they should be useful for the interpretation of a broad range of experimental results without having to rely on numerical calculations.Fil: Grosse, Constantino. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; ArgentinaAmerican Chemical Society2012-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77165Grosse, Constantino; Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity; American Chemical Society; Journal of Physical Chemistry B; 116; 45; 11-2012; 13538-135531520-6106CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://dx.doi.org/10.1021/jp3075404info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp3075404info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:36:17Zoai:ri.conicet.gov.ar:11336/77165instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:36:17.634CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
title Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
spellingShingle Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
Grosse, Constantino
Low Frequency Dielectric Dispersion
Different Valences
Stagnant Layer Conductivity
Stern Layer Conductivity
title_short Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
title_full Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
title_fullStr Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
title_full_unstemmed Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
title_sort Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity
dc.creator.none.fl_str_mv Grosse, Constantino
author Grosse, Constantino
author_facet Grosse, Constantino
author_role author
dc.subject.none.fl_str_mv Low Frequency Dielectric Dispersion
Different Valences
Stagnant Layer Conductivity
Stern Layer Conductivity
topic Low Frequency Dielectric Dispersion
Different Valences
Stagnant Layer Conductivity
Stern Layer Conductivity
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A unified extension of the classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal dispersions is presented. Purely analytical expressions for the AC dielectric and electrokinetic response over a broad frequency range including different counterion and co-ion valences and the presence of the stagnant layer conductivity are deduced. The obtained results are generally in good to very good agreement with available numerical data, showing that they should be useful for the interpretation of a broad range of experimental results without having to rely on numerical calculations.
Fil: Grosse, Constantino. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina
description A unified extension of the classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal dispersions is presented. Purely analytical expressions for the AC dielectric and electrokinetic response over a broad frequency range including different counterion and co-ion valences and the presence of the stagnant layer conductivity are deduced. The obtained results are generally in good to very good agreement with available numerical data, showing that they should be useful for the interpretation of a broad range of experimental results without having to rely on numerical calculations.
publishDate 2012
dc.date.none.fl_str_mv 2012-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/77165
Grosse, Constantino; Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity; American Chemical Society; Journal of Physical Chemistry B; 116; 45; 11-2012; 13538-13553
1520-6106
CONICET Digital
CONICET
url http://hdl.handle.net/11336/77165
identifier_str_mv Grosse, Constantino; Extension of a classic low frequency dielectric dispersion theory of colloidal suspensions to include different counterion and co-ion valences, a broad frequency range, and the stagnant layer conductivity; American Chemical Society; Journal of Physical Chemistry B; 116; 45; 11-2012; 13538-13553
1520-6106
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://dx.doi.org/10.1021/jp3075404
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp3075404
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614382918565888
score 13.070432

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