Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain

Autores
Grosse, Constantino
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal suspensions in binary electrolyte solutions [Shilov, V. N.; Dukhin, S. S., Colloid J. 1970, 32, 245.; Dukhin, S. S.; Shilov, V. N. Dielectric Phenomena and the Double Layer in Disperse Systems and Polyelectrolytes; Wiley: New York, 1974] was developed for the frequency range corresponding to the concentration polarization phenomenon: up to a few megahertz. While a few extensions to a broad frequency range including the Maxwell-Wagner-OKonski dispersion exist, they all consist of modifications of the final results of the theory rather than modifications of its hypothesis, extending their validity to high frequencies. In this work we avoid this artificial process by providing a high frequency extension fully from within the theory.
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina
Materia
Low Frequency Dielectric Dispersion
Maxwell-Wagner Dispersion
Broad Frequency Range
Wide Frequency Range
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/73568

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network_name_str CONICET Digital (CONICET)
spelling Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domainGrosse, ConstantinoLow Frequency Dielectric DispersionMaxwell-Wagner DispersionBroad Frequency RangeWide Frequency Rangehttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal suspensions in binary electrolyte solutions [Shilov, V. N.; Dukhin, S. S., Colloid J. 1970, 32, 245.; Dukhin, S. S.; Shilov, V. N. Dielectric Phenomena and the Double Layer in Disperse Systems and Polyelectrolytes; Wiley: New York, 1974] was developed for the frequency range corresponding to the concentration polarization phenomenon: up to a few megahertz. While a few extensions to a broad frequency range including the Maxwell-Wagner-OKonski dispersion exist, they all consist of modifications of the final results of the theory rather than modifications of its hypothesis, extending their validity to high frequencies. In this work we avoid this artificial process by providing a high frequency extension fully from within the theory.Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; ArgentinaAmerican Chemical Society2010-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/73568Grosse, Constantino; Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain; American Chemical Society; Journal of Physical Chemistry B; 114; 39; 10-2010; 12520-125271520-6106CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp106336ginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp106336ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:57:58Zoai:ri.conicet.gov.ar:11336/73568instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:57:58.725CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
title Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
spellingShingle Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
Grosse, Constantino
Low Frequency Dielectric Dispersion
Maxwell-Wagner Dispersion
Broad Frequency Range
Wide Frequency Range
title_short Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
title_full Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
title_fullStr Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
title_full_unstemmed Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
title_sort Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain
dc.creator.none.fl_str_mv Grosse, Constantino
author Grosse, Constantino
author_facet Grosse, Constantino
author_role author
dc.subject.none.fl_str_mv Low Frequency Dielectric Dispersion
Maxwell-Wagner Dispersion
Broad Frequency Range
Wide Frequency Range
topic Low Frequency Dielectric Dispersion
Maxwell-Wagner Dispersion
Broad Frequency Range
Wide Frequency Range
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal suspensions in binary electrolyte solutions [Shilov, V. N.; Dukhin, S. S., Colloid J. 1970, 32, 245.; Dukhin, S. S.; Shilov, V. N. Dielectric Phenomena and the Double Layer in Disperse Systems and Polyelectrolytes; Wiley: New York, 1974] was developed for the frequency range corresponding to the concentration polarization phenomenon: up to a few megahertz. While a few extensions to a broad frequency range including the Maxwell-Wagner-OKonski dispersion exist, they all consist of modifications of the final results of the theory rather than modifications of its hypothesis, extending their validity to high frequencies. In this work we avoid this artificial process by providing a high frequency extension fully from within the theory.
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina
description The classic Shilov-Dukhin theory of the low frequency dielectric dispersion of colloidal suspensions in binary electrolyte solutions [Shilov, V. N.; Dukhin, S. S., Colloid J. 1970, 32, 245.; Dukhin, S. S.; Shilov, V. N. Dielectric Phenomena and the Double Layer in Disperse Systems and Polyelectrolytes; Wiley: New York, 1974] was developed for the frequency range corresponding to the concentration polarization phenomenon: up to a few megahertz. While a few extensions to a broad frequency range including the Maxwell-Wagner-OKonski dispersion exist, they all consist of modifications of the final results of the theory rather than modifications of its hypothesis, extending their validity to high frequencies. In this work we avoid this artificial process by providing a high frequency extension fully from within the theory.
publishDate 2010
dc.date.none.fl_str_mv 2010-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/73568
Grosse, Constantino; Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain; American Chemical Society; Journal of Physical Chemistry B; 114; 39; 10-2010; 12520-12527
1520-6106
CONICET Digital
CONICET
url http://hdl.handle.net/11336/73568
identifier_str_mv Grosse, Constantino; Extension of a classic theory of the low frequency dielectric dispersion of colloidal suspensions to the high frequency domain; American Chemical Society; Journal of Physical Chemistry B; 114; 39; 10-2010; 12520-12527
1520-6106
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jp106336g
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp106336g
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432