Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines

Autores
Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules.
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Materia
HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE)
OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE)
CRYSTAL STRUCTURES
SUPRAMOLECULAR ADDUCTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/192573

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network_name_str CONICET Digital (CONICET)
spelling Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain DiaminesCastellano, Eduardo ErnestoPiro, Oscar EnriqueParajón Costa, Beatriz SusanaBaran, Enrique JoséHEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE)OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE)CRYSTAL STRUCTURESSUPRAMOLECULAR ADDUCTShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules.Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; BrasilFil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaDe Gruyter2009-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/192573Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 64; 9; 9-2009; 1041-10450932-0776CONICET DigitalCONICETenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:50:42Zoai:ri.conicet.gov.ar:11336/192573instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:50:42.421CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
title Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
spellingShingle Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
Castellano, Eduardo Ernesto
HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE)
OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE)
CRYSTAL STRUCTURES
SUPRAMOLECULAR ADDUCTS
title_short Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
title_full Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
title_fullStr Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
title_full_unstemmed Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
title_sort Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
dc.creator.none.fl_str_mv Castellano, Eduardo Ernesto
Piro, Oscar Enrique
Parajón Costa, Beatriz Susana
Baran, Enrique José
author Castellano, Eduardo Ernesto
author_facet Castellano, Eduardo Ernesto
Piro, Oscar Enrique
Parajón Costa, Beatriz Susana
Baran, Enrique José
author_role author
author2 Piro, Oscar Enrique
Parajón Costa, Beatriz Susana
Baran, Enrique José
author2_role author
author
author
dc.subject.none.fl_str_mv HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE)
OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE)
CRYSTAL STRUCTURES
SUPRAMOLECULAR ADDUCTS
topic HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE)
OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE)
CRYSTAL STRUCTURES
SUPRAMOLECULAR ADDUCTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules.
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
description The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules.
publishDate 2009
dc.date.none.fl_str_mv 2009-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/192573
Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 64; 9; 9-2009; 1041-1045
0932-0776
CONICET Digital
CONICET
url http://hdl.handle.net/11336/192573
identifier_str_mv Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 64; 9; 9-2009; 1041-1045
0932-0776
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv De Gruyter
publisher.none.fl_str_mv De Gruyter
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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