Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines
- Autores
- Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules.
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina - Materia
-
HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE)
OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE)
CRYSTAL STRUCTURES
SUPRAMOLECULAR ADDUCTS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/192573
Ver los metadatos del registro completo
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Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain DiaminesCastellano, Eduardo ErnestoPiro, Oscar EnriqueParajón Costa, Beatriz SusanaBaran, Enrique JoséHEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE)OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE)CRYSTAL STRUCTURESSUPRAMOLECULAR ADDUCTShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules.Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; BrasilFil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaDe Gruyter2009-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/192573Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 64; 9; 9-2009; 1041-10450932-0776CONICET DigitalCONICETenginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:50:42Zoai:ri.conicet.gov.ar:11336/192573instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:50:42.421CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines |
title |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines |
spellingShingle |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines Castellano, Eduardo Ernesto HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE) OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE) CRYSTAL STRUCTURES SUPRAMOLECULAR ADDUCTS |
title_short |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines |
title_full |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines |
title_fullStr |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines |
title_full_unstemmed |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines |
title_sort |
Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines |
dc.creator.none.fl_str_mv |
Castellano, Eduardo Ernesto Piro, Oscar Enrique Parajón Costa, Beatriz Susana Baran, Enrique José |
author |
Castellano, Eduardo Ernesto |
author_facet |
Castellano, Eduardo Ernesto Piro, Oscar Enrique Parajón Costa, Beatriz Susana Baran, Enrique José |
author_role |
author |
author2 |
Piro, Oscar Enrique Parajón Costa, Beatriz Susana Baran, Enrique José |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE) OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE) CRYSTAL STRUCTURES SUPRAMOLECULAR ADDUCTS |
topic |
HEPTAMETHYLENEDIAMMONIUM BIS(SACCHARINATE) OCTAMEHYLENEDIAMMONIUM BIS(SACCHARINATE) CRYSTAL STRUCTURES SUPRAMOLECULAR ADDUCTS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules. Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina |
description |
The crystal structures of heptamethylenediammonium bis(saccharuinate) monohydrate,[H3N-(CH2)7-NH3](sac)2.H2O (I) and octamethylenediammonium bis(saccharinate) hemihydrate, [NH3-(CH2)8-NH3].1/2H2O (II) were determined by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P(-1) with 2 molecules per unit cell, and II in the monoclinic space group P21/a with Z = 4. The saccharinate moiety is planar in both compounds. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three dimensional supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent molecules. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/192573 Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 64; 9; 9-2009; 1041-1045 0932-0776 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/192573 |
identifier_str_mv |
Castellano, Eduardo Ernesto; Piro, Oscar Enrique; Parajón Costa, Beatriz Susana; Baran, Enrique José; Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines; De Gruyter; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 64; 9; 9-2009; 1041-1045 0932-0776 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
De Gruyter |
publisher.none.fl_str_mv |
De Gruyter |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613562402603008 |
score |
13.070432 |