Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes

Autores
Williams, Patricia Ana María; Ferrer, Evelina Gloria; Baeza, Natalia; Piro, Oscar Enrique; Castellano, Eduardo Ernesto; Baran, Enrique José
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The reaction of the CuII and NiII complexes of saccharin with dicyandiamide (cyanoguanidine, cnge) in methanol produces the addition of methanol to the nitrile moiety of this molecule. Furthermore, the product of the reaction coordinates the metal centers generating two new complexes containing saccharinate as the counter anion. The crystal structures of [Cu(cnge-OCH3)2]-(sac)2 and of [Ni(cnge-OCH3)2](sac)2·2H2O (cnge-OCH3 = 1-amidino-O-methylurea) were solved by single crystal X-ray diffractometry. Both complexes crystallize in the triclinic space group P1 and the metallic cations present a quite similar centrosymmetric planar conformation. The complexes were characterized by means of electronic and infrared spectroscopy and also their magnetic and thermal behavior was investigated.
Fil: Williams, Patricia Ana María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Ferrer, Evelina Gloria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baeza, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
COPPER
METHANOL ADDITION
NICKEL
SACCHARINATE COMPLEXES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/186883
Acceder
id CONICETDig_cf6722c5aa0e6452837a034402fb550b
oai_identifier_str oai:ri.conicet.gov.ar:11336/186883
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) ComplexesWilliams, Patricia Ana MaríaFerrer, Evelina GloriaBaeza, NataliaPiro, Oscar EnriqueCastellano, Eduardo ErnestoBaran, Enrique JoséCOPPERMETHANOL ADDITIONNICKELSACCHARINATE COMPLEXEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The reaction of the CuII and NiII complexes of saccharin with dicyandiamide (cyanoguanidine, cnge) in methanol produces the addition of methanol to the nitrile moiety of this molecule. Furthermore, the product of the reaction coordinates the metal centers generating two new complexes containing saccharinate as the counter anion. The crystal structures of [Cu(cnge-OCH3)2]-(sac)2 and of [Ni(cnge-OCH3)2](sac)2·2H2O (cnge-OCH3 = 1-amidino-O-methylurea) were solved by single crystal X-ray diffractometry. Both complexes crystallize in the triclinic space group P1 and the metallic cations present a quite similar centrosymmetric planar conformation. The complexes were characterized by means of electronic and infrared spectroscopy and also their magnetic and thermal behavior was investigated.Fil: Williams, Patricia Ana María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Ferrer, Evelina Gloria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Baeza, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; BrasilFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaJohn Wiley & Sons Ltd2005-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/186883Williams, Patricia Ana María; Ferrer, Evelina Gloria; Baeza, Natalia; Piro, Oscar Enrique; Castellano, Eduardo Ernesto; et al.; Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes; John Wiley & Sons Ltd; Zeitschrift Fur Anorganische Und Allgemeine Chemie; 631; 8; 12-2005; 1502-15060044-23131521-3749CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200500002info:eu-repo/semantics/altIdentifier/doi/10.1002/zaac.200500002info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:22:46Zoai:ri.conicet.gov.ar:11336/186883instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:22:46.842CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
title Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
spellingShingle Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
Williams, Patricia Ana María
COPPER
METHANOL ADDITION
NICKEL
SACCHARINATE COMPLEXES
title_short Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
title_full Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
title_fullStr Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
title_full_unstemmed Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
title_sort Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes
dc.creator.none.fl_str_mv Williams, Patricia Ana María
Ferrer, Evelina Gloria
Baeza, Natalia
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Baran, Enrique José
author Williams, Patricia Ana María
author_facet Williams, Patricia Ana María
Ferrer, Evelina Gloria
Baeza, Natalia
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Baran, Enrique José
author_role author
author2 Ferrer, Evelina Gloria
Baeza, Natalia
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Baran, Enrique José
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv COPPER
METHANOL ADDITION
NICKEL
SACCHARINATE COMPLEXES
topic COPPER
METHANOL ADDITION
NICKEL
SACCHARINATE COMPLEXES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The reaction of the CuII and NiII complexes of saccharin with dicyandiamide (cyanoguanidine, cnge) in methanol produces the addition of methanol to the nitrile moiety of this molecule. Furthermore, the product of the reaction coordinates the metal centers generating two new complexes containing saccharinate as the counter anion. The crystal structures of [Cu(cnge-OCH3)2]-(sac)2 and of [Ni(cnge-OCH3)2](sac)2·2H2O (cnge-OCH3 = 1-amidino-O-methylurea) were solved by single crystal X-ray diffractometry. Both complexes crystallize in the triclinic space group P1 and the metallic cations present a quite similar centrosymmetric planar conformation. The complexes were characterized by means of electronic and infrared spectroscopy and also their magnetic and thermal behavior was investigated.
Fil: Williams, Patricia Ana María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Ferrer, Evelina Gloria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Baeza, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Castellano, Eduardo Ernesto. Universidade de Sao Paulo; Brasil
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description The reaction of the CuII and NiII complexes of saccharin with dicyandiamide (cyanoguanidine, cnge) in methanol produces the addition of methanol to the nitrile moiety of this molecule. Furthermore, the product of the reaction coordinates the metal centers generating two new complexes containing saccharinate as the counter anion. The crystal structures of [Cu(cnge-OCH3)2]-(sac)2 and of [Ni(cnge-OCH3)2](sac)2·2H2O (cnge-OCH3 = 1-amidino-O-methylurea) were solved by single crystal X-ray diffractometry. Both complexes crystallize in the triclinic space group P1 and the metallic cations present a quite similar centrosymmetric planar conformation. The complexes were characterized by means of electronic and infrared spectroscopy and also their magnetic and thermal behavior was investigated.
publishDate 2005
dc.date.none.fl_str_mv 2005-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/186883
Williams, Patricia Ana María; Ferrer, Evelina Gloria; Baeza, Natalia; Piro, Oscar Enrique; Castellano, Eduardo Ernesto; et al.; Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes; John Wiley & Sons Ltd; Zeitschrift Fur Anorganische Und Allgemeine Chemie; 631; 8; 12-2005; 1502-1506
0044-2313
1521-3749
CONICET Digital
CONICET
url http://hdl.handle.net/11336/186883
identifier_str_mv Williams, Patricia Ana María; Ferrer, Evelina Gloria; Baeza, Natalia; Piro, Oscar Enrique; Castellano, Eduardo Ernesto; et al.; Transition Metal Promoted Addition of Methanol to Cyanoguanidine. Molecular Structure and Properties of the Generated Copper(II) and Nickel(II) Complexes; John Wiley & Sons Ltd; Zeitschrift Fur Anorganische Und Allgemeine Chemie; 631; 8; 12-2005; 1502-1506
0044-2313
1521-3749
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.200500002
info:eu-repo/semantics/altIdentifier/doi/10.1002/zaac.200500002
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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