A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
- Autores
- Barán, Enrique José; Piro, Oscar Enrique; Zinczuk, Juan
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.
Centro de Química Inorgánica
Instituto de Física La Plata - Materia
-
Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-nd/3.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/83080
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A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamineBarán, Enrique JoséPiro, Oscar EnriqueZinczuk, JuanQuímicaCrystallographic dataHexamethylenediammonium bis(thiosaccharinate) dihydrateIR spectraSupramolecular adductThe crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.Centro de Química InorgánicaInstituto de Física La Plata2007info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1530-1534http://sedici.unlp.edu.ar/handle/10915/83080enginfo:eu-repo/semantics/altIdentifier/issn/0932-0776info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2007-1210info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/3.0/Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:15:45Zoai:sedici.unlp.edu.ar:10915/83080Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:15:45.898SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine |
title |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine |
spellingShingle |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine Barán, Enrique José Química Crystallographic data Hexamethylenediammonium bis(thiosaccharinate) dihydrate IR spectra Supramolecular adduct |
title_short |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine |
title_full |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine |
title_fullStr |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine |
title_full_unstemmed |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine |
title_sort |
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine |
dc.creator.none.fl_str_mv |
Barán, Enrique José Piro, Oscar Enrique Zinczuk, Juan |
author |
Barán, Enrique José |
author_facet |
Barán, Enrique José Piro, Oscar Enrique Zinczuk, Juan |
author_role |
author |
author2 |
Piro, Oscar Enrique Zinczuk, Juan |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Química Crystallographic data Hexamethylenediammonium bis(thiosaccharinate) dihydrate IR spectra Supramolecular adduct |
topic |
Química Crystallographic data Hexamethylenediammonium bis(thiosaccharinate) dihydrate IR spectra Supramolecular adduct |
dc.description.none.fl_txt_mv |
The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules. Centro de Química Inorgánica Instituto de Física La Plata |
description |
The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/83080 |
url |
http://sedici.unlp.edu.ar/handle/10915/83080 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0932-0776 info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2007-1210 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/3.0/ Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-nd/3.0/ Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) |
dc.format.none.fl_str_mv |
application/pdf 1530-1534 |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
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