A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine

Autores
Barán, Enrique José; Piro, Oscar Enrique; Zinczuk, Juan
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.
Centro de Química Inorgánica
Instituto de Física La Plata
Materia
Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/3.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/83080
Acceder
id SEDICI_c5697e8b3634e8ddb0f062062de0084d
oai_identifier_str oai:sedici.unlp.edu.ar:10915/83080
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamineBarán, Enrique JoséPiro, Oscar EnriqueZinczuk, JuanQuímicaCrystallographic dataHexamethylenediammonium bis(thiosaccharinate) dihydrateIR spectraSupramolecular adductThe crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.Centro de Química InorgánicaInstituto de Física La Plata2007info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1530-1534http://sedici.unlp.edu.ar/handle/10915/83080enginfo:eu-repo/semantics/altIdentifier/issn/0932-0776info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2007-1210info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/3.0/Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T16:56:33Zoai:sedici.unlp.edu.ar:10915/83080Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 16:56:33.388SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
spellingShingle A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
Barán, Enrique José
Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
title_short A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_full A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_fullStr A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_full_unstemmed A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_sort A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
dc.creator.none.fl_str_mv Barán, Enrique José
Piro, Oscar Enrique
Zinczuk, Juan
author Barán, Enrique José
author_facet Barán, Enrique José
Piro, Oscar Enrique
Zinczuk, Juan
author_role author
author2 Piro, Oscar Enrique
Zinczuk, Juan
author2_role author
author
dc.subject.none.fl_str_mv Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
topic Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
dc.description.none.fl_txt_mv The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.
Centro de Química Inorgánica
Instituto de Física La Plata
description The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.
publishDate 2007
dc.date.none.fl_str_mv 2007
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/83080
url http://sedici.unlp.edu.ar/handle/10915/83080
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0932-0776
info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2007-1210
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/3.0/
Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/3.0/
Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)
dc.format.none.fl_str_mv application/pdf
1530-1534
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 12.982451

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