Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles

Autores
Nador, Fabiana Gabriela; Moglie, Yanina Fernanda; Vitale, Cristian Alejandro; Yus, Miguel; Alonso, Francisco; Radivoy, Gabriel Eduardo
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new methodology for the partial reduction of polycyclic aromatic and heteroaromatic hydrocarbons under mild reaction conditions is presented, the process being a reasonable alternative to the catalytic hydrogenation or the Birch reaction. The reduction protocol described is based on the use of cobalt or manganese nanoparticles generated in situ in a simple and economic way, by reduction of commercially available CoCl2·6H2O or MnCl2·2H2O in the presence of lithium sand and the corresponding PAH, acting itself as an electron carrier. The use of a deuterium-oxide-containing cobalt(II) salt allows the simple preparation of deuterium labeled products. The regiochemistry and degree of reduction in the case of 1-substituted naphthalene derivatives markedly depends on the nature of the metal-NPs used. © 2010 Elsevier Ltd. All rights reserved.
Fil: Nador, Fabiana Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Moglie, Yanina Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Vitale, Cristian Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Yus, Miguel. Universidad de Alicante; España
Fil: Alonso, Francisco. Universidad de Alicante; España
Fil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Materia
Cobalt
Manganese
Nanoparticles
Polycyclic Aromatic Hydrocarbons
Reduction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/64067
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticlesNador, Fabiana GabrielaMoglie, Yanina FernandaVitale, Cristian AlejandroYus, MiguelAlonso, FranciscoRadivoy, Gabriel EduardoCobaltManganeseNanoparticlesPolycyclic Aromatic HydrocarbonsReductionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new methodology for the partial reduction of polycyclic aromatic and heteroaromatic hydrocarbons under mild reaction conditions is presented, the process being a reasonable alternative to the catalytic hydrogenation or the Birch reaction. The reduction protocol described is based on the use of cobalt or manganese nanoparticles generated in situ in a simple and economic way, by reduction of commercially available CoCl2·6H2O or MnCl2·2H2O in the presence of lithium sand and the corresponding PAH, acting itself as an electron carrier. The use of a deuterium-oxide-containing cobalt(II) salt allows the simple preparation of deuterium labeled products. The regiochemistry and degree of reduction in the case of 1-substituted naphthalene derivatives markedly depends on the nature of the metal-NPs used. © 2010 Elsevier Ltd. All rights reserved.Fil: Nador, Fabiana Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Moglie, Yanina Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Vitale, Cristian Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Yus, Miguel. Universidad de Alicante; EspañaFil: Alonso, Francisco. Universidad de Alicante; EspañaFil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaPergamon-Elsevier Science Ltd2010-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64067Nador, Fabiana Gabriela; Moglie, Yanina Fernanda; Vitale, Cristian Alejandro; Yus, Miguel; Alonso, Francisco; et al.; Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles; Pergamon-Elsevier Science Ltd; Tetrahedron; 66; 24; 6-2010; 4318-43250040-4020CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0040402010005697info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tet.2010.04.026info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:37Zoai:ri.conicet.gov.ar:11336/64067instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:38.255CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
title Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
spellingShingle Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
Nador, Fabiana Gabriela
Cobalt
Manganese
Nanoparticles
Polycyclic Aromatic Hydrocarbons
Reduction
title_short Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
title_full Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
title_fullStr Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
title_full_unstemmed Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
title_sort Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles
dc.creator.none.fl_str_mv Nador, Fabiana Gabriela
Moglie, Yanina Fernanda
Vitale, Cristian Alejandro
Yus, Miguel
Alonso, Francisco
Radivoy, Gabriel Eduardo
author Nador, Fabiana Gabriela
author_facet Nador, Fabiana Gabriela
Moglie, Yanina Fernanda
Vitale, Cristian Alejandro
Yus, Miguel
Alonso, Francisco
Radivoy, Gabriel Eduardo
author_role author
author2 Moglie, Yanina Fernanda
Vitale, Cristian Alejandro
Yus, Miguel
Alonso, Francisco
Radivoy, Gabriel Eduardo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Cobalt
Manganese
Nanoparticles
Polycyclic Aromatic Hydrocarbons
Reduction
topic Cobalt
Manganese
Nanoparticles
Polycyclic Aromatic Hydrocarbons
Reduction
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A new methodology for the partial reduction of polycyclic aromatic and heteroaromatic hydrocarbons under mild reaction conditions is presented, the process being a reasonable alternative to the catalytic hydrogenation or the Birch reaction. The reduction protocol described is based on the use of cobalt or manganese nanoparticles generated in situ in a simple and economic way, by reduction of commercially available CoCl2·6H2O or MnCl2·2H2O in the presence of lithium sand and the corresponding PAH, acting itself as an electron carrier. The use of a deuterium-oxide-containing cobalt(II) salt allows the simple preparation of deuterium labeled products. The regiochemistry and degree of reduction in the case of 1-substituted naphthalene derivatives markedly depends on the nature of the metal-NPs used. © 2010 Elsevier Ltd. All rights reserved.
Fil: Nador, Fabiana Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Moglie, Yanina Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Vitale, Cristian Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Yus, Miguel. Universidad de Alicante; España
Fil: Alonso, Francisco. Universidad de Alicante; España
Fil: Radivoy, Gabriel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
description A new methodology for the partial reduction of polycyclic aromatic and heteroaromatic hydrocarbons under mild reaction conditions is presented, the process being a reasonable alternative to the catalytic hydrogenation or the Birch reaction. The reduction protocol described is based on the use of cobalt or manganese nanoparticles generated in situ in a simple and economic way, by reduction of commercially available CoCl2·6H2O or MnCl2·2H2O in the presence of lithium sand and the corresponding PAH, acting itself as an electron carrier. The use of a deuterium-oxide-containing cobalt(II) salt allows the simple preparation of deuterium labeled products. The regiochemistry and degree of reduction in the case of 1-substituted naphthalene derivatives markedly depends on the nature of the metal-NPs used. © 2010 Elsevier Ltd. All rights reserved.
publishDate 2010
dc.date.none.fl_str_mv 2010-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/64067
Nador, Fabiana Gabriela; Moglie, Yanina Fernanda; Vitale, Cristian Alejandro; Yus, Miguel; Alonso, Francisco; et al.; Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles; Pergamon-Elsevier Science Ltd; Tetrahedron; 66; 24; 6-2010; 4318-4325
0040-4020
CONICET Digital
CONICET
url http://hdl.handle.net/11336/64067
identifier_str_mv Nador, Fabiana Gabriela; Moglie, Yanina Fernanda; Vitale, Cristian Alejandro; Yus, Miguel; Alonso, Francisco; et al.; Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles; Pergamon-Elsevier Science Ltd; Tetrahedron; 66; 24; 6-2010; 4318-4325
0040-4020
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0040402010005697
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tet.2010.04.026
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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