Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges

Autores
Bortolato, Santiago Andres; Arancibia, Juan Alberto; Escandar, Graciela Monica
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The most concerned polycyclic aromatic hydrocarbons (PAHs) benzo[a]pyrene, dibenz[a,h]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]fluoranthene and benz[a]anthracene were simultaneously determined in the presence of other 10 interfering PAHs, applying second-order multivariate calibration to the data obtained with a flow-through optosensor interfaced to a fast-scanning spectrofluorimeter. Using a sample volume of 2.5 mL, detection limits in the range 5-115 ng L-1 were obtained in interfering samples, with a sample frequency of ca. 15 samples per hour, and with a minimum use of organic solvents, competing very favorably with chromatographic methods. The significance of this study lies in the solution of the quantitative analysis problem of six PAHs in real matrices of unknown composition. The unfolded partial least-squares/residual bilinearization (U-PLS/RBL) algorithm showed the best performance in resolving the complex studied system.
Fil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad Nacional de Rosario; Argentina
Fil: Arancibia, Juan Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina. Universidad Nacional de Rosario; Argentina
Fil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina. Universidad Nacional de Rosario; Argentina
Materia
Polycyclic Aromatic Hydrocarbons
Fluorescence
Optosensor
Chemometric Analysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/13224
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludgesBortolato, Santiago AndresArancibia, Juan AlbertoEscandar, Graciela MonicaPolycyclic Aromatic HydrocarbonsFluorescenceOptosensorChemometric Analysishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The most concerned polycyclic aromatic hydrocarbons (PAHs) benzo[a]pyrene, dibenz[a,h]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]fluoranthene and benz[a]anthracene were simultaneously determined in the presence of other 10 interfering PAHs, applying second-order multivariate calibration to the data obtained with a flow-through optosensor interfaced to a fast-scanning spectrofluorimeter. Using a sample volume of 2.5 mL, detection limits in the range 5-115 ng L-1 were obtained in interfering samples, with a sample frequency of ca. 15 samples per hour, and with a minimum use of organic solvents, competing very favorably with chromatographic methods. The significance of this study lies in the solution of the quantitative analysis problem of six PAHs in real matrices of unknown composition. The unfolded partial least-squares/residual bilinearization (U-PLS/RBL) algorithm showed the best performance in resolving the complex studied system.Fil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad Nacional de Rosario; ArgentinaFil: Arancibia, Juan Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina. Universidad Nacional de Rosario; ArgentinaFil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina. Universidad Nacional de Rosario; ArgentinaAmerican Chemical Society2011-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13224Bortolato, Santiago Andres; Arancibia, Juan Alberto; Escandar, Graciela Monica; Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges; American Chemical Society; Environmental Science & Technology; 45; 4; 3-2011; 1513-15200013-936Xenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/es102811hinfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/es102811hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:31Zoai:ri.conicet.gov.ar:11336/13224instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:31.734CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
title Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
spellingShingle Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
Bortolato, Santiago Andres
Polycyclic Aromatic Hydrocarbons
Fluorescence
Optosensor
Chemometric Analysis
title_short Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
title_full Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
title_fullStr Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
title_full_unstemmed Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
title_sort Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges
dc.creator.none.fl_str_mv Bortolato, Santiago Andres
Arancibia, Juan Alberto
Escandar, Graciela Monica
author Bortolato, Santiago Andres
author_facet Bortolato, Santiago Andres
Arancibia, Juan Alberto
Escandar, Graciela Monica
author_role author
author2 Arancibia, Juan Alberto
Escandar, Graciela Monica
author2_role author
author
dc.subject.none.fl_str_mv Polycyclic Aromatic Hydrocarbons
Fluorescence
Optosensor
Chemometric Analysis
topic Polycyclic Aromatic Hydrocarbons
Fluorescence
Optosensor
Chemometric Analysis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The most concerned polycyclic aromatic hydrocarbons (PAHs) benzo[a]pyrene, dibenz[a,h]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]fluoranthene and benz[a]anthracene were simultaneously determined in the presence of other 10 interfering PAHs, applying second-order multivariate calibration to the data obtained with a flow-through optosensor interfaced to a fast-scanning spectrofluorimeter. Using a sample volume of 2.5 mL, detection limits in the range 5-115 ng L-1 were obtained in interfering samples, with a sample frequency of ca. 15 samples per hour, and with a minimum use of organic solvents, competing very favorably with chromatographic methods. The significance of this study lies in the solution of the quantitative analysis problem of six PAHs in real matrices of unknown composition. The unfolded partial least-squares/residual bilinearization (U-PLS/RBL) algorithm showed the best performance in resolving the complex studied system.
Fil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad Nacional de Rosario; Argentina
Fil: Arancibia, Juan Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina. Universidad Nacional de Rosario; Argentina
Fil: Escandar, Graciela Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina. Universidad Nacional de Rosario; Argentina
description The most concerned polycyclic aromatic hydrocarbons (PAHs) benzo[a]pyrene, dibenz[a,h]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]fluoranthene and benz[a]anthracene were simultaneously determined in the presence of other 10 interfering PAHs, applying second-order multivariate calibration to the data obtained with a flow-through optosensor interfaced to a fast-scanning spectrofluorimeter. Using a sample volume of 2.5 mL, detection limits in the range 5-115 ng L-1 were obtained in interfering samples, with a sample frequency of ca. 15 samples per hour, and with a minimum use of organic solvents, competing very favorably with chromatographic methods. The significance of this study lies in the solution of the quantitative analysis problem of six PAHs in real matrices of unknown composition. The unfolded partial least-squares/residual bilinearization (U-PLS/RBL) algorithm showed the best performance in resolving the complex studied system.
publishDate 2011
dc.date.none.fl_str_mv 2011-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/13224
Bortolato, Santiago Andres; Arancibia, Juan Alberto; Escandar, Graciela Monica; Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges; American Chemical Society; Environmental Science & Technology; 45; 4; 3-2011; 1513-1520
0013-936X
url http://hdl.handle.net/11336/13224
identifier_str_mv Bortolato, Santiago Andres; Arancibia, Juan Alberto; Escandar, Graciela Monica; Chemometrics-assisted fluorimetry for the rapid and selective determination of heavy polycyclic aromatic hydrocarbons in contaminated river waters and activated sludges; American Chemical Society; Environmental Science & Technology; 45; 4; 3-2011; 1513-1520
0013-936X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/es102811h
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/es102811h
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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