Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction

Autores
Vargas Balda, Ronald Eduardo; Carvajal, David; Madriz Ruiz, Lorean Mercedes; Scharifker, Benjamín R.
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
After introducing the basic aspects of the photoelectrochemical processes for the oxygen transfer reaction, we present the simplest kinetics models that have been built to represent the dynamics of light-induced redox reactions. Additionally, we discuss the basic chemical kinetics formalism usedin photocatalysis and photoelectrochemistry, where interplay between the oxidation process and nonequilibrium adsorbed states is considered. We also comment about the experimental developments related to the treatment of wastewater with electricity or H2 generation. Finally, we discuss the need to measure reaction rates to determine and compare the physicochemical parameters describing thechemical interactions during photoelectrochemical processes, in order to understand these reactive systems and apply them to new challenges related to the environment and energy.
Fil: Vargas Balda, Ronald Eduardo. Universidad Simon Bolivar.; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Instituto de Investigaciones Biotecnológicas "Dr. Raúl Alfonsín" (sede Chascomús). Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas. Instituto de Investigaciones Biotecnológicas "Dr. Raúl Alfonsín" (sede Chascomús); Argentina
Fil: Carvajal, David. Universidad Simon Bolivar.; Venezuela
Fil: Madriz Ruiz, Lorean Mercedes. Universidad Simon Bolivar.; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Scharifker, Benjamín R.. Universidad Simon Bolivar.; Venezuela. Universidad Metropolitana.; Venezuela
Materia
PHOTOELECTROCHEMISTRY
KINETIC MODELS
PHOTOCATALYSIS
WASTEWATER TREATMENT
H2 SOLAR FUEL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/118534
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reactionVargas Balda, Ronald EduardoCarvajal, DavidMadriz Ruiz, Lorean MercedesScharifker, Benjamín R.PHOTOELECTROCHEMISTRYKINETIC MODELSPHOTOCATALYSISWASTEWATER TREATMENTH2 SOLAR FUELhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1After introducing the basic aspects of the photoelectrochemical processes for the oxygen transfer reaction, we present the simplest kinetics models that have been built to represent the dynamics of light-induced redox reactions. Additionally, we discuss the basic chemical kinetics formalism usedin photocatalysis and photoelectrochemistry, where interplay between the oxidation process and nonequilibrium adsorbed states is considered. We also comment about the experimental developments related to the treatment of wastewater with electricity or H2 generation. Finally, we discuss the need to measure reaction rates to determine and compare the physicochemical parameters describing thechemical interactions during photoelectrochemical processes, in order to understand these reactive systems and apply them to new challenges related to the environment and energy.Fil: Vargas Balda, Ronald Eduardo. Universidad Simon Bolivar.; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Instituto de Investigaciones Biotecnológicas "Dr. Raúl Alfonsín" (sede Chascomús). Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas. Instituto de Investigaciones Biotecnológicas "Dr. Raúl Alfonsín" (sede Chascomús); ArgentinaFil: Carvajal, David. Universidad Simon Bolivar.; VenezuelaFil: Madriz Ruiz, Lorean Mercedes. Universidad Simon Bolivar.; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Scharifker, Benjamín R.. Universidad Simon Bolivar.; Venezuela. Universidad Metropolitana.; VenezuelaElsevier2019-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/118534Vargas Balda, Ronald Eduardo; Carvajal, David; Madriz Ruiz, Lorean Mercedes; Scharifker, Benjamín R.; Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction; Elsevier; Energy Reports; 6; S4; 2-2019; 2-122352-4847CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.egyr.2019.10.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2352484719303543?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:55:52Zoai:ri.conicet.gov.ar:11336/118534instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:55:53.145CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
title Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
spellingShingle Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
Vargas Balda, Ronald Eduardo
PHOTOELECTROCHEMISTRY
KINETIC MODELS
PHOTOCATALYSIS
WASTEWATER TREATMENT
H2 SOLAR FUEL
title_short Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
title_full Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
title_fullStr Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
title_full_unstemmed Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
title_sort Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction
dc.creator.none.fl_str_mv Vargas Balda, Ronald Eduardo
Carvajal, David
Madriz Ruiz, Lorean Mercedes
Scharifker, Benjamín R.
author Vargas Balda, Ronald Eduardo
author_facet Vargas Balda, Ronald Eduardo
Carvajal, David
Madriz Ruiz, Lorean Mercedes
Scharifker, Benjamín R.
author_role author
author2 Carvajal, David
Madriz Ruiz, Lorean Mercedes
Scharifker, Benjamín R.
author2_role author
author
author
dc.subject.none.fl_str_mv PHOTOELECTROCHEMISTRY
KINETIC MODELS
PHOTOCATALYSIS
WASTEWATER TREATMENT
H2 SOLAR FUEL
topic PHOTOELECTROCHEMISTRY
KINETIC MODELS
PHOTOCATALYSIS
WASTEWATER TREATMENT
H2 SOLAR FUEL
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv After introducing the basic aspects of the photoelectrochemical processes for the oxygen transfer reaction, we present the simplest kinetics models that have been built to represent the dynamics of light-induced redox reactions. Additionally, we discuss the basic chemical kinetics formalism usedin photocatalysis and photoelectrochemistry, where interplay between the oxidation process and nonequilibrium adsorbed states is considered. We also comment about the experimental developments related to the treatment of wastewater with electricity or H2 generation. Finally, we discuss the need to measure reaction rates to determine and compare the physicochemical parameters describing thechemical interactions during photoelectrochemical processes, in order to understand these reactive systems and apply them to new challenges related to the environment and energy.
Fil: Vargas Balda, Ronald Eduardo. Universidad Simon Bolivar.; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Biotecnológicas. Instituto de Investigaciones Biotecnológicas "Dr. Raúl Alfonsín" (sede Chascomús). Universidad Nacional de San Martín. Instituto de Investigaciones Biotecnológicas. Instituto de Investigaciones Biotecnológicas "Dr. Raúl Alfonsín" (sede Chascomús); Argentina
Fil: Carvajal, David. Universidad Simon Bolivar.; Venezuela
Fil: Madriz Ruiz, Lorean Mercedes. Universidad Simon Bolivar.; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Scharifker, Benjamín R.. Universidad Simon Bolivar.; Venezuela. Universidad Metropolitana.; Venezuela
description After introducing the basic aspects of the photoelectrochemical processes for the oxygen transfer reaction, we present the simplest kinetics models that have been built to represent the dynamics of light-induced redox reactions. Additionally, we discuss the basic chemical kinetics formalism usedin photocatalysis and photoelectrochemistry, where interplay between the oxidation process and nonequilibrium adsorbed states is considered. We also comment about the experimental developments related to the treatment of wastewater with electricity or H2 generation. Finally, we discuss the need to measure reaction rates to determine and compare the physicochemical parameters describing thechemical interactions during photoelectrochemical processes, in order to understand these reactive systems and apply them to new challenges related to the environment and energy.
publishDate 2019
dc.date.none.fl_str_mv 2019-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/118534
Vargas Balda, Ronald Eduardo; Carvajal, David; Madriz Ruiz, Lorean Mercedes; Scharifker, Benjamín R.; Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction; Elsevier; Energy Reports; 6; S4; 2-2019; 2-12
2352-4847
CONICET Digital
CONICET
url http://hdl.handle.net/11336/118534
identifier_str_mv Vargas Balda, Ronald Eduardo; Carvajal, David; Madriz Ruiz, Lorean Mercedes; Scharifker, Benjamín R.; Chemical kinetics in solar to chemical energy conversion: The photoelectrochemical oxygen transfer reaction; Elsevier; Energy Reports; 6; S4; 2-2019; 2-12
2352-4847
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.egyr.2019.10.004
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2352484719303543?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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