Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation

Autores
Avila, Adolfo María; Yu, Z.; Fazli, S.; Sawada, J. A.; Kuznicki, S. M.
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Lab-scale ethane dehydrogenation experiments with natural mordenite disks in a membrane reactor showed an increase in ethane conversion and ethylene yield compared to their equilibrium values. Experiments performed with larger membrane permeation area confirmed the trend that higher conversions are expected as the ratio of product permeation and product formation rates increases. Using the lab-scale membrane reactor module an ethylene yield enhancement of ∼17% was observed at 500 °C. At a higher reaction temperature (550 °C), ethane dehydrogenation experiments resulted in a ∼10% ethylene yield enhancement versus ∼6% for comparative experiments at 500 °C. At 550 °C the membrane reactor effectiveness improved since the H2 permeation rate increased proportionally more than its formation rate. This material screening test revealed natural mordenite as a material to be considered in the development of highly-integrated membrane reactor modules for dehydrogenation of alkanes.
Fil: Avila, Adolfo María. University of Alberta; Canadá. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yu, Z.. University of Alberta; Canadá
Fil: Fazli, S.. University of Alberta; Canadá
Fil: Sawada, J. A.. University of Alberta; Canadá
Fil: Kuznicki, S. M.. University of Alberta; Canadá
Materia
Membrane Reactor
Ethane Dehydrogenation
Ethylene Production
Material Screening
Natural Zeolite
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31603
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenationAvila, Adolfo MaríaYu, Z.Fazli, S.Sawada, J. A.Kuznicki, S. M.Membrane ReactorEthane DehydrogenationEthylene ProductionMaterial ScreeningNatural Zeolitehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Lab-scale ethane dehydrogenation experiments with natural mordenite disks in a membrane reactor showed an increase in ethane conversion and ethylene yield compared to their equilibrium values. Experiments performed with larger membrane permeation area confirmed the trend that higher conversions are expected as the ratio of product permeation and product formation rates increases. Using the lab-scale membrane reactor module an ethylene yield enhancement of ∼17% was observed at 500 °C. At a higher reaction temperature (550 °C), ethane dehydrogenation experiments resulted in a ∼10% ethylene yield enhancement versus ∼6% for comparative experiments at 500 °C. At 550 °C the membrane reactor effectiveness improved since the H2 permeation rate increased proportionally more than its formation rate. This material screening test revealed natural mordenite as a material to be considered in the development of highly-integrated membrane reactor modules for dehydrogenation of alkanes.Fil: Avila, Adolfo María. University of Alberta; Canadá. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Yu, Z.. University of Alberta; CanadáFil: Fazli, S.. University of Alberta; CanadáFil: Sawada, J. A.. University of Alberta; CanadáFil: Kuznicki, S. M.. University of Alberta; CanadáElsevier2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31603Fazli, S.; Yu, Z.; Sawada, J. A.; Avila, Adolfo María; Kuznicki, S. M.; Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation; Elsevier; Microporous and Mesoporous Materials; 190; 2-2014; 301-3081387-1811CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2014.02.024info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387181114000857info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:51:03Zoai:ri.conicet.gov.ar:11336/31603instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:51:04.231CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
title Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
spellingShingle Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
Avila, Adolfo María
Membrane Reactor
Ethane Dehydrogenation
Ethylene Production
Material Screening
Natural Zeolite
title_short Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
title_full Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
title_fullStr Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
title_full_unstemmed Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
title_sort Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation
dc.creator.none.fl_str_mv Avila, Adolfo María
Yu, Z.
Fazli, S.
Sawada, J. A.
Kuznicki, S. M.
author Avila, Adolfo María
author_facet Avila, Adolfo María
Yu, Z.
Fazli, S.
Sawada, J. A.
Kuznicki, S. M.
author_role author
author2 Yu, Z.
Fazli, S.
Sawada, J. A.
Kuznicki, S. M.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Membrane Reactor
Ethane Dehydrogenation
Ethylene Production
Material Screening
Natural Zeolite
topic Membrane Reactor
Ethane Dehydrogenation
Ethylene Production
Material Screening
Natural Zeolite
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Lab-scale ethane dehydrogenation experiments with natural mordenite disks in a membrane reactor showed an increase in ethane conversion and ethylene yield compared to their equilibrium values. Experiments performed with larger membrane permeation area confirmed the trend that higher conversions are expected as the ratio of product permeation and product formation rates increases. Using the lab-scale membrane reactor module an ethylene yield enhancement of ∼17% was observed at 500 °C. At a higher reaction temperature (550 °C), ethane dehydrogenation experiments resulted in a ∼10% ethylene yield enhancement versus ∼6% for comparative experiments at 500 °C. At 550 °C the membrane reactor effectiveness improved since the H2 permeation rate increased proportionally more than its formation rate. This material screening test revealed natural mordenite as a material to be considered in the development of highly-integrated membrane reactor modules for dehydrogenation of alkanes.
Fil: Avila, Adolfo María. University of Alberta; Canadá. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yu, Z.. University of Alberta; Canadá
Fil: Fazli, S.. University of Alberta; Canadá
Fil: Sawada, J. A.. University of Alberta; Canadá
Fil: Kuznicki, S. M.. University of Alberta; Canadá
description Lab-scale ethane dehydrogenation experiments with natural mordenite disks in a membrane reactor showed an increase in ethane conversion and ethylene yield compared to their equilibrium values. Experiments performed with larger membrane permeation area confirmed the trend that higher conversions are expected as the ratio of product permeation and product formation rates increases. Using the lab-scale membrane reactor module an ethylene yield enhancement of ∼17% was observed at 500 °C. At a higher reaction temperature (550 °C), ethane dehydrogenation experiments resulted in a ∼10% ethylene yield enhancement versus ∼6% for comparative experiments at 500 °C. At 550 °C the membrane reactor effectiveness improved since the H2 permeation rate increased proportionally more than its formation rate. This material screening test revealed natural mordenite as a material to be considered in the development of highly-integrated membrane reactor modules for dehydrogenation of alkanes.
publishDate 2014
dc.date.none.fl_str_mv 2014-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31603
Fazli, S.; Yu, Z.; Sawada, J. A.; Avila, Adolfo María; Kuznicki, S. M.; Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation; Elsevier; Microporous and Mesoporous Materials; 190; 2-2014; 301-308
1387-1811
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31603
identifier_str_mv Fazli, S.; Yu, Z.; Sawada, J. A.; Avila, Adolfo María; Kuznicki, S. M.; Hydrogen-selective natural mordenite in a membrane reactor for ethane dehydrogenation; Elsevier; Microporous and Mesoporous Materials; 190; 2-2014; 301-308
1387-1811
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2014.02.024
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1387181114000857
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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