Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study

Autores
Rodriguez, Maria Laura; Ardissone, Daniel Enrique; Heracleous, Eleni; Lemonidou, Angeliki A.; Lopez, Eduardo; Pedernera, Marisa Noemi; Borio, Daniel Oscar
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This contribution presents a theoretical study of a multitubular packed-bed membrane reactor for the ethane to ethylene oxidative dehydrogenation reaction over a highly active and selective Ni-Nb-O mixed oxide catalyst. This theoretical study takes into account the radial composition and temperature profiles using a two-dimensional pseudo-homogeneous model on the reaction side. The feasibility and convenience of using this novel design, as well as the influence of the main operating variables on the reactor performance, are analyzed. The introduction of the membrane leads to lower oxygen partial pressures inside the catalyst tubes, which results in an improved selectivity to ethylene (lower heat generation rates) and high effective heat transfer area per unit volume. The multitubular membrane reactor enables significant ethylene productions per tube and milder temperature profiles than a conventional wall-cooled fixed-bed reactor. Operating conditions have to be carefully adjusted to avoid undesired oxygen accumulation inside the tubes. The presence of small amounts of oxygen at the reactor inlet significantly improves the ethylene production rates. © 2010 Elsevier B.V. All rights reserved.
Fil: Rodriguez, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Ardissone, Daniel Enrique. Universidad Nacional de San Luis; Argentina
Fil: Heracleous, Eleni. Aristotle Univ. of Thessaloniki; Grecia
Fil: Lemonidou, Angeliki A.. Aristotle Univ. of Thessaloniki; Grecia
Fil: Lopez, Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pedernera, Marisa Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Borio, Daniel Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Ethane
Membrane Reactor
Modeling
Ni-Nb-O Catalyst
Oxidative Dehydrogenation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/57730
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/57730
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical studyRodriguez, Maria LauraArdissone, Daniel EnriqueHeracleous, EleniLemonidou, Angeliki A.Lopez, EduardoPedernera, Marisa NoemiBorio, Daniel OscarEthaneMembrane ReactorModelingNi-Nb-O CatalystOxidative Dehydrogenationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This contribution presents a theoretical study of a multitubular packed-bed membrane reactor for the ethane to ethylene oxidative dehydrogenation reaction over a highly active and selective Ni-Nb-O mixed oxide catalyst. This theoretical study takes into account the radial composition and temperature profiles using a two-dimensional pseudo-homogeneous model on the reaction side. The feasibility and convenience of using this novel design, as well as the influence of the main operating variables on the reactor performance, are analyzed. The introduction of the membrane leads to lower oxygen partial pressures inside the catalyst tubes, which results in an improved selectivity to ethylene (lower heat generation rates) and high effective heat transfer area per unit volume. The multitubular membrane reactor enables significant ethylene productions per tube and milder temperature profiles than a conventional wall-cooled fixed-bed reactor. Operating conditions have to be carefully adjusted to avoid undesired oxygen accumulation inside the tubes. The presence of small amounts of oxygen at the reactor inlet significantly improves the ethylene production rates. © 2010 Elsevier B.V. All rights reserved.Fil: Rodriguez, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Ardissone, Daniel Enrique. Universidad Nacional de San Luis; ArgentinaFil: Heracleous, Eleni. Aristotle Univ. of Thessaloniki; GreciaFil: Lemonidou, Angeliki A.. Aristotle Univ. of Thessaloniki; GreciaFil: Lopez, Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Pedernera, Marisa Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Borio, Daniel Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2010-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57730Rodriguez, Maria Laura; Ardissone, Daniel Enrique; Heracleous, Eleni; Lemonidou, Angeliki A.; Lopez, Eduardo; et al.; Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study; Elsevier Science; Catalysis Today; 157; 1-4; 11-2010; 303-3090920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2010.01.053info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586110000593info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:08:37Zoai:ri.conicet.gov.ar:11336/57730instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:08:37.675CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
title Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
spellingShingle Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
Rodriguez, Maria Laura
Ethane
Membrane Reactor
Modeling
Ni-Nb-O Catalyst
Oxidative Dehydrogenation
title_short Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
title_full Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
title_fullStr Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
title_full_unstemmed Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
title_sort Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study
dc.creator.none.fl_str_mv Rodriguez, Maria Laura
Ardissone, Daniel Enrique
Heracleous, Eleni
Lemonidou, Angeliki A.
Lopez, Eduardo
Pedernera, Marisa Noemi
Borio, Daniel Oscar
author Rodriguez, Maria Laura
author_facet Rodriguez, Maria Laura
Ardissone, Daniel Enrique
Heracleous, Eleni
Lemonidou, Angeliki A.
Lopez, Eduardo
Pedernera, Marisa Noemi
Borio, Daniel Oscar
author_role author
author2 Ardissone, Daniel Enrique
Heracleous, Eleni
Lemonidou, Angeliki A.
Lopez, Eduardo
Pedernera, Marisa Noemi
Borio, Daniel Oscar
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Ethane
Membrane Reactor
Modeling
Ni-Nb-O Catalyst
Oxidative Dehydrogenation
topic Ethane
Membrane Reactor
Modeling
Ni-Nb-O Catalyst
Oxidative Dehydrogenation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This contribution presents a theoretical study of a multitubular packed-bed membrane reactor for the ethane to ethylene oxidative dehydrogenation reaction over a highly active and selective Ni-Nb-O mixed oxide catalyst. This theoretical study takes into account the radial composition and temperature profiles using a two-dimensional pseudo-homogeneous model on the reaction side. The feasibility and convenience of using this novel design, as well as the influence of the main operating variables on the reactor performance, are analyzed. The introduction of the membrane leads to lower oxygen partial pressures inside the catalyst tubes, which results in an improved selectivity to ethylene (lower heat generation rates) and high effective heat transfer area per unit volume. The multitubular membrane reactor enables significant ethylene productions per tube and milder temperature profiles than a conventional wall-cooled fixed-bed reactor. Operating conditions have to be carefully adjusted to avoid undesired oxygen accumulation inside the tubes. The presence of small amounts of oxygen at the reactor inlet significantly improves the ethylene production rates. © 2010 Elsevier B.V. All rights reserved.
Fil: Rodriguez, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Ardissone, Daniel Enrique. Universidad Nacional de San Luis; Argentina
Fil: Heracleous, Eleni. Aristotle Univ. of Thessaloniki; Grecia
Fil: Lemonidou, Angeliki A.. Aristotle Univ. of Thessaloniki; Grecia
Fil: Lopez, Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pedernera, Marisa Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Borio, Daniel Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description This contribution presents a theoretical study of a multitubular packed-bed membrane reactor for the ethane to ethylene oxidative dehydrogenation reaction over a highly active and selective Ni-Nb-O mixed oxide catalyst. This theoretical study takes into account the radial composition and temperature profiles using a two-dimensional pseudo-homogeneous model on the reaction side. The feasibility and convenience of using this novel design, as well as the influence of the main operating variables on the reactor performance, are analyzed. The introduction of the membrane leads to lower oxygen partial pressures inside the catalyst tubes, which results in an improved selectivity to ethylene (lower heat generation rates) and high effective heat transfer area per unit volume. The multitubular membrane reactor enables significant ethylene productions per tube and milder temperature profiles than a conventional wall-cooled fixed-bed reactor. Operating conditions have to be carefully adjusted to avoid undesired oxygen accumulation inside the tubes. The presence of small amounts of oxygen at the reactor inlet significantly improves the ethylene production rates. © 2010 Elsevier B.V. All rights reserved.
publishDate 2010
dc.date.none.fl_str_mv 2010-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/57730
Rodriguez, Maria Laura; Ardissone, Daniel Enrique; Heracleous, Eleni; Lemonidou, Angeliki A.; Lopez, Eduardo; et al.; Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study; Elsevier Science; Catalysis Today; 157; 1-4; 11-2010; 303-309
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/57730
identifier_str_mv Rodriguez, Maria Laura; Ardissone, Daniel Enrique; Heracleous, Eleni; Lemonidou, Angeliki A.; Lopez, Eduardo; et al.; Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study; Elsevier Science; Catalysis Today; 157; 1-4; 11-2010; 303-309
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2010.01.053
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586110000593
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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