Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane

Autores
Bortolozzi, Juan Pablo; Portela, Raquel; Ávila, Pedro; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A novel gamma-alumina-supported Ni-Ce-Zr catalyst with cellular structure was developed for oxidative dehydrogenation of ethane (ODHE). First, powdered samples were synthesized to study the effect of both the total metal content and the Ce/Zr ratio on the physicochemical properties and performance of these catalysts. All synthesized powdered samples were highly active and selective for ODHE with a maximum ethylene productivity of 6.94 µmolethylene gact cat-1 s-1. According to the results, cerium addition increased the most reducible nickel species population, which would benefit ethane conversion, whereas zirconium incorporation would enhance ethylene selectivity through the generation of higher amounts of the least reducible nickel species. Therefore, the modification of active site properties by addition of both promoters synergistically increases the productivity of the Ni-based catalysts. The most efficient formulation, in terms of ethylene productivity per active phase amount, contained 15 wt% of the mixed oxide with Ni0.85Ce0.075Zr0.075 composition. This formulation was selected to synthesize a Ni-Ce-Zr/Al2O3 structured body by deposition of the active phase onto a homemade gamma-alumina monolith. The structured support was manufactured by extrusion of boehmite-containing dough. The main properties of the Ni0.85Ce0.075Zr0.075 powder were successfully preserved after the shaping procedure. In addition, the catalytic performance of the monolithic sample was comparable in terms of ethylene productivity to that of the powdered counterpart.
Fil: Bortolozzi, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Portela, Raquel. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Ávila, Pedro. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Ni-Ce-Zr
ALUMINA CELLULAR STRUCTURE
OXIDATIVE DEHYDROGENATION
ETHYLENE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44152
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/44152
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of EthaneBortolozzi, Juan PabloPortela, RaquelÁvila, PedroMilt, Viviana GuadalupeMiro, Eduardo ErnestoNi-Ce-ZrALUMINA CELLULAR STRUCTUREOXIDATIVE DEHYDROGENATIONETHYLENEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A novel gamma-alumina-supported Ni-Ce-Zr catalyst with cellular structure was developed for oxidative dehydrogenation of ethane (ODHE). First, powdered samples were synthesized to study the effect of both the total metal content and the Ce/Zr ratio on the physicochemical properties and performance of these catalysts. All synthesized powdered samples were highly active and selective for ODHE with a maximum ethylene productivity of 6.94 µmolethylene gact cat-1 s-1. According to the results, cerium addition increased the most reducible nickel species population, which would benefit ethane conversion, whereas zirconium incorporation would enhance ethylene selectivity through the generation of higher amounts of the least reducible nickel species. Therefore, the modification of active site properties by addition of both promoters synergistically increases the productivity of the Ni-based catalysts. The most efficient formulation, in terms of ethylene productivity per active phase amount, contained 15 wt% of the mixed oxide with Ni0.85Ce0.075Zr0.075 composition. This formulation was selected to synthesize a Ni-Ce-Zr/Al2O3 structured body by deposition of the active phase onto a homemade gamma-alumina monolith. The structured support was manufactured by extrusion of boehmite-containing dough. The main properties of the Ni0.85Ce0.075Zr0.075 powder were successfully preserved after the shaping procedure. In addition, the catalytic performance of the monolithic sample was comparable in terms of ethylene productivity to that of the powdered counterpart.Fil: Bortolozzi, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Portela, Raquel. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; EspañaFil: Ávila, Pedro. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; EspañaFil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaMDPI2017-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44152Bortolozzi, Juan Pablo; Portela, Raquel; Ávila, Pedro; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto; Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane; MDPI; Catalysts; 7; 11; 11-2017; 331-3442073-4344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.mdpi.com/2073-4344/7/11/331info:eu-repo/semantics/altIdentifier/doi/doi:10.3390/catal7110331info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:55:43Zoai:ri.conicet.gov.ar:11336/44152instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:55:43.394CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
title Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
spellingShingle Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
Bortolozzi, Juan Pablo
Ni-Ce-Zr
ALUMINA CELLULAR STRUCTURE
OXIDATIVE DEHYDROGENATION
ETHYLENE
title_short Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
title_full Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
title_fullStr Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
title_full_unstemmed Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
title_sort Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane
dc.creator.none.fl_str_mv Bortolozzi, Juan Pablo
Portela, Raquel
Ávila, Pedro
Milt, Viviana Guadalupe
Miro, Eduardo Ernesto
author Bortolozzi, Juan Pablo
author_facet Bortolozzi, Juan Pablo
Portela, Raquel
Ávila, Pedro
Milt, Viviana Guadalupe
Miro, Eduardo Ernesto
author_role author
author2 Portela, Raquel
Ávila, Pedro
Milt, Viviana Guadalupe
Miro, Eduardo Ernesto
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ni-Ce-Zr
ALUMINA CELLULAR STRUCTURE
OXIDATIVE DEHYDROGENATION
ETHYLENE
topic Ni-Ce-Zr
ALUMINA CELLULAR STRUCTURE
OXIDATIVE DEHYDROGENATION
ETHYLENE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A novel gamma-alumina-supported Ni-Ce-Zr catalyst with cellular structure was developed for oxidative dehydrogenation of ethane (ODHE). First, powdered samples were synthesized to study the effect of both the total metal content and the Ce/Zr ratio on the physicochemical properties and performance of these catalysts. All synthesized powdered samples were highly active and selective for ODHE with a maximum ethylene productivity of 6.94 µmolethylene gact cat-1 s-1. According to the results, cerium addition increased the most reducible nickel species population, which would benefit ethane conversion, whereas zirconium incorporation would enhance ethylene selectivity through the generation of higher amounts of the least reducible nickel species. Therefore, the modification of active site properties by addition of both promoters synergistically increases the productivity of the Ni-based catalysts. The most efficient formulation, in terms of ethylene productivity per active phase amount, contained 15 wt% of the mixed oxide with Ni0.85Ce0.075Zr0.075 composition. This formulation was selected to synthesize a Ni-Ce-Zr/Al2O3 structured body by deposition of the active phase onto a homemade gamma-alumina monolith. The structured support was manufactured by extrusion of boehmite-containing dough. The main properties of the Ni0.85Ce0.075Zr0.075 powder were successfully preserved after the shaping procedure. In addition, the catalytic performance of the monolithic sample was comparable in terms of ethylene productivity to that of the powdered counterpart.
Fil: Bortolozzi, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Portela, Raquel. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Ávila, Pedro. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description A novel gamma-alumina-supported Ni-Ce-Zr catalyst with cellular structure was developed for oxidative dehydrogenation of ethane (ODHE). First, powdered samples were synthesized to study the effect of both the total metal content and the Ce/Zr ratio on the physicochemical properties and performance of these catalysts. All synthesized powdered samples were highly active and selective for ODHE with a maximum ethylene productivity of 6.94 µmolethylene gact cat-1 s-1. According to the results, cerium addition increased the most reducible nickel species population, which would benefit ethane conversion, whereas zirconium incorporation would enhance ethylene selectivity through the generation of higher amounts of the least reducible nickel species. Therefore, the modification of active site properties by addition of both promoters synergistically increases the productivity of the Ni-based catalysts. The most efficient formulation, in terms of ethylene productivity per active phase amount, contained 15 wt% of the mixed oxide with Ni0.85Ce0.075Zr0.075 composition. This formulation was selected to synthesize a Ni-Ce-Zr/Al2O3 structured body by deposition of the active phase onto a homemade gamma-alumina monolith. The structured support was manufactured by extrusion of boehmite-containing dough. The main properties of the Ni0.85Ce0.075Zr0.075 powder were successfully preserved after the shaping procedure. In addition, the catalytic performance of the monolithic sample was comparable in terms of ethylene productivity to that of the powdered counterpart.
publishDate 2017
dc.date.none.fl_str_mv 2017-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44152
Bortolozzi, Juan Pablo; Portela, Raquel; Ávila, Pedro; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto; Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane; MDPI; Catalysts; 7; 11; 11-2017; 331-344
2073-4344
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44152
identifier_str_mv Bortolozzi, Juan Pablo; Portela, Raquel; Ávila, Pedro; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto; Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane; MDPI; Catalysts; 7; 11; 11-2017; 331-344
2073-4344
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.mdpi.com/2073-4344/7/11/331
info:eu-repo/semantics/altIdentifier/doi/doi:10.3390/catal7110331
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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