Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations

Autores
Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy.
Fil: Boscoboinik, Alejandro Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Tysoe, W. T.. University of Wisconsin; Estados Unidos
Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Boscoboinik, Alejandro Miguel. Brookhaven National Laboratory; Estados Unidos
Materia
Nanoarchitectures
Molecular Wires
Self-Assembly
Monte Carlo Simulation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/60570

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spelling Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo SimulationsBoscoboinik, Alejandro MiguelManzi, Sergio JavierTysoe, W. T.Pereyra, Victor DanielBoscoboinik, Alejandro MiguelNanoarchitecturesMolecular WiresSelf-AssemblyMonte Carlo Simulationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy.Fil: Boscoboinik, Alejandro Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Tysoe, W. T.. University of Wisconsin; Estados UnidosFil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Boscoboinik, Alejandro Miguel. Brookhaven National Laboratory; Estados UnidosAmerican Chemical Society2015-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/60570Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel; Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations; American Chemical Society; Chemistry Of Materials; 27; 19; 9-2015; 6642-66490897-4756CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.5b02413info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.5b02413info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:25:47Zoai:ri.conicet.gov.ar:11336/60570instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:25:47.697CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
title Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
spellingShingle Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
Boscoboinik, Alejandro Miguel
Nanoarchitectures
Molecular Wires
Self-Assembly
Monte Carlo Simulation
title_short Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
title_full Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
title_fullStr Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
title_full_unstemmed Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
title_sort Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
dc.creator.none.fl_str_mv Boscoboinik, Alejandro Miguel
Manzi, Sergio Javier
Tysoe, W. T.
Pereyra, Victor Daniel
Boscoboinik, Alejandro Miguel
author Boscoboinik, Alejandro Miguel
author_facet Boscoboinik, Alejandro Miguel
Manzi, Sergio Javier
Tysoe, W. T.
Pereyra, Victor Daniel
author_role author
author2 Manzi, Sergio Javier
Tysoe, W. T.
Pereyra, Victor Daniel
author2_role author
author
author
dc.subject.none.fl_str_mv Nanoarchitectures
Molecular Wires
Self-Assembly
Monte Carlo Simulation
topic Nanoarchitectures
Molecular Wires
Self-Assembly
Monte Carlo Simulation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy.
Fil: Boscoboinik, Alejandro Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Tysoe, W. T.. University of Wisconsin; Estados Unidos
Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Boscoboinik, Alejandro Miguel. Brookhaven National Laboratory; Estados Unidos
description The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy.
publishDate 2015
dc.date.none.fl_str_mv 2015-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/60570
Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel; Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations; American Chemical Society; Chemistry Of Materials; 27; 19; 9-2015; 6642-6649
0897-4756
CONICET Digital
CONICET
url http://hdl.handle.net/11336/60570
identifier_str_mv Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel; Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations; American Chemical Society; Chemistry Of Materials; 27; 19; 9-2015; 6642-6649
0897-4756
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.5b02413
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.5b02413
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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