Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
- Autores
- Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy.
Fil: Boscoboinik, Alejandro Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Tysoe, W. T.. University of Wisconsin; Estados Unidos
Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Boscoboinik, Alejandro Miguel. Brookhaven National Laboratory; Estados Unidos - Materia
-
Nanoarchitectures
Molecular Wires
Self-Assembly
Monte Carlo Simulation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/60570
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Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo SimulationsBoscoboinik, Alejandro MiguelManzi, Sergio JavierTysoe, W. T.Pereyra, Victor DanielBoscoboinik, Alejandro MiguelNanoarchitecturesMolecular WiresSelf-AssemblyMonte Carlo Simulationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy.Fil: Boscoboinik, Alejandro Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Tysoe, W. T.. University of Wisconsin; Estados UnidosFil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Boscoboinik, Alejandro Miguel. Brookhaven National Laboratory; Estados UnidosAmerican Chemical Society2015-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/60570Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel; Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations; American Chemical Society; Chemistry Of Materials; 27; 19; 9-2015; 6642-66490897-4756CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.5b02413info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.5b02413info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:25:47Zoai:ri.conicet.gov.ar:11336/60570instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:25:47.697CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations |
title |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations |
spellingShingle |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations Boscoboinik, Alejandro Miguel Nanoarchitectures Molecular Wires Self-Assembly Monte Carlo Simulation |
title_short |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations |
title_full |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations |
title_fullStr |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations |
title_full_unstemmed |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations |
title_sort |
Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations |
dc.creator.none.fl_str_mv |
Boscoboinik, Alejandro Miguel Manzi, Sergio Javier Tysoe, W. T. Pereyra, Victor Daniel Boscoboinik, Alejandro Miguel |
author |
Boscoboinik, Alejandro Miguel |
author_facet |
Boscoboinik, Alejandro Miguel Manzi, Sergio Javier Tysoe, W. T. Pereyra, Victor Daniel |
author_role |
author |
author2 |
Manzi, Sergio Javier Tysoe, W. T. Pereyra, Victor Daniel |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Nanoarchitectures Molecular Wires Self-Assembly Monte Carlo Simulation |
topic |
Nanoarchitectures Molecular Wires Self-Assembly Monte Carlo Simulation |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy. Fil: Boscoboinik, Alejandro Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina Fil: Tysoe, W. T.. University of Wisconsin; Estados Unidos Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina Fil: Boscoboinik, Alejandro Miguel. Brookhaven National Laboratory; Estados Unidos |
description |
The influence of directing agents in the self-assembly of molecular wires to produce two-dimensional electronic nanoarchitectures is studied here using a Monte Carlo approach to simulate the effect of arbitrarily locating nodal points on a surface, from which the growth of self-assembled molecular wires can be nucleated. This is compared to experimental results reported for the self-assembly of molecular wires when 1,4-phenylenediisocyanide (PDI) is adsorbed on Au(111). The latter results in the formation of (Au-PDI)n organometallic chains, which were shown to be conductive when linked between gold nanoparticles on an insulating substrate. The present study analyzes, by means of stochastic methods, the influence of variables that affect the growth and design of self-assembled conductive nanoarchitectures, such as the distance between nodes, coverage of the monomeric units that leads to the formation of the desired architectures, and the interaction between the monomeric units. This work proposes an approach and sets the stage for the production of complex 2D nanoarchitectures using a bottom-up strategy but including the use of current state-of-the-art top-down technology as an integral part of the self-assembly strategy. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/60570 Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel; Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations; American Chemical Society; Chemistry Of Materials; 27; 19; 9-2015; 6642-6649 0897-4756 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/60570 |
identifier_str_mv |
Boscoboinik, Alejandro Miguel; Manzi, Sergio Javier; Tysoe, W. T.; Pereyra, Victor Daniel; Boscoboinik, Alejandro Miguel; Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations; American Chemical Society; Chemistry Of Materials; 27; 19; 9-2015; 6642-6649 0897-4756 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.5b02413 info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.5b02413 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1846082696779923456 |
score |
13.22299 |