Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach

Autores
Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Soler Illia, Galo Juan de Avila Arturo; Tang, Qiyun; Müller, Marcus; Takahashi, Masahide
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Mesoporous crystalline (hydr)oxides of low-valence metal ions (M(II) and M(III)) are highly demanded in the context of various applications. In this study, we demonstrate key factors to the successful formation of ordered mesoporous films through the assembly of nanobuilding block (ANBB) approach using a colloidal solution of crystalline M(OH) 2 (M = Mn, Fe, Co, Ni, and Cu). The colloidal system of α-Ni(OH) 2 is presented in depth as a typical example. Crystal growth and aggregation kinetics of the NBB were tuned by synthetic parameters. Nanometer-sized NBBs of tailored size between oligomer scale to over 20 nm were obtained. The films prepared from α-Ni(OH) 2 NBBs with a diameter of ≤7.5 nm showed ordered mesostructures through evaporation-induced self-assembly in the presence of supramolecular templates. Coarse-grained simulations suggest that there is a threshold diameter of NBB toward the formation of well-ordered mesostructures. It was found that, as well as limiting the diameter of NBB, inhibition of an aggregation of NBBs by using coordinative additives or diluting the NBB colloidal solution was essential to control the assembly of NBBs and templates into the ordered mesostructures. The results obtained here open up the synthesis of ordered mesoporous materials with a crystalline wall of variety of chemical compositions containing low-valence metal elements.
Fil: Tarutani, Naoki. Osaka Prefecture University; Japón
Fil: Tokudome, Yasuaki. Osaka Prefecture University; Japón
Fil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Tang, Qiyun. Universität Göttingen; Alemania
Fil: Müller, Marcus. Universität Göttingen; Alemania
Fil: Takahashi, Masahide. Osaka Prefecture University; Japón
Materia
mesoporous films
self assembly
epoxide route
simulation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/133152
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/133152
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approachTarutani, NaokiTokudome, YasuakiJobbagy, MatiasSoler Illia, Galo Juan de Avila ArturoTang, QiyunMüller, MarcusTakahashi, Masahidemesoporous filmsself assemblyepoxide routesimulationhttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Mesoporous crystalline (hydr)oxides of low-valence metal ions (M(II) and M(III)) are highly demanded in the context of various applications. In this study, we demonstrate key factors to the successful formation of ordered mesoporous films through the assembly of nanobuilding block (ANBB) approach using a colloidal solution of crystalline M(OH) 2 (M = Mn, Fe, Co, Ni, and Cu). The colloidal system of α-Ni(OH) 2 is presented in depth as a typical example. Crystal growth and aggregation kinetics of the NBB were tuned by synthetic parameters. Nanometer-sized NBBs of tailored size between oligomer scale to over 20 nm were obtained. The films prepared from α-Ni(OH) 2 NBBs with a diameter of ≤7.5 nm showed ordered mesostructures through evaporation-induced self-assembly in the presence of supramolecular templates. Coarse-grained simulations suggest that there is a threshold diameter of NBB toward the formation of well-ordered mesostructures. It was found that, as well as limiting the diameter of NBB, inhibition of an aggregation of NBBs by using coordinative additives or diluting the NBB colloidal solution was essential to control the assembly of NBBs and templates into the ordered mesostructures. The results obtained here open up the synthesis of ordered mesoporous materials with a crystalline wall of variety of chemical compositions containing low-valence metal elements.Fil: Tarutani, Naoki. Osaka Prefecture University; JapónFil: Tokudome, Yasuaki. Osaka Prefecture University; JapónFil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Tang, Qiyun. Universität Göttingen; AlemaniaFil: Müller, Marcus. Universität Göttingen; AlemaniaFil: Takahashi, Masahide. Osaka Prefecture University; JapónAmerican Chemical Society2019-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/133152Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Soler Illia, Galo Juan de Avila Arturo; Tang, Qiyun; et al.; Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach; American Chemical Society; Chemistry Of Materials; 31; 2; 1-2019; 322-3300897-4756CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.8b03082info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.8b03082info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:17Zoai:ri.conicet.gov.ar:11336/133152instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:18.007CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
title Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
spellingShingle Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
Tarutani, Naoki
mesoporous films
self assembly
epoxide route
simulation
title_short Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
title_full Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
title_fullStr Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
title_full_unstemmed Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
title_sort Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach
dc.creator.none.fl_str_mv Tarutani, Naoki
Tokudome, Yasuaki
Jobbagy, Matias
Soler Illia, Galo Juan de Avila Arturo
Tang, Qiyun
Müller, Marcus
Takahashi, Masahide
author Tarutani, Naoki
author_facet Tarutani, Naoki
Tokudome, Yasuaki
Jobbagy, Matias
Soler Illia, Galo Juan de Avila Arturo
Tang, Qiyun
Müller, Marcus
Takahashi, Masahide
author_role author
author2 Tokudome, Yasuaki
Jobbagy, Matias
Soler Illia, Galo Juan de Avila Arturo
Tang, Qiyun
Müller, Marcus
Takahashi, Masahide
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv mesoporous films
self assembly
epoxide route
simulation
topic mesoporous films
self assembly
epoxide route
simulation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Mesoporous crystalline (hydr)oxides of low-valence metal ions (M(II) and M(III)) are highly demanded in the context of various applications. In this study, we demonstrate key factors to the successful formation of ordered mesoporous films through the assembly of nanobuilding block (ANBB) approach using a colloidal solution of crystalline M(OH) 2 (M = Mn, Fe, Co, Ni, and Cu). The colloidal system of α-Ni(OH) 2 is presented in depth as a typical example. Crystal growth and aggregation kinetics of the NBB were tuned by synthetic parameters. Nanometer-sized NBBs of tailored size between oligomer scale to over 20 nm were obtained. The films prepared from α-Ni(OH) 2 NBBs with a diameter of ≤7.5 nm showed ordered mesostructures through evaporation-induced self-assembly in the presence of supramolecular templates. Coarse-grained simulations suggest that there is a threshold diameter of NBB toward the formation of well-ordered mesostructures. It was found that, as well as limiting the diameter of NBB, inhibition of an aggregation of NBBs by using coordinative additives or diluting the NBB colloidal solution was essential to control the assembly of NBBs and templates into the ordered mesostructures. The results obtained here open up the synthesis of ordered mesoporous materials with a crystalline wall of variety of chemical compositions containing low-valence metal elements.
Fil: Tarutani, Naoki. Osaka Prefecture University; Japón
Fil: Tokudome, Yasuaki. Osaka Prefecture University; Japón
Fil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Tang, Qiyun. Universität Göttingen; Alemania
Fil: Müller, Marcus. Universität Göttingen; Alemania
Fil: Takahashi, Masahide. Osaka Prefecture University; Japón
description Mesoporous crystalline (hydr)oxides of low-valence metal ions (M(II) and M(III)) are highly demanded in the context of various applications. In this study, we demonstrate key factors to the successful formation of ordered mesoporous films through the assembly of nanobuilding block (ANBB) approach using a colloidal solution of crystalline M(OH) 2 (M = Mn, Fe, Co, Ni, and Cu). The colloidal system of α-Ni(OH) 2 is presented in depth as a typical example. Crystal growth and aggregation kinetics of the NBB were tuned by synthetic parameters. Nanometer-sized NBBs of tailored size between oligomer scale to over 20 nm were obtained. The films prepared from α-Ni(OH) 2 NBBs with a diameter of ≤7.5 nm showed ordered mesostructures through evaporation-induced self-assembly in the presence of supramolecular templates. Coarse-grained simulations suggest that there is a threshold diameter of NBB toward the formation of well-ordered mesostructures. It was found that, as well as limiting the diameter of NBB, inhibition of an aggregation of NBBs by using coordinative additives or diluting the NBB colloidal solution was essential to control the assembly of NBBs and templates into the ordered mesostructures. The results obtained here open up the synthesis of ordered mesoporous materials with a crystalline wall of variety of chemical compositions containing low-valence metal elements.
publishDate 2019
dc.date.none.fl_str_mv 2019-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/133152
Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Soler Illia, Galo Juan de Avila Arturo; Tang, Qiyun; et al.; Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach; American Chemical Society; Chemistry Of Materials; 31; 2; 1-2019; 322-330
0897-4756
CONICET Digital
CONICET
url http://hdl.handle.net/11336/133152
identifier_str_mv Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Soler Illia, Galo Juan de Avila Arturo; Tang, Qiyun; et al.; Highly ordered mesoporous hydroxide thin films through self-assembly of size-tailored nanobuilding blocks: a theoretical-experimental approach; American Chemical Society; Chemistry Of Materials; 31; 2; 1-2019; 322-330
0897-4756
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.8b03082
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.8b03082
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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