Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
- Autores
- Aparicio, Francisca; Escalada, Juan Pablo; De Gerónimo, Eduardo; Aparicio, Virginia C.; García Einschlag, Fernando Sebastián; Magnacca, Giuliana; Carlos, Luciano; Mártire, Daniel Osvaldo
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Química
Magnetite nanoparticles
Humic acids
carbamazepine
Photo-Fenton
Contaminants of emerging concern - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/107855
Ver los metadatos del registro completo
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Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite NanoparticlesAparicio, FranciscaEscalada, Juan PabloDe Gerónimo, EduardoAparicio, Virginia C.García Einschlag, Fernando SebastiánMagnacca, GiulianaCarlos, LucianoMártire, Daniel OsvaldoCiencias ExactasQuímicaMagnetite nanoparticlesHumic acidscarbamazepinePhoto-FentonContaminants of emerging concernThe use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe<sup>2+</sup> and Fe<sup>3+</sup> profiles point to the generation of Fe<sup>3+</sup> at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/107855enginfo:eu-repo/semantics/altIdentifier/url/http://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC6836229&blobtype=pdfinfo:eu-repo/semantics/altIdentifier/issn/2079-4991info:eu-repo/semantics/altIdentifier/pmid/31561528info:eu-repo/semantics/altIdentifier/doi/10.3390/nano9101379info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:23:52Zoai:sedici.unlp.edu.ar:10915/107855Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:23:52.826SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
spellingShingle |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles Aparicio, Francisca Ciencias Exactas Química Magnetite nanoparticles Humic acids carbamazepine Photo-Fenton Contaminants of emerging concern |
title_short |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_full |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_fullStr |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_full_unstemmed |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_sort |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
dc.creator.none.fl_str_mv |
Aparicio, Francisca Escalada, Juan Pablo De Gerónimo, Eduardo Aparicio, Virginia C. García Einschlag, Fernando Sebastián Magnacca, Giuliana Carlos, Luciano Mártire, Daniel Osvaldo |
author |
Aparicio, Francisca |
author_facet |
Aparicio, Francisca Escalada, Juan Pablo De Gerónimo, Eduardo Aparicio, Virginia C. García Einschlag, Fernando Sebastián Magnacca, Giuliana Carlos, Luciano Mártire, Daniel Osvaldo |
author_role |
author |
author2 |
Escalada, Juan Pablo De Gerónimo, Eduardo Aparicio, Virginia C. García Einschlag, Fernando Sebastián Magnacca, Giuliana Carlos, Luciano Mártire, Daniel Osvaldo |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Ciencias Exactas Química Magnetite nanoparticles Humic acids carbamazepine Photo-Fenton Contaminants of emerging concern |
topic |
Ciencias Exactas Química Magnetite nanoparticles Humic acids carbamazepine Photo-Fenton Contaminants of emerging concern |
dc.description.none.fl_txt_mv |
The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe<sup>2+</sup> and Fe<sup>3+</sup> profiles point to the generation of Fe<sup>3+</sup> at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
description |
The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe<sup>2+</sup> and Fe<sup>3+</sup> profiles point to the generation of Fe<sup>3+</sup> at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019 |
dc.type.none.fl_str_mv |
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article |
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publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/107855 |
url |
http://sedici.unlp.edu.ar/handle/10915/107855 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
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openAccess |
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