Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants

Autores
Gomis, J.; Bianco Prevot, A.; Montoneri, E.; Gonzalez, Monica Cristina; Amat, A. M.; Martire, Daniel Osvaldo; Arques, A.; Carlos, Luciano
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of soluble bio-based organic substances (SBO) isolated from urban wastes on photochemical wastewater treatments was investigated using a mixture of six emerging pollutants (EPs), namely acetaminophen, caffeine, acetamiprid, clofibric acid, carbamazepine and amoxicillin. Solar simulated experiments showed that although SBO were able to enhance the indirect photolysis of the EPs, they could not compensate for the light screening effect produced by these colored materials. In contrast, SBO were able to enhance photo-Fenton at slightly acidic conditions (pH = 5.2), most probably increasing iron availability. In the later case, the order of reactivity (amoxicillinPcarbamazepine Pclofibric acid > caffeine > acetaminophen > acetamiprid) was similar to that of the rate constants determined for all six EPs with OH. Finally, experiments performed at pilot plant scale with real sunlight at pH = 5.2 and SBO showed that 5 of the EPs were removed in only 25 min and only acetamiprid was more resistant to the process. The overall results show not only how we can use waste to clean out wastes, but also contribute to the studies which show how wastes can become a source of revenue through the industrial exploitation of their chemical value.
Fil: Gomis, J.. Universidad Politecnica de Valencia; España
Fil: Bianco Prevot, A.. Universitã  Di Torino; Italia
Fil: Montoneri, E.. Universitã  Di Torino; Italia
Fil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Amat, A. M.. Universidad Politecnica de Valencia; España
Fil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Arques, A.. Universidad Politecnica de Valencia; España
Fil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Materia
Wastewater
Sunlight Photolysis
Emerging Pollutants
Photo-Fenton
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5163
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5163
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutantsGomis, J.Bianco Prevot, A.Montoneri, E.Gonzalez, Monica CristinaAmat, A. M.Martire, Daniel OsvaldoArques, A.Carlos, LucianoWastewaterSunlight PhotolysisEmerging PollutantsPhoto-Fentonhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of soluble bio-based organic substances (SBO) isolated from urban wastes on photochemical wastewater treatments was investigated using a mixture of six emerging pollutants (EPs), namely acetaminophen, caffeine, acetamiprid, clofibric acid, carbamazepine and amoxicillin. Solar simulated experiments showed that although SBO were able to enhance the indirect photolysis of the EPs, they could not compensate for the light screening effect produced by these colored materials. In contrast, SBO were able to enhance photo-Fenton at slightly acidic conditions (pH = 5.2), most probably increasing iron availability. In the later case, the order of reactivity (amoxicillinPcarbamazepine Pclofibric acid > caffeine > acetaminophen > acetamiprid) was similar to that of the rate constants determined for all six EPs with OH. Finally, experiments performed at pilot plant scale with real sunlight at pH = 5.2 and SBO showed that 5 of the EPs were removed in only 25 min and only acetamiprid was more resistant to the process. The overall results show not only how we can use waste to clean out wastes, but also contribute to the studies which show how wastes can become a source of revenue through the industrial exploitation of their chemical value.Fil: Gomis, J.. Universidad Politecnica de Valencia; EspañaFil: Bianco Prevot, A.. Universitã  Di Torino; ItaliaFil: Montoneri, E.. Universitã  Di Torino; ItaliaFil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Amat, A. M.. Universidad Politecnica de Valencia; EspañaFil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Arques, A.. Universidad Politecnica de Valencia; EspañaFil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaElsevier2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfhttp://hdl.handle.net/11336/5163Gomis, J.; Bianco Prevot, A.; Montoneri, E.; Gonzalez, Monica Cristina; Amat, A. M.; et al.; Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants; Elsevier; Chemical Engineering Journal; 235; 1-2014; 236-2431385-8947enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894713011807info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2013.09.009info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:42:45Zoai:ri.conicet.gov.ar:11336/5163instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:42:45.95CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
title Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
spellingShingle Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
Gomis, J.
Wastewater
Sunlight Photolysis
Emerging Pollutants
Photo-Fenton
title_short Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
title_full Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
title_fullStr Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
title_full_unstemmed Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
title_sort Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants
dc.creator.none.fl_str_mv Gomis, J.
Bianco Prevot, A.
Montoneri, E.
Gonzalez, Monica Cristina
Amat, A. M.
Martire, Daniel Osvaldo
Arques, A.
Carlos, Luciano
author Gomis, J.
author_facet Gomis, J.
Bianco Prevot, A.
Montoneri, E.
Gonzalez, Monica Cristina
Amat, A. M.
Martire, Daniel Osvaldo
Arques, A.
Carlos, Luciano
author_role author
author2 Bianco Prevot, A.
Montoneri, E.
Gonzalez, Monica Cristina
Amat, A. M.
Martire, Daniel Osvaldo
Arques, A.
Carlos, Luciano
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Wastewater
Sunlight Photolysis
Emerging Pollutants
Photo-Fenton
topic Wastewater
Sunlight Photolysis
Emerging Pollutants
Photo-Fenton
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The effect of soluble bio-based organic substances (SBO) isolated from urban wastes on photochemical wastewater treatments was investigated using a mixture of six emerging pollutants (EPs), namely acetaminophen, caffeine, acetamiprid, clofibric acid, carbamazepine and amoxicillin. Solar simulated experiments showed that although SBO were able to enhance the indirect photolysis of the EPs, they could not compensate for the light screening effect produced by these colored materials. In contrast, SBO were able to enhance photo-Fenton at slightly acidic conditions (pH = 5.2), most probably increasing iron availability. In the later case, the order of reactivity (amoxicillinPcarbamazepine Pclofibric acid > caffeine > acetaminophen > acetamiprid) was similar to that of the rate constants determined for all six EPs with OH. Finally, experiments performed at pilot plant scale with real sunlight at pH = 5.2 and SBO showed that 5 of the EPs were removed in only 25 min and only acetamiprid was more resistant to the process. The overall results show not only how we can use waste to clean out wastes, but also contribute to the studies which show how wastes can become a source of revenue through the industrial exploitation of their chemical value.
Fil: Gomis, J.. Universidad Politecnica de Valencia; España
Fil: Bianco Prevot, A.. Universitã  Di Torino; Italia
Fil: Montoneri, E.. Universitã  Di Torino; Italia
Fil: Gonzalez, Monica Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Amat, A. M.. Universidad Politecnica de Valencia; España
Fil: Martire, Daniel Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
Fil: Arques, A.. Universidad Politecnica de Valencia; España
Fil: Carlos, Luciano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; Argentina
description The effect of soluble bio-based organic substances (SBO) isolated from urban wastes on photochemical wastewater treatments was investigated using a mixture of six emerging pollutants (EPs), namely acetaminophen, caffeine, acetamiprid, clofibric acid, carbamazepine and amoxicillin. Solar simulated experiments showed that although SBO were able to enhance the indirect photolysis of the EPs, they could not compensate for the light screening effect produced by these colored materials. In contrast, SBO were able to enhance photo-Fenton at slightly acidic conditions (pH = 5.2), most probably increasing iron availability. In the later case, the order of reactivity (amoxicillinPcarbamazepine Pclofibric acid > caffeine > acetaminophen > acetamiprid) was similar to that of the rate constants determined for all six EPs with OH. Finally, experiments performed at pilot plant scale with real sunlight at pH = 5.2 and SBO showed that 5 of the EPs were removed in only 25 min and only acetamiprid was more resistant to the process. The overall results show not only how we can use waste to clean out wastes, but also contribute to the studies which show how wastes can become a source of revenue through the industrial exploitation of their chemical value.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5163
Gomis, J.; Bianco Prevot, A.; Montoneri, E.; Gonzalez, Monica Cristina; Amat, A. M.; et al.; Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants; Elsevier; Chemical Engineering Journal; 235; 1-2014; 236-243
1385-8947
url http://hdl.handle.net/11336/5163
identifier_str_mv Gomis, J.; Bianco Prevot, A.; Montoneri, E.; Gonzalez, Monica Cristina; Amat, A. M.; et al.; Waste sourced bio-based substances for solar-driven wastewater remediation: Photodegradation of emerging pollutants; Elsevier; Chemical Engineering Journal; 235; 1-2014; 236-243
1385-8947
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894713011807
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2013.09.009
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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