Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
- Autores
- Aparicio, Francisca; Escalada, Juan Pablo; De Geronimo, Eduardo; Aparicio, Virginia Carolina; Gracía Einschlag, Fernando; Magnacca, Giuliana; Carlos, Luciano; Mártire, Daniel
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.
EEA Balcarce
Fil: Aparicio, Francisca .Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina
Fil: Escalada, Juan Pablo. Universidad Nacional de la Patagonia Austral. Unidad Académica Río Gallegos; Argentina.
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: García Einschlag, Fernando. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina
Fil: Magnacca, Giuliana. Università di Torino. Dipartimento di Chimica and NIS Inter-departmental Centre; Italia
Fil: Carlos, Luciano. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina.
Fil: Mártire, Daniel. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina. - Fuente
- Nanomaterials 9 (10) : 1379 (2019)
- Materia
-
Nanopartículas
Hierro
Acido Húmico
Polución del Agua
Degradación Ambiental
Nanoparticles
Iron
Humic Acids
Water Pollution
Environmental Degradation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Instituto Nacional de Tecnología Agropecuaria
- OAI Identificador
- oai:localhost:20.500.12123/6185
Ver los metadatos del registro completo
id |
INTADig_7db8f10f8952eb997349ef83a8d29c44 |
---|---|
oai_identifier_str |
oai:localhost:20.500.12123/6185 |
network_acronym_str |
INTADig |
repository_id_str |
l |
network_name_str |
INTA Digital (INTA) |
spelling |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite NanoparticlesAparicio, FranciscaEscalada, Juan PabloDe Geronimo, EduardoAparicio, Virginia CarolinaGracía Einschlag, FernandoMagnacca, GiulianaCarlos, LucianoMártire, DanielNanopartículasHierroAcido HúmicoPolución del AguaDegradación AmbientalNanoparticlesIronHumic AcidsWater PollutionEnvironmental DegradationThe use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.EEA BalcarceFil: Aparicio, Francisca .Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; ArgentinaFil: Escalada, Juan Pablo. Universidad Nacional de la Patagonia Austral. Unidad Académica Río Gallegos; Argentina.Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: García Einschlag, Fernando. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; ArgentinaFil: Magnacca, Giuliana. Università di Torino. Dipartimento di Chimica and NIS Inter-departmental Centre; ItaliaFil: Carlos, Luciano. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina.Fil: Mártire, Daniel. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina.Multidisciplinary Digital Publishing Institute (MDPI)2019-10-23T16:48:33Z2019-10-23T16:48:33Z2019-09-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://www.mdpi.com/2079-4991/9/10/1379http://hdl.handle.net/20.500.12123/61852079-4991https://doi.org/10.3390/nano9101379Nanomaterials 9 (10) : 1379 (2019)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)2025-09-29T13:44:48Zoai:localhost:20.500.12123/6185instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:44:48.561INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse |
dc.title.none.fl_str_mv |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
spellingShingle |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles Aparicio, Francisca Nanopartículas Hierro Acido Húmico Polución del Agua Degradación Ambiental Nanoparticles Iron Humic Acids Water Pollution Environmental Degradation |
title_short |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_full |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_fullStr |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_full_unstemmed |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
title_sort |
Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles |
dc.creator.none.fl_str_mv |
Aparicio, Francisca Escalada, Juan Pablo De Geronimo, Eduardo Aparicio, Virginia Carolina Gracía Einschlag, Fernando Magnacca, Giuliana Carlos, Luciano Mártire, Daniel |
author |
Aparicio, Francisca |
author_facet |
Aparicio, Francisca Escalada, Juan Pablo De Geronimo, Eduardo Aparicio, Virginia Carolina Gracía Einschlag, Fernando Magnacca, Giuliana Carlos, Luciano Mártire, Daniel |
author_role |
author |
author2 |
Escalada, Juan Pablo De Geronimo, Eduardo Aparicio, Virginia Carolina Gracía Einschlag, Fernando Magnacca, Giuliana Carlos, Luciano Mártire, Daniel |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Nanopartículas Hierro Acido Húmico Polución del Agua Degradación Ambiental Nanoparticles Iron Humic Acids Water Pollution Environmental Degradation |
topic |
Nanopartículas Hierro Acido Húmico Polución del Agua Degradación Ambiental Nanoparticles Iron Humic Acids Water Pollution Environmental Degradation |
dc.description.none.fl_txt_mv |
The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater. EEA Balcarce Fil: Aparicio, Francisca .Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina Fil: Escalada, Juan Pablo. Universidad Nacional de la Patagonia Austral. Unidad Académica Río Gallegos; Argentina. Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina. Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina. Fil: García Einschlag, Fernando. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina Fil: Magnacca, Giuliana. Università di Torino. Dipartimento di Chimica and NIS Inter-departmental Centre; Italia Fil: Carlos, Luciano. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina. Fil: Mártire, Daniel. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina. |
description |
The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-10-23T16:48:33Z 2019-10-23T16:48:33Z 2019-09-26 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
https://www.mdpi.com/2079-4991/9/10/1379 http://hdl.handle.net/20.500.12123/6185 2079-4991 https://doi.org/10.3390/nano9101379 |
url |
https://www.mdpi.com/2079-4991/9/10/1379 http://hdl.handle.net/20.500.12123/6185 https://doi.org/10.3390/nano9101379 |
identifier_str_mv |
2079-4991 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute (MDPI) |
publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute (MDPI) |
dc.source.none.fl_str_mv |
Nanomaterials 9 (10) : 1379 (2019) reponame:INTA Digital (INTA) instname:Instituto Nacional de Tecnología Agropecuaria |
reponame_str |
INTA Digital (INTA) |
collection |
INTA Digital (INTA) |
instname_str |
Instituto Nacional de Tecnología Agropecuaria |
repository.name.fl_str_mv |
INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria |
repository.mail.fl_str_mv |
tripaldi.nicolas@inta.gob.ar |
_version_ |
1844619139072655360 |
score |
12.559606 |