Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles

Autores
Aparicio, Francisca; Escalada, Juan Pablo; De Geronimo, Eduardo; Aparicio, Virginia Carolina; Gracía Einschlag, Fernando; Magnacca, Giuliana; Carlos, Luciano; Mártire, Daniel
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.
EEA Balcarce
Fil: Aparicio, Francisca .Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina
Fil: Escalada, Juan Pablo. Universidad Nacional de la Patagonia Austral. Unidad Académica Río Gallegos; Argentina.
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: García Einschlag, Fernando. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina
Fil: Magnacca, Giuliana. Università di Torino. Dipartimento di Chimica and NIS Inter-departmental Centre; Italia
Fil: Carlos, Luciano. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina.
Fil: Mártire, Daniel. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina.
Fuente
Nanomaterials 9 (10) : 1379 (2019)
Materia
Nanopartículas
Hierro
Acido Húmico
Polución del Agua
Degradación Ambiental
Nanoparticles
Iron
Humic Acids
Water Pollution
Environmental Degradation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/6185
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oai_identifier_str oai:localhost:20.500.12123/6185
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spelling Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite NanoparticlesAparicio, FranciscaEscalada, Juan PabloDe Geronimo, EduardoAparicio, Virginia CarolinaGracía Einschlag, FernandoMagnacca, GiulianaCarlos, LucianoMártire, DanielNanopartículasHierroAcido HúmicoPolución del AguaDegradación AmbientalNanoparticlesIronHumic AcidsWater PollutionEnvironmental DegradationThe use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.EEA BalcarceFil: Aparicio, Francisca .Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; ArgentinaFil: Escalada, Juan Pablo. Universidad Nacional de la Patagonia Austral. Unidad Académica Río Gallegos; Argentina.Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.Fil: García Einschlag, Fernando. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; ArgentinaFil: Magnacca, Giuliana. Università di Torino. Dipartimento di Chimica and NIS Inter-departmental Centre; ItaliaFil: Carlos, Luciano. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina.Fil: Mártire, Daniel. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina.Multidisciplinary Digital Publishing Institute (MDPI)2019-10-23T16:48:33Z2019-10-23T16:48:33Z2019-09-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://www.mdpi.com/2079-4991/9/10/1379http://hdl.handle.net/20.500.12123/61852079-4991https://doi.org/10.3390/nano9101379Nanomaterials 9 (10) : 1379 (2019)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)2025-10-23T11:17:06Zoai:localhost:20.500.12123/6185instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-10-23 11:17:06.88INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
title Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
spellingShingle Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
Aparicio, Francisca
Nanopartículas
Hierro
Acido Húmico
Polución del Agua
Degradación Ambiental
Nanoparticles
Iron
Humic Acids
Water Pollution
Environmental Degradation
title_short Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
title_full Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
title_fullStr Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
title_full_unstemmed Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
title_sort Carbamazepine Degradation Mediated by Light in the Presence of Humic Substances-Coated Magnetite Nanoparticles
dc.creator.none.fl_str_mv Aparicio, Francisca
Escalada, Juan Pablo
De Geronimo, Eduardo
Aparicio, Virginia Carolina
Gracía Einschlag, Fernando
Magnacca, Giuliana
Carlos, Luciano
Mártire, Daniel
author Aparicio, Francisca
author_facet Aparicio, Francisca
Escalada, Juan Pablo
De Geronimo, Eduardo
Aparicio, Virginia Carolina
Gracía Einschlag, Fernando
Magnacca, Giuliana
Carlos, Luciano
Mártire, Daniel
author_role author
author2 Escalada, Juan Pablo
De Geronimo, Eduardo
Aparicio, Virginia Carolina
Gracía Einschlag, Fernando
Magnacca, Giuliana
Carlos, Luciano
Mártire, Daniel
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Nanopartículas
Hierro
Acido Húmico
Polución del Agua
Degradación Ambiental
Nanoparticles
Iron
Humic Acids
Water Pollution
Environmental Degradation
topic Nanopartículas
Hierro
Acido Húmico
Polución del Agua
Degradación Ambiental
Nanoparticles
Iron
Humic Acids
Water Pollution
Environmental Degradation
dc.description.none.fl_txt_mv The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.
EEA Balcarce
Fil: Aparicio, Francisca .Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina
Fil: Escalada, Juan Pablo. Universidad Nacional de la Patagonia Austral. Unidad Académica Río Gallegos; Argentina.
Fil: De Gerónimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina.
Fil: García Einschlag, Fernando. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina
Fil: Magnacca, Giuliana. Università di Torino. Dipartimento di Chimica and NIS Inter-departmental Centre; Italia
Fil: Carlos, Luciano. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina.
Fil: Mártire, Daniel. Universidad Nacional de La Plata. Facultad de Ciencias Exactas, Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires; Argentina.
description The use of iron-based nanomaterials for environmental remediation processes has recently received considerable attention. Here, we employed core-shell magnetite-humic acids nanoparticles as a heterogeneous photosensitizer and iron source in photo-Fenton reaction for the degradation of the psychiatric drug carbamazepine (CBZ). CBZ showed low photodegradation rates in the presence of the magnetic nanoparticles, whereas the addition of hydrogen peroxide at pH = 3 to the system drastically increased the abatement of the contaminant. The measured Fe2+ and Fe3+ profiles point to the generation of Fe3+ at the surface of the nanoparticles, indicating a heterogeneous oxidation of the contaminant mediated by hydroxyl radicals. Products with a higher transformation degree were observed in the photo-Fenton procedure and support the attack of the HO• radical on the CBZ molecule. Promising results encourage the use of the nanoparticles as efficient iron sources with enhanced magnet-sensitive properties, suitable for applications in photo-Fenton treatments for the purification of wastewater.
publishDate 2019
dc.date.none.fl_str_mv 2019-10-23T16:48:33Z
2019-10-23T16:48:33Z
2019-09-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://www.mdpi.com/2079-4991/9/10/1379
http://hdl.handle.net/20.500.12123/6185
2079-4991
https://doi.org/10.3390/nano9101379
url https://www.mdpi.com/2079-4991/9/10/1379
http://hdl.handle.net/20.500.12123/6185
https://doi.org/10.3390/nano9101379
identifier_str_mv 2079-4991
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
dc.source.none.fl_str_mv Nanomaterials 9 (10) : 1379 (2019)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.982451

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