Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering

Autores
Martínez, Juan Manuel; Hernández, María Florencia; Booth, Raúl Fernando Nicolás; López, Paula Virginia; Suárez, Gustavo; Conconi, María Susana; Rendtorff Birrer, Nicolás Maximiliano
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Novel 1:1 Yttria partially stabilized zirconia (PSZ) - aluminum borate (AB: Al₁₁B₄O₃₃) ceramic composites were prepared and characterized by a simple direct sintering process of PSZ-AB mixtures. Sintering was performed below 1300 °C to minimize the decomposition of borate. Phases were corroborated by XRD. SEM permitted to characterize the microstructure as interlocking needles of AB - rounded by PSZ grains. Porous microstructure configuration was achieved by the proposed processing route. Porosity was within 30 % for samples thermally treated at 1200 and 1300 °C. Mechanical behavior was evaluated by diametral compression. A fragile behavior was observed. Both strength and apparent Young modulus were evaluated being ≈30 MPa and ≈3 GPa respectively; values four times higher than the corresponding alumina-AB composite. This is more important when firing at higher temperature. The density of the obtained composites coupled with the mechanical behavior are the main characteristics of this novel composite with potential structural, insulating and filtering applications.
Centro de Tecnología de Recursos Minerales y Cerámica
Materia
Química
Composites
Stabilized zirconia
Aluminum borate
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/128465

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network_name_str SEDICI (UNLP)
spelling Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct SinteringMartínez, Juan ManuelHernández, María FlorenciaBooth, Raúl Fernando NicolásLópez, Paula VirginiaSuárez, GustavoConconi, María SusanaRendtorff Birrer, Nicolás MaximilianoQuímicaCompositesStabilized zirconiaAluminum borateNovel 1:1 Yttria partially stabilized zirconia (PSZ) - aluminum borate (AB: Al₁₁B₄O₃₃) ceramic composites were prepared and characterized by a simple direct sintering process of PSZ-AB mixtures. Sintering was performed below 1300 °C to minimize the decomposition of borate. Phases were corroborated by XRD. SEM permitted to characterize the microstructure as interlocking needles of AB - rounded by PSZ grains. Porous microstructure configuration was achieved by the proposed processing route. Porosity was within 30 % for samples thermally treated at 1200 and 1300 °C. Mechanical behavior was evaluated by diametral compression. A fragile behavior was observed. Both strength and apparent Young modulus were evaluated being ≈30 MPa and ≈3 GPa respectively; values four times higher than the corresponding alumina-AB composite. This is more important when firing at higher temperature. The density of the obtained composites coupled with the mechanical behavior are the main characteristics of this novel composite with potential structural, insulating and filtering applications.Centro de Tecnología de Recursos Minerales y Cerámica2021info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf9-18http://sedici.unlp.edu.ar/handle/10915/128465enginfo:eu-repo/semantics/altIdentifier/issn/0350-820Xinfo:eu-repo/semantics/altIdentifier/issn/1820-7413info:eu-repo/semantics/altIdentifier/doi/10.2298/sos2101009minfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T11:03:09Zoai:sedici.unlp.edu.ar:10915/128465Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 11:03:09.537SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
title Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
spellingShingle Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
Martínez, Juan Manuel
Química
Composites
Stabilized zirconia
Aluminum borate
title_short Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
title_full Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
title_fullStr Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
title_full_unstemmed Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
title_sort Partially Stabilized Zirconia (3Y-ZrO₂) Aluminum Borate (Al₁₈B₄O₃₃) Needles Composite Materials by Direct Sintering
dc.creator.none.fl_str_mv Martínez, Juan Manuel
Hernández, María Florencia
Booth, Raúl Fernando Nicolás
López, Paula Virginia
Suárez, Gustavo
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author Martínez, Juan Manuel
author_facet Martínez, Juan Manuel
Hernández, María Florencia
Booth, Raúl Fernando Nicolás
López, Paula Virginia
Suárez, Gustavo
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author_role author
author2 Hernández, María Florencia
Booth, Raúl Fernando Nicolás
López, Paula Virginia
Suárez, Gustavo
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Química
Composites
Stabilized zirconia
Aluminum borate
topic Química
Composites
Stabilized zirconia
Aluminum borate
dc.description.none.fl_txt_mv Novel 1:1 Yttria partially stabilized zirconia (PSZ) - aluminum borate (AB: Al₁₁B₄O₃₃) ceramic composites were prepared and characterized by a simple direct sintering process of PSZ-AB mixtures. Sintering was performed below 1300 °C to minimize the decomposition of borate. Phases were corroborated by XRD. SEM permitted to characterize the microstructure as interlocking needles of AB - rounded by PSZ grains. Porous microstructure configuration was achieved by the proposed processing route. Porosity was within 30 % for samples thermally treated at 1200 and 1300 °C. Mechanical behavior was evaluated by diametral compression. A fragile behavior was observed. Both strength and apparent Young modulus were evaluated being ≈30 MPa and ≈3 GPa respectively; values four times higher than the corresponding alumina-AB composite. This is more important when firing at higher temperature. The density of the obtained composites coupled with the mechanical behavior are the main characteristics of this novel composite with potential structural, insulating and filtering applications.
Centro de Tecnología de Recursos Minerales y Cerámica
description Novel 1:1 Yttria partially stabilized zirconia (PSZ) - aluminum borate (AB: Al₁₁B₄O₃₃) ceramic composites were prepared and characterized by a simple direct sintering process of PSZ-AB mixtures. Sintering was performed below 1300 °C to minimize the decomposition of borate. Phases were corroborated by XRD. SEM permitted to characterize the microstructure as interlocking needles of AB - rounded by PSZ grains. Porous microstructure configuration was achieved by the proposed processing route. Porosity was within 30 % for samples thermally treated at 1200 and 1300 °C. Mechanical behavior was evaluated by diametral compression. A fragile behavior was observed. Both strength and apparent Young modulus were evaluated being ≈30 MPa and ≈3 GPa respectively; values four times higher than the corresponding alumina-AB composite. This is more important when firing at higher temperature. The density of the obtained composites coupled with the mechanical behavior are the main characteristics of this novel composite with potential structural, insulating and filtering applications.
publishDate 2021
dc.date.none.fl_str_mv 2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/128465
url http://sedici.unlp.edu.ar/handle/10915/128465
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0350-820X
info:eu-repo/semantics/altIdentifier/issn/1820-7413
info:eu-repo/semantics/altIdentifier/doi/10.2298/sos2101009m
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
9-18
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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