Spectroscopic investigations of iron(II) and iron(III) oxalates

Autores
D'Antonio, Maria C.; Wladimirsky, Alejandra; Palacios, Daniel; Coggiola, Liliana; González Baró, Ana Cecilia; Baran, Enrique José; Mercader, Roberto Carlos
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In an attempt to contribute to a better characterization of FeII and FeIII oxalate complexes, an investigation of their vibrational (infrared and Raman) and 57Fe-Mössbauer spectra was performed. It is shown that the two polymorphs, α and β, of FeC2O4.2H2O cannot be accurately differentiated with any of these spectroscopic methods, demonstrating the high structural similarity of these two crystalline forms. Partially deuterated samples of β-FeC2O4·2H2O were also investigated to improve the vibrational-spectroscopic analysis. In the case of Fe2(C2O4)3·4H2O, a structural model, derived from results of combined vibrational and Mössbauer data, could be proposed. The 298 K Mössbauer spectrum for this complex is discussed in detail for the first time.
Facultad de Ciencias Exactas
Centro de Química Inorgánica
Materia
Química
IR spectroscopy
Iron oxalates
Mössbauer
Raman spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/82742
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/82742
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Spectroscopic investigations of iron(II) and iron(III) oxalatesD'Antonio, Maria C.Wladimirsky, AlejandraPalacios, DanielCoggiola, LilianaGonzález Baró, Ana CeciliaBaran, Enrique JoséMercader, Roberto CarlosQuímicaIR spectroscopyIron oxalatesMössbauerRaman spectroscopyIn an attempt to contribute to a better characterization of FeII and FeIII oxalate complexes, an investigation of their vibrational (infrared and Raman) and 57Fe-Mössbauer spectra was performed. It is shown that the two polymorphs, α and β, of FeC2O4.2H2O cannot be accurately differentiated with any of these spectroscopic methods, demonstrating the high structural similarity of these two crystalline forms. Partially deuterated samples of β-FeC2O4·2H2O were also investigated to improve the vibrational-spectroscopic analysis. In the case of Fe2(C2O4)3·4H2O, a structural model, derived from results of combined vibrational and Mössbauer data, could be proposed. The 298 K Mössbauer spectrum for this complex is discussed in detail for the first time.Facultad de Ciencias ExactasCentro de Química Inorgánica2009info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf445-450http://sedici.unlp.edu.ar/handle/10915/82742enginfo:eu-repo/semantics/altIdentifier/issn/0103-5053info:eu-repo/semantics/altIdentifier/doi/10.1590/S0103-50532009000300006info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:15:36Zoai:sedici.unlp.edu.ar:10915/82742Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:15:36.466SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Spectroscopic investigations of iron(II) and iron(III) oxalates
title Spectroscopic investigations of iron(II) and iron(III) oxalates
spellingShingle Spectroscopic investigations of iron(II) and iron(III) oxalates
D'Antonio, Maria C.
Química
IR spectroscopy
Iron oxalates
Mössbauer
Raman spectroscopy
title_short Spectroscopic investigations of iron(II) and iron(III) oxalates
title_full Spectroscopic investigations of iron(II) and iron(III) oxalates
title_fullStr Spectroscopic investigations of iron(II) and iron(III) oxalates
title_full_unstemmed Spectroscopic investigations of iron(II) and iron(III) oxalates
title_sort Spectroscopic investigations of iron(II) and iron(III) oxalates
dc.creator.none.fl_str_mv D'Antonio, Maria C.
Wladimirsky, Alejandra
Palacios, Daniel
Coggiola, Liliana
González Baró, Ana Cecilia
Baran, Enrique José
Mercader, Roberto Carlos
author D'Antonio, Maria C.
author_facet D'Antonio, Maria C.
Wladimirsky, Alejandra
Palacios, Daniel
Coggiola, Liliana
González Baró, Ana Cecilia
Baran, Enrique José
Mercader, Roberto Carlos
author_role author
author2 Wladimirsky, Alejandra
Palacios, Daniel
Coggiola, Liliana
González Baró, Ana Cecilia
Baran, Enrique José
Mercader, Roberto Carlos
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Química
IR spectroscopy
Iron oxalates
Mössbauer
Raman spectroscopy
topic Química
IR spectroscopy
Iron oxalates
Mössbauer
Raman spectroscopy
dc.description.none.fl_txt_mv In an attempt to contribute to a better characterization of FeII and FeIII oxalate complexes, an investigation of their vibrational (infrared and Raman) and 57Fe-Mössbauer spectra was performed. It is shown that the two polymorphs, α and β, of FeC2O4.2H2O cannot be accurately differentiated with any of these spectroscopic methods, demonstrating the high structural similarity of these two crystalline forms. Partially deuterated samples of β-FeC2O4·2H2O were also investigated to improve the vibrational-spectroscopic analysis. In the case of Fe2(C2O4)3·4H2O, a structural model, derived from results of combined vibrational and Mössbauer data, could be proposed. The 298 K Mössbauer spectrum for this complex is discussed in detail for the first time.
Facultad de Ciencias Exactas
Centro de Química Inorgánica
description In an attempt to contribute to a better characterization of FeII and FeIII oxalate complexes, an investigation of their vibrational (infrared and Raman) and 57Fe-Mössbauer spectra was performed. It is shown that the two polymorphs, α and β, of FeC2O4.2H2O cannot be accurately differentiated with any of these spectroscopic methods, demonstrating the high structural similarity of these two crystalline forms. Partially deuterated samples of β-FeC2O4·2H2O were also investigated to improve the vibrational-spectroscopic analysis. In the case of Fe2(C2O4)3·4H2O, a structural model, derived from results of combined vibrational and Mössbauer data, could be proposed. The 298 K Mössbauer spectrum for this complex is discussed in detail for the first time.
publishDate 2009
dc.date.none.fl_str_mv 2009
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/82742
url http://sedici.unlp.edu.ar/handle/10915/82742
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0103-5053
info:eu-repo/semantics/altIdentifier/doi/10.1590/S0103-50532009000300006
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
445-450
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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