Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability

Autores
Qi, Wenbin; Li, Jingwei; Chain, Cecilia Yamil; Pasquevich, Gustavo Alberto; Pasquevich, Gustavo Alberto; Cowan, James
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Assembly and stabilization of a glutathione-complexed [2Fe–2S] cluster is promoted by aggregation of glutathione. The cluster core selects the tetramer species from a collection of equilibrating solution aggregate species, and in turn the core is stabilized toward hydrolytic degradation. Studies of glutathione derivatives, in combination with mass spectrometric and Mo¨ssbauer investigations provide insight on reaction intermediates during formation of [2Fe–2S](GS)4
Fil: Qi, Wenbin. Ohio State University; Estados Unidos
Fil: Li, Jingwei. Ohio State University; Estados Unidos
Fil: Chain, Cecilia Yamil. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: Pasquevich, Gustavo Alberto. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: Pasquevich, Gustavo Alberto. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: Cowan, James. Ohio State University; Estados Unidos
Materia
Iron- Sulfur Clusters
Glutathione
Mass Spectroscopy
Mössbauer Spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/7627
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and StabilityQi, WenbinLi, JingweiChain, Cecilia YamilPasquevich, Gustavo AlbertoPasquevich, Gustavo AlbertoCowan, JamesIron- Sulfur ClustersGlutathioneMass SpectroscopyMössbauer Spectroscopyhttps://purl.org/becyt/ford/1.6https://purl.org/becyt/ford/1Assembly and stabilization of a glutathione-complexed [2Fe–2S] cluster is promoted by aggregation of glutathione. The cluster core selects the tetramer species from a collection of equilibrating solution aggregate species, and in turn the core is stabilized toward hydrolytic degradation. Studies of glutathione derivatives, in combination with mass spectrometric and Mo¨ssbauer investigations provide insight on reaction intermediates during formation of [2Fe–2S](GS)4Fil: Qi, Wenbin. Ohio State University; Estados UnidosFil: Li, Jingwei. Ohio State University; Estados UnidosFil: Chain, Cecilia Yamil. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; ArgentinaFil: Pasquevich, Gustavo Alberto. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; ArgentinaFil: Pasquevich, Gustavo Alberto. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; ArgentinaFil: Cowan, James. Ohio State University; Estados UnidosRoyal Society Of Chemistry2013-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/zipapplication/pdfhttp://hdl.handle.net/11336/7627Qi, Wenbin; Li, Jingwei; Chain, Cecilia Yamil; Pasquevich, Gustavo Alberto; Pasquevich, Gustavo Alberto; et al.; Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability; Royal Society Of Chemistry; Chemical Communications; 49; 56; 5-2013; 6313-63191359-7345enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc43620a#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C3CC43620Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:46:41Zoai:ri.conicet.gov.ar:11336/7627instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:46:41.75CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
title Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
spellingShingle Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
Qi, Wenbin
Iron- Sulfur Clusters
Glutathione
Mass Spectroscopy
Mössbauer Spectroscopy
title_short Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
title_full Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
title_fullStr Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
title_full_unstemmed Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
title_sort Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability
dc.creator.none.fl_str_mv Qi, Wenbin
Li, Jingwei
Chain, Cecilia Yamil
Pasquevich, Gustavo Alberto
Pasquevich, Gustavo Alberto
Cowan, James
author Qi, Wenbin
author_facet Qi, Wenbin
Li, Jingwei
Chain, Cecilia Yamil
Pasquevich, Gustavo Alberto
Cowan, James
author_role author
author2 Li, Jingwei
Chain, Cecilia Yamil
Pasquevich, Gustavo Alberto
Cowan, James
author2_role author
author
author
author
dc.subject.none.fl_str_mv Iron- Sulfur Clusters
Glutathione
Mass Spectroscopy
Mössbauer Spectroscopy
topic Iron- Sulfur Clusters
Glutathione
Mass Spectroscopy
Mössbauer Spectroscopy
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.6
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Assembly and stabilization of a glutathione-complexed [2Fe–2S] cluster is promoted by aggregation of glutathione. The cluster core selects the tetramer species from a collection of equilibrating solution aggregate species, and in turn the core is stabilized toward hydrolytic degradation. Studies of glutathione derivatives, in combination with mass spectrometric and Mo¨ssbauer investigations provide insight on reaction intermediates during formation of [2Fe–2S](GS)4
Fil: Qi, Wenbin. Ohio State University; Estados Unidos
Fil: Li, Jingwei. Ohio State University; Estados Unidos
Fil: Chain, Cecilia Yamil. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: Pasquevich, Gustavo Alberto. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: Pasquevich, Gustavo Alberto. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: Cowan, James. Ohio State University; Estados Unidos
description Assembly and stabilization of a glutathione-complexed [2Fe–2S] cluster is promoted by aggregation of glutathione. The cluster core selects the tetramer species from a collection of equilibrating solution aggregate species, and in turn the core is stabilized toward hydrolytic degradation. Studies of glutathione derivatives, in combination with mass spectrometric and Mo¨ssbauer investigations provide insight on reaction intermediates during formation of [2Fe–2S](GS)4
publishDate 2013
dc.date.none.fl_str_mv 2013-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/7627
Qi, Wenbin; Li, Jingwei; Chain, Cecilia Yamil; Pasquevich, Gustavo Alberto; Pasquevich, Gustavo Alberto; et al.; Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability; Royal Society Of Chemistry; Chemical Communications; 49; 56; 5-2013; 6313-6319
1359-7345
url http://hdl.handle.net/11336/7627
identifier_str_mv Qi, Wenbin; Li, Jingwei; Chain, Cecilia Yamil; Pasquevich, Gustavo Alberto; Pasquevich, Gustavo Alberto; et al.; Glutathione Complexed Iron- Sulfur Centres. Reaction Intermediates and Evidence for a Template Effect Promoting Assembly and Stability; Royal Society Of Chemistry; Chemical Communications; 49; 56; 5-2013; 6313-6319
1359-7345
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc43620a#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/C3CC43620A
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/zip
application/pdf
dc.publisher.none.fl_str_mv Royal Society Of Chemistry
publisher.none.fl_str_mv Royal Society Of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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