Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)

Autores
Parajón Costa, Beatriz Susana; Mercader, Roberto Carlos; Baran, Enrique José
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The mixed cation diphosphates of composition MI FeIIIP2O7 have been prepared using the so called co-precipitation method starting with Fe(III) and M(I) nitrate solutions and solid (NH4)H2PO4, and characterized by X-ray powder diffractometry. The infrared and Raman spectra of the compounds were recorded and the results are briefly discussed on the basis of their structural peculiarities. The 57FeMossbauer spectra show that the typical high-spin Fe ¨ IIIO6 octahedra existent in these compounds exhibit almost no distortion. However, the hyperfine parameters are sensitive to some characteristics of the MI cations and to the different structural types.
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Mercader, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
Inorganic Compounds
Chemical Synthesis
Infrared Spectroscopy
Mossbauer Spectroscopy
Raman Spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/24008
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)Parajón Costa, Beatriz SusanaMercader, Roberto CarlosBaran, Enrique JoséInorganic CompoundsChemical SynthesisInfrared SpectroscopyMossbauer SpectroscopyRaman Spectroscopyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The mixed cation diphosphates of composition MI FeIIIP2O7 have been prepared using the so called co-precipitation method starting with Fe(III) and M(I) nitrate solutions and solid (NH4)H2PO4, and characterized by X-ray powder diffractometry. The infrared and Raman spectra of the compounds were recorded and the results are briefly discussed on the basis of their structural peculiarities. The 57FeMossbauer spectra show that the typical high-spin Fe ¨ IIIO6 octahedra existent in these compounds exhibit almost no distortion. However, the hyperfine parameters are sensitive to some characteristics of the MI cations and to the different structural types.Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Mercader, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaPergamon-Elsevier Science Ltd2013-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24008Parajón Costa, Beatriz Susana; Mercader, Roberto Carlos; Baran, Enrique José; Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag); Pergamon-Elsevier Science Ltd; Journal of Physics and Chemistry of Solids; 74; 2; 2-2013; 354-3590022-3697CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpcs.2012.10.012info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022369712003290info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:15:33Zoai:ri.conicet.gov.ar:11336/24008instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:15:33.877CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
title Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
spellingShingle Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
Parajón Costa, Beatriz Susana
Inorganic Compounds
Chemical Synthesis
Infrared Spectroscopy
Mossbauer Spectroscopy
Raman Spectroscopy
title_short Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
title_full Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
title_fullStr Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
title_full_unstemmed Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
title_sort Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag)
dc.creator.none.fl_str_mv Parajón Costa, Beatriz Susana
Mercader, Roberto Carlos
Baran, Enrique José
author Parajón Costa, Beatriz Susana
author_facet Parajón Costa, Beatriz Susana
Mercader, Roberto Carlos
Baran, Enrique José
author_role author
author2 Mercader, Roberto Carlos
Baran, Enrique José
author2_role author
author
dc.subject.none.fl_str_mv Inorganic Compounds
Chemical Synthesis
Infrared Spectroscopy
Mossbauer Spectroscopy
Raman Spectroscopy
topic Inorganic Compounds
Chemical Synthesis
Infrared Spectroscopy
Mossbauer Spectroscopy
Raman Spectroscopy
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The mixed cation diphosphates of composition MI FeIIIP2O7 have been prepared using the so called co-precipitation method starting with Fe(III) and M(I) nitrate solutions and solid (NH4)H2PO4, and characterized by X-ray powder diffractometry. The infrared and Raman spectra of the compounds were recorded and the results are briefly discussed on the basis of their structural peculiarities. The 57FeMossbauer spectra show that the typical high-spin Fe ¨ IIIO6 octahedra existent in these compounds exhibit almost no distortion. However, the hyperfine parameters are sensitive to some characteristics of the MI cations and to the different structural types.
Fil: Parajón Costa, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Mercader, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description The mixed cation diphosphates of composition MI FeIIIP2O7 have been prepared using the so called co-precipitation method starting with Fe(III) and M(I) nitrate solutions and solid (NH4)H2PO4, and characterized by X-ray powder diffractometry. The infrared and Raman spectra of the compounds were recorded and the results are briefly discussed on the basis of their structural peculiarities. The 57FeMossbauer spectra show that the typical high-spin Fe ¨ IIIO6 octahedra existent in these compounds exhibit almost no distortion. However, the hyperfine parameters are sensitive to some characteristics of the MI cations and to the different structural types.
publishDate 2013
dc.date.none.fl_str_mv 2013-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/24008
Parajón Costa, Beatriz Susana; Mercader, Roberto Carlos; Baran, Enrique José; Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag); Pergamon-Elsevier Science Ltd; Journal of Physics and Chemistry of Solids; 74; 2; 2-2013; 354-359
0022-3697
CONICET Digital
CONICET
url http://hdl.handle.net/11336/24008
identifier_str_mv Parajón Costa, Beatriz Susana; Mercader, Roberto Carlos; Baran, Enrique José; Spectroscopic characterization of mixed cation diphosphates of the type MI FeIIIP2O7 (with MI¼Li, Na, K, Rb, Cs, Ag); Pergamon-Elsevier Science Ltd; Journal of Physics and Chemistry of Solids; 74; 2; 2-2013; 354-359
0022-3697
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpcs.2012.10.012
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022369712003290
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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