A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine

Autores
Piro, Oscar Enrique; Zinczuk, Juan; Baran, Enrique José
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented.
Publicado on line en 2014.
Centro de Química Inorgánica
Materia
Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/3.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/120123
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/120123
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and PyridinePiro, Oscar EnriqueZinczuk, JuanBaran, Enrique JoséQuímicaPyridiniumThiosaccharinate ThiosaccharinCrystal StructureSupramolecular AdductIR SpectraThe crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented.Publicado on line en 2014.Centro de Química Inorgánica2008info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf877-879http://sedici.unlp.edu.ar/handle/10915/120123enginfo:eu-repo/semantics/altIdentifier/issn/1865-7117info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2008-0712info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/3.0/Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:09:19Zoai:sedici.unlp.edu.ar:10915/120123Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:09:19.933SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
spellingShingle A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
Piro, Oscar Enrique
Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
title_short A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_full A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_fullStr A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_full_unstemmed A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_sort A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Zinczuk, Juan
Baran, Enrique José
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Zinczuk, Juan
Baran, Enrique José
author_role author
author2 Zinczuk, Juan
Baran, Enrique José
author2_role author
author
dc.subject.none.fl_str_mv Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
topic Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
dc.description.none.fl_txt_mv The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented.
Publicado on line en 2014.
Centro de Química Inorgánica
description The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented.
publishDate 2008
dc.date.none.fl_str_mv 2008
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/120123
url http://sedici.unlp.edu.ar/handle/10915/120123
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1865-7117
info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2008-0712
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/3.0/
Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/3.0/
Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)
dc.format.none.fl_str_mv application/pdf
877-879
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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