A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
- Autores
- Piro, Oscar Enrique; Zinczuk, Juan; Baran, Enrique José
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented.
Publicado on line en 2014.
Centro de Química Inorgánica - Materia
-
Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-nd/3.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/120123
Ver los metadatos del registro completo
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A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and PyridinePiro, Oscar EnriqueZinczuk, JuanBaran, Enrique JoséQuímicaPyridiniumThiosaccharinate ThiosaccharinCrystal StructureSupramolecular AdductIR SpectraThe crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented.Publicado on line en 2014.Centro de Química Inorgánica2008info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf877-879http://sedici.unlp.edu.ar/handle/10915/120123enginfo:eu-repo/semantics/altIdentifier/issn/1865-7117info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2008-0712info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/3.0/Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:28:24Zoai:sedici.unlp.edu.ar:10915/120123Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:28:24.814SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine |
title |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine |
spellingShingle |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine Piro, Oscar Enrique Química Pyridinium Thiosaccharinate Thiosaccharin Crystal Structure Supramolecular Adduct IR Spectra |
title_short |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine |
title_full |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine |
title_fullStr |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine |
title_full_unstemmed |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine |
title_sort |
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine |
dc.creator.none.fl_str_mv |
Piro, Oscar Enrique Zinczuk, Juan Baran, Enrique José |
author |
Piro, Oscar Enrique |
author_facet |
Piro, Oscar Enrique Zinczuk, Juan Baran, Enrique José |
author_role |
author |
author2 |
Zinczuk, Juan Baran, Enrique José |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Química Pyridinium Thiosaccharinate Thiosaccharin Crystal Structure Supramolecular Adduct IR Spectra |
topic |
Química Pyridinium Thiosaccharinate Thiosaccharin Crystal Structure Supramolecular Adduct IR Spectra |
dc.description.none.fl_txt_mv |
The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented. Publicado on line en 2014. Centro de Química Inorgánica |
description |
The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/120123 |
url |
http://sedici.unlp.edu.ar/handle/10915/120123 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1865-7117 info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2008-0712 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/3.0/ Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-nd/3.0/ Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) |
dc.format.none.fl_str_mv |
application/pdf 877-879 |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
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