Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
- Autores
- Benzo, Fabián; Sienra, Beatriz; Piro, Oscar Enrique
- Año de publicación
- 1998
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.
Facultad de Ciencias Exactas - Materia
-
Física
Química
Co(III) complex
crystal structure
kinetics
steric effects - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/147277
Ver los metadatos del registro completo
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Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂Benzo, FabiánSienra, BeatrizPiro, Oscar EnriqueFísicaQuímicaCo(III) complexcrystal structurekineticssteric effectsThe title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.Facultad de Ciencias Exactas1998-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf69-72http://sedici.unlp.edu.ar/handle/10915/147277enginfo:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1021786804676info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:13:16Zoai:sedici.unlp.edu.ar:10915/147277Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:13:16.301SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ |
| title |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ |
| spellingShingle |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ Benzo, Fabián Física Química Co(III) complex crystal structure kinetics steric effects |
| title_short |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ |
| title_full |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ |
| title_fullStr |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ |
| title_full_unstemmed |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ |
| title_sort |
Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ |
| dc.creator.none.fl_str_mv |
Benzo, Fabián Sienra, Beatriz Piro, Oscar Enrique |
| author |
Benzo, Fabián |
| author_facet |
Benzo, Fabián Sienra, Beatriz Piro, Oscar Enrique |
| author_role |
author |
| author2 |
Sienra, Beatriz Piro, Oscar Enrique |
| author2_role |
author author |
| dc.subject.none.fl_str_mv |
Física Química Co(III) complex crystal structure kinetics steric effects |
| topic |
Física Química Co(III) complex crystal structure kinetics steric effects |
| dc.description.none.fl_txt_mv |
The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results. Facultad de Ciencias Exactas |
| description |
The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results. |
| publishDate |
1998 |
| dc.date.none.fl_str_mv |
1998-01 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/147277 |
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http://sedici.unlp.edu.ar/handle/10915/147277 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1074-1542 info:eu-repo/semantics/altIdentifier/issn/1572-8854 info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1021786804676 |
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openAccess |
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http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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application/pdf 69-72 |
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