Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂

Autores
Benzo, Fabián; Sienra, Beatriz; Piro, Oscar Enrique
Año de publicación
1998
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.
Facultad de Ciencias Exactas
Materia
Física
Química
Co(III) complex
crystal structure
kinetics
steric effects
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/147277
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/147277
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂Benzo, FabiánSienra, BeatrizPiro, Oscar EnriqueFísicaQuímicaCo(III) complexcrystal structurekineticssteric effectsThe title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.Facultad de Ciencias Exactas1998-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf69-72http://sedici.unlp.edu.ar/handle/10915/147277enginfo:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1021786804676info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:21Zoai:sedici.unlp.edu.ar:10915/147277Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:21.977SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
title Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
spellingShingle Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
Benzo, Fabián
Física
Química
Co(III) complex
crystal structure
kinetics
steric effects
title_short Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
title_full Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
title_fullStr Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
title_full_unstemmed Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
title_sort Molecular structure of trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂
dc.creator.none.fl_str_mv Benzo, Fabián
Sienra, Beatriz
Piro, Oscar Enrique
author Benzo, Fabián
author_facet Benzo, Fabián
Sienra, Beatriz
Piro, Oscar Enrique
author_role author
author2 Sienra, Beatriz
Piro, Oscar Enrique
author2_role author
author
dc.subject.none.fl_str_mv Física
Química
Co(III) complex
crystal structure
kinetics
steric effects
topic Física
Química
Co(III) complex
crystal structure
kinetics
steric effects
dc.description.none.fl_txt_mv The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.
Facultad de Ciencias Exactas
description The title compound crystallizes in the orthorhombic space group Pnma, with a = 7.9209(5), b = 9.818(1), c = 16.867(2) Å, and Z = 4. The structure was solved employing 1864 independent x-ray reflections with I>2σ(I) by Patterson and difference Fourier techniques and refined by full-matrix least-squares to R = 0.036. The trans-[Co(NH₃)₄(NH₂CH₃)Cl](ClO₄)₂ molecule is on a crystallographic mirror plane. The cobalt ion is in an elongated octahedral coordination with four equatorial ammonia ligands [average Co–N distance equal to 1.966(2) Å], an axial methylamine [Co–N=1.965(3)Å], and an axial chlorine ion [Co–Cl=2.2771(9)Å]. Kinetic steric effects of the complex are interpreted in terms of structural results.
publishDate 1998
dc.date.none.fl_str_mv 1998-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/147277
url http://sedici.unlp.edu.ar/handle/10915/147277
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1074-1542
info:eu-repo/semantics/altIdentifier/issn/1572-8854
info:eu-repo/semantics/altIdentifier/doi/10.1023/a:1021786804676
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
69-72
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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