Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄

Autores
Chacón Villalba, María Elizabeth; Echeverría, Gustavo Alberto; Aymonino, Pedro José; Varetti, Eduardo Lelio
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structure of [Ru(NH₃)₄(OH)(NO)]ZnCl₄ was determined by X-ray diffraction methods. Such study confirmed the already reported data for the complex cation and allowed a description of the main features of the lattice structure. An infrared and Raman study of that compound was also performed in order to revise the existing assignment of the vibrational bands. This last study, backed by quantum chemical calculations, lead to a reinterpretation of the spectra. Data were also collected on the structural and vibrational characteristics of the ZnCl₄²⁻ anion. The X-ray structure of the title compound was determined. An infrared and Raman study of the substance was also performed and the data interpreted with the aid of theoretical calculations.
Centro de Química Inorgánica
Instituto de Física La Plata
Materia
Química
Física
Rutenium nitrosyl complex
ZnCl₄²⁻ anion
Structure
Infrared
Raman
Theoretical calculations
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/145142
Acceder
id SEDICI_83d4c8cc48d11bfb11610609add8783f
oai_identifier_str oai:sedici.unlp.edu.ar:10915/145142
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄Chacón Villalba, María ElizabethEcheverría, Gustavo AlbertoAymonino, Pedro JoséVaretti, Eduardo LelioQuímicaFísicaRutenium nitrosyl complexZnCl₄²⁻ anionStructureInfraredRamanTheoretical calculationsThe crystal structure of [Ru(NH₃)₄(OH)(NO)]ZnCl₄ was determined by X-ray diffraction methods. Such study confirmed the already reported data for the complex cation and allowed a description of the main features of the lattice structure. An infrared and Raman study of that compound was also performed in order to revise the existing assignment of the vibrational bands. This last study, backed by quantum chemical calculations, lead to a reinterpretation of the spectra. Data were also collected on the structural and vibrational characteristics of the ZnCl₄²⁻ anion. The X-ray structure of the title compound was determined. An infrared and Raman study of the substance was also performed and the data interpreted with the aid of theoretical calculations.Centro de Química InorgánicaInstituto de Física La Plata2011-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf508-513http://sedici.unlp.edu.ar/handle/10915/145142enginfo:eu-repo/semantics/altIdentifier/issn/1074-1542info:eu-repo/semantics/altIdentifier/issn/1572-8854info:eu-repo/semantics/altIdentifier/doi/10.1007/s10870-010-9910-8info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:16Zoai:sedici.unlp.edu.ar:10915/145142Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:17.196SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
title Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
spellingShingle Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
Chacón Villalba, María Elizabeth
Química
Física
Rutenium nitrosyl complex
ZnCl₄²⁻ anion
Structure
Infrared
Raman
Theoretical calculations
title_short Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
title_full Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
title_fullStr Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
title_full_unstemmed Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
title_sort Crystal Structure and Vibrational Spectra of [Ru(NH₃)₄(OH)(NO)] ZnCl₄
dc.creator.none.fl_str_mv Chacón Villalba, María Elizabeth
Echeverría, Gustavo Alberto
Aymonino, Pedro José
Varetti, Eduardo Lelio
author Chacón Villalba, María Elizabeth
author_facet Chacón Villalba, María Elizabeth
Echeverría, Gustavo Alberto
Aymonino, Pedro José
Varetti, Eduardo Lelio
author_role author
author2 Echeverría, Gustavo Alberto
Aymonino, Pedro José
Varetti, Eduardo Lelio
author2_role author
author
author
dc.subject.none.fl_str_mv Química
Física
Rutenium nitrosyl complex
ZnCl₄²⁻ anion
Structure
Infrared
Raman
Theoretical calculations
topic Química
Física
Rutenium nitrosyl complex
ZnCl₄²⁻ anion
Structure
Infrared
Raman
Theoretical calculations
dc.description.none.fl_txt_mv The crystal structure of [Ru(NH₃)₄(OH)(NO)]ZnCl₄ was determined by X-ray diffraction methods. Such study confirmed the already reported data for the complex cation and allowed a description of the main features of the lattice structure. An infrared and Raman study of that compound was also performed in order to revise the existing assignment of the vibrational bands. This last study, backed by quantum chemical calculations, lead to a reinterpretation of the spectra. Data were also collected on the structural and vibrational characteristics of the ZnCl₄²⁻ anion. The X-ray structure of the title compound was determined. An infrared and Raman study of the substance was also performed and the data interpreted with the aid of theoretical calculations.
Centro de Química Inorgánica
Instituto de Física La Plata
description The crystal structure of [Ru(NH₃)₄(OH)(NO)]ZnCl₄ was determined by X-ray diffraction methods. Such study confirmed the already reported data for the complex cation and allowed a description of the main features of the lattice structure. An infrared and Raman study of that compound was also performed in order to revise the existing assignment of the vibrational bands. This last study, backed by quantum chemical calculations, lead to a reinterpretation of the spectra. Data were also collected on the structural and vibrational characteristics of the ZnCl₄²⁻ anion. The X-ray structure of the title compound was determined. An infrared and Raman study of the substance was also performed and the data interpreted with the aid of theoretical calculations.
publishDate 2011
dc.date.none.fl_str_mv 2011-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/145142
url http://sedici.unlp.edu.ar/handle/10915/145142
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1074-1542
info:eu-repo/semantics/altIdentifier/issn/1572-8854
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10870-010-9910-8
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
508-513
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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